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Cảm ơn bạn @anayuiky đã nhắc lỗi sai. Mình sửa lại ý c):
PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo phương trình \(n_{KMnO_4}=n_{O_2}.2=0,25.2=0,5mol\)
\(\rightarrow m_{KMnO_4}=0,5.\left(39+55+16.4\right)=79g\)
a. \(n_{H_2}=\frac{V}{22,4}=\frac{11,2}{22,4}=0,5mol\)
\(n_{O_2}=\frac{V}{22,4}=\frac{10,08}{22,4}=0,45mol\)
PTHH: \(2H_2+O_2\rightarrow^{t^o}2H_2O\)
Ban đầu: 0,5 0,45 mol
Trong pứng: 0,5 0,25 0,5 mol
Sau pứng: 0 0,2 0,5 mol
\(\rightarrow M_{O_2\left(dư\right)}=n.M=0,2.32=6,4g\)
b. Theo phương trình \(n_{H_2O}=n_{H_2}=0,5mol\)
\(\rightarrow m_{H_2O}=n.M=0,5.18=9g\)
c. PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9 0,45 mol
\(\rightarrow n_{KMnO_4}=\frac{2}{1}n_{O_2}=\frac{0,45.2}{1}=0,9mol\)
\(\rightarrow m_{KMnO_4}=n.M=0,9.158=142,2g\)
a) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,45}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25----->0,5
=> \(m_{O_2\left(dư\right)}=\left(0,45-0,25\right).32=6,4\left(g\right)\)
b) \(m_{H_2O}=0,5.18=9\left(g\right)\)
c)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
Bài 2:
\(n_{Zn}=\dfrac{15,6}{65}=0,24\left(mol\right);n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a,Vì:\dfrac{0,4}{1}>\dfrac{0,24}{1}\Rightarrow H_2SO_4dư\\ n_{H_2\left(LT\right)}=n_{H_2SO_4\left(p.ứ\right)}=n_{Zn}=0,24\left(mol\right)\\ a,n_{H_2\left(TT\right)}=50\%.0,24=0,12\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc,thực.tế\right)}=0,12.22,4=2,688\left(l\right)\\ b,n_{H_2SO_4\left(dư\right)}=0,4-0,24=0,16\left(mol\right)\\ \Rightarrow m_{H_2SO_4\left(dư\right)}=0,16.98=15,68\left(g\right)\)
Bài trên
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right);n_{O_2}=\dfrac{22,4}{22,4}=1\left(mol\right)\\ a,PTHH:2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ Vì:\dfrac{1}{1}>\dfrac{0,5}{2}\Rightarrow O_2thừa\\ n_{O_2\left(thừa\right)}=1-\dfrac{0,5}{2}=0,75\left(mol\right)\\ \Rightarrow m_{O_2\left(thừa\right)}=0,75.32=24\left(g\right)\\ b,n_{H_2O}=n_{H_2}=0,5\left(mol\right)\Rightarrow m_{H_2O}=0,5.18=9\left(g\right)\)
nO2 = 8.96/22.4 =0.4 mol
nFe = 11.2 : 56 = 0.2 mol
PTHH: 3Fe + 2O2 -----> Fe2O3
Theo PT: 3 - 2 -1 (mol)
BC: 0.2 - 0.4 (mol)
Ta có: \(\dfrac{3}{0.2}\)>\(\dfrac{2}{0.4}\)
Suy ra: số mol của Fe dư
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
nP=\(\dfrac{62}{31}\)=0,2(mol)
nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)
PTHH:4P+5O2to→2P2O5
tpứ: 0,2 0,35
pứ: 0,2 0,25 0,1
spứ: 0 0,1 0,1
a)chất còn dư là oxi
mO2dư=0,1.32=3,2(g)
b)mP2O5=n.M=0,1.142=14,2(g)
\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
Câu 8:
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{0,2}{1}\), ta được O2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=0,05\left(mol\right)\\n_{H_2O}=n_{H_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2\left(dư\right)}=0,15.22,4=3,36\left(l\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
Bạn tham khảo nhé!
Câu 9:
a, PT: \(2R+O_2\underrightarrow{t^o}2RO\)
Theo ĐLBT KL, có: mR + mO2 = mRO
⇒ mO2 = 4,8 (g)
\(\Rightarrow n_{O_2}=\dfrac{4,8}{32}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
b, Theo PT: \(n_R=2n_{O_2}=0,3\left(mol\right)\)
\(\Rightarrow M_R=\dfrac{19,2}{0,3}=64\left(g/mol\right)\)
Vậy: M là đồng (Cu).
Câu 10:
Ta có: mBaCl2 = 200.15% = 30 (g)
a, m dd = 200 + 100 = 300 (g)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{30}{300}.100\%=10\%\)
⇒ Nồng độ dung dịch giảm 5%
b, Ta có: \(C\%_{BaCl_2}=\dfrac{30}{150}.100\%=20\%\)
⇒ Nồng độ dung dịch tăng 5%.
Bạn tham khảo nhé!
nP = 6.2/31 = 0.2 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
4P + 5O2 -to-> 2P2O5
0.2___0.25_____0.1
mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g)
mP2O5 = 0.1*142 = 14.2 (g)
Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)
PTHH:
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
ta có:
\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)
=> \(O_2\) dư
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 ----------->2
0.2---------->0.1=nP2O5
=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)
a)
\(n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)\\ n_{O_2} = \dfrac{3,36}{22,4}= 0,15(mol)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\)
Ta thấy :
\( \dfrac{n_{Mg}}{2} = 0,1 < n_{O_2} = 0,15 \) nên O2 dư.
\(n_{O_2\ pư} = \dfrac{n_{Mg}}{2} = 0,1(mol)\\ m_{O_2\ dư} = (0,15-0,1).32 = 1,6(gam)\\ V_{O_2\ dư} = (0,15-0,1).22,4 = 1,12(lít)\)
b)
\(n_{MgO} = n_{Mg} = 0,2\ mol\\ \Rightarrow m_{MgO} = 0,2.40 = 8\ gam\)
a, PTHH: S + O2 -> (t°) SO2
b, nS = 6,4/32 = 0,2 (mol)
nO2 = 6,72/22,4 = 0,3 (mol)
LTL: 0,2 < 0,3 => O2 dư
nO2 (pư) = nSO2 = nS = 0,2 (mol)
mO2 (dư) = (0,3 - 0,2) . 32 = 3,2 (g)
c, mSO2 = 64 . 0,2 = 12,8 (g)
a, \(S+O_2\underrightarrow{t^o}SO_2\)
\(nS=\dfrac{6,4}{32}=0,2\left(mol\right)\)
\(nO_2=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => oxi dư
\(nO_{2\left(dư\right)}=0,1\left(mol\right)\)
\(mO_{2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
\(nSO_2=nS=0,2\left(mol\right)\)
\(mSO_2=0,2.64=12,8\left(g\right)\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
2H2 + O2----t0---> 2H2O
Ta có \(\dfrac{0,5}{2}< \dfrac{0,5}{1}\)
=> H2 phản ứng hết, O2 là chất conf dư
\(m_{O_2du}=m_{O_2bd}-m_{O_2pu}=11,2-0,25.32=3,2\left(g\right)\)
\(m_{H_2O}=0,5.18=9\left(g\right)\)
2H2 + O2 -----> 2H2O
2.........1................1
Ta thấy:
11,2 : 2 < 11,2 : 1
=> O2 dư
=> O2 dư : 11,2 : 2 = 5,6 (lít)
=> nO2(dư) = 5,6 : 22,4 = 0,25(mol)
=> mO2(dư) = 0,25 . 32 = 8(g)
b)
nH2O = 11,2 : 22,4 = 0,5(mol)
=> mH2O = 0,5 . 18 = 9(g)