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\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,5 0,5
\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)
\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)
\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)
\(\%V_{C_2H_4}=100\%-60\%=40\%\)
nC2H4Br2 = \(\dfrac{4,7}{188}\)=0,025(mol)
C2H4 + Br2 -> C2H4Br2
0,025 <-----------0,025
=>VC2H4 = 0,025 . 22,4=0,56(l)
=> VCH4 = 2,8 - 0,56 =2,24 (l)
%VCH4 =\(\dfrac{2,24.100}{2,8}\)=80%
%VC2H4 = 100 % -80% = 20%
Bài 9 :
Metan không tác dụng với dung dịch Brom nên :
\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)
a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_2|\)
1 1 1
0,025 0,025
b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)
\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)
\(\%V_{C2H4}=\dfrac{0,56.100}{2,8}=20\%\)
\(\%V_{CH4}=100\%-20\%=80\%\)
Chúc bạn học tốt
Bài 14 :
Vì metan không tác dụng với Brom nên :
\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)
a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_{2|}\)
1 1 1
0,025 0,025
b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)
\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)
\(V_{CH4\left(dktc\right)}=1,4-0,56=0,84\left(l\right)\)
0/0VCH4 = \(\dfrac{0,84.100}{1,4}=60\)0/0
0/0VC2H4 = \(\dfrac{0,56.100}{1,4}=40\)0/0
Chúc bạn học tốt
Cho hỗn hợp qua dung dịch brom dư
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Khí thoát ra là \(CH_4\)
\(CH_4+2O_2\rightarrow^{t^o}CO_2+2H_2O\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
Ta có:
\(n_{CaCO_3}=\frac{40}{100}=0,4mol=n_{CO_2}=n_{CH_4}\)
\(\rightarrow V_{CH_4}=0,4.22,4=8,96l\)
\(\rightarrow\%V_{CH_4}=\frac{8,96}{13,56}=66\%\rightarrow\%V_{C_2H_4}=34\%\)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
nBr2 = 32/160 = 0,2 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,2 <--- 0,2
VC2H4 = 0,2 . 22,4 = 4,48 (l)
%VC2H4 = 4,48/6,2 = 72,25%
%VCH4 = 100% - 72,25% = 27,75%
a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)
\(a,n_{Br_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,04<---0,04
\(\rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,04.22,4=0,896\left(l\right)\\V_{CH_4}=2,24-0,896=1,344\left(l\right)\end{matrix}\right.\\ b,\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,896}{2,24}.100\%=40\%\\\%V_{CH_4}=100\%-40\%=60\%\end{matrix}\right.\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, - Khí thoát ra là CH4.
⇒ VCH4 = 4,48 (l)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{4,48}{11,2}.100\%=40\%\\\%V_{C_2H_4}=100-40=60\%\end{matrix}\right.\)
C2H4+Br2---->C2H4Br2
nC2H4Br2=1,88/188=0,1 mol
theo pt nC2H4=nC2H4Br2=0,1 mol
suy ra V C2H4=0,1*22,4=2,24 l
V%c2h4=20%
V%ch4=80%