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a) nHNO3=189/63=3(mol); nKOH= 112/56=2(mol)
PTHH: KOH + HNO3 -> KNO3 + H2O
Ta có: 3/1 > 2/1
-> KOH hết, HNO3 (dư)
nHNO3(p.ứ)= nKOH=2(mol) -> nHNO3(dư)=3-2=1(mol)
2 HNO3 + Ba(OH)2 -> Ba(NO3)2 + 2 H2O
1________0,5(mol)
b) => mBa(OH)2= 171.0,5= 85,5(g)
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
Theo giả thiết ta có : nCO2 = 6,72/22,4 = 0,3 (mol)
a) PTHH :
CO2+Ba(OH)2−>BaCO3↓+H2OCO2+Ba(OH)2−>BaCO3↓+H2O
0,3mol......0,3mol................0,3mol.........0,3mol
b) nồng độ mol của dd Ba(OH)2 đã dùng là :
CMBa(OH)2=0,30,6=0,5(M)CMBa(OH)2=0,30,6=0,5(M)
c) khối lượng kết tủa tạo thành là :
mBaCO3=0,3.197=59,1(g) Bn áp dụng làm nhé
a)
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15<---------0,3<------------------------0,15
=> \(C\%_{dd.CH_3COOH}=\dfrac{0,3.60}{200}.100\%=9\%\)
b)
\(m_{dd.Na_2CO_3}=\dfrac{0,15.106.100}{15}=106\left(g\right)\)
c)
PTHH: 2CH3COOH + Ba(OH)2 --> (CH3COO)2Ba + 2H2O
0,3--------->0,15
=> \(V_{dd.Ba\left(OH\right)_2}=\dfrac{0,15}{0,5}=0,3\left(l\right)=300\left(ml\right)\)
PTHH: \(KOH+HNO_3\rightarrow KNO_3+H_2O\)
\(Ba\left(OH\right)_2+2HNO_3\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{112}{56}=2\left(mol\right)\\n_{HNO_3}=\dfrac{189}{63}=3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) HNO3 dư 1 mol
\(\Rightarrow n_{Ba\left(OH\right)_2}=0,5\left(mol\right)\) \(\Rightarrow m_{ddBa\left(OH\right)_2}=\dfrac{0,5\cdot171}{25\%}=342\left(g\right)\)
a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
a_____3a_______a______\(\dfrac{3}{2}a\) (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b_____2b_______b______b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27a+24b=7,8\\\dfrac{3}{2}a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2\cdot27=5,4\left(g\right)\\m_{Mg}=2,4\left(g\right)\\n_{HCl}=0,8\left(mol\right)=n_{H^+}\end{matrix}\right.\)
b) PT ion: \(H^++OH^-\rightarrow H_2O\)
0,8______0,8
Ta có: \(\left[OH^-\right]=C_{M_{NaOH}}+2C_{M_{Ba\left(OH\right)_2}}=2,2\left(M\right)\) \(\Rightarrow V_{OH^-}=\dfrac{0,8}{2,2}\approx0,36\left(l\right)\)
PTHH: \(HCl+KOH\rightarrow KCl+H_2O\)
\(2HCl_{\left(dư\right)}+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
Axit dư nên tính theo KOH
Ta có: \(\left\{{}\begin{matrix}\Sigma n_{HCl}=\dfrac{109,5}{36,5}=3\left(mol\right)\\n_{KOH}=\dfrac{112}{56}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow n_{HCl\left(dư\right)}=1\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH\right)_2}=0,5\left(mol\right)\) \(\Rightarrow m_{ddBa\left(OH\right)_2}=\dfrac{0,5\cdot171}{25\%}=342\left(g\right)\)