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\(n_{Br_2}=\dfrac{8}{160}=0.05\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(0.05......0.05\)
\(V_{C_2H_4}=0.05\cdot22.4=1.12\left(l\right)\)
\(V_{CH_4}=20-1.12=18.88\left(l\right)\left(mol\right)\)
\(\%V_{C_2H_4}=\dfrac{1.12}{20}\cdot100\%=5.6\%\)
\(\%V_{CH_4}=100-5.6=94.4\%\)
a)
PTHH: C2H2 + 2Br2 --> C2H2Br4
Khí thoát ra là CH4
\(n_{CH_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(n_{C_2H_2}=\dfrac{6,72}{22,4}-0,2=0,1\left(mol\right)\)
\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,2.16}{0,2.16+0,1.26}.100\%=55,17\%\\\%m_{C_2H_2}=\dfrac{0,1.26}{0,2.16+0,1.26}.100\%=44,83\%\end{matrix}\right.\)
b)
PTHH: C2H2 + 2Br2 --> C2H2Br4
0,1--->0,2
=> mBr2 = 0,2.160 = 32 (g)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
ta có :
nBr2=\(\dfrac{16}{160}=0,1mol\)
C2H4+Br2->C2H4Br2
0,1------0,1
=>VC2H4=0,1.22,4=2,24l
=>VCH4=3,36l->n CH4=0,15 mol
->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%
=>%VCH4=60%
c)
CH4+2O2-to>CO2+2H2O
0,15---------------0,15
C2H4+3O2--to>2CO2+2H2O
0,1--------------------0,2
=>m CaCO3=0,35.100=35g
\(a,n_{Br_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,04<---0,04
\(\rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,04.22,4=0,896\left(l\right)\\V_{CH_4}=2,24-0,896=1,344\left(l\right)\end{matrix}\right.\\ b,\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,896}{2,24}.100\%=40\%\\\%V_{CH_4}=100\%-40\%=60\%\end{matrix}\right.\)
Ta có: m dd Br2 tăng = mC2H4 = 2,8 (g)
\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)
⇒ m hh = mCH4 + mC2H4 = 0,05.16 + 0,1.28 = 3,6 (g)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)
\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{6,72}{22,4}-0,1=0,2\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{48}{160}=0,3\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
a--->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = 0,3 (2)
(1)(2) => a = 0,1 (mol); b = 0,1 (mol)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,1.28+0,1.26}.100\%=22,857\%\)
\(\%m_{C_2H_4}=\dfrac{0,1.28}{0,1.16+0,1.28+0,1.26}.100\%=40\%\)
\(\%m_{C_2H_2}=\dfrac{0,1.26}{0,1.16+0,1.28+0,1.26}.100\%=37,143\%\)