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\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\)
\(CO_2+Na\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
b. \(n_{MgCO_3}=\dfrac{21}{84}=0,25mol\) \(\Rightarrow n_{HCl}=2.0,25=0,5mol\)
\(V_{ddHCl}=\dfrac{0,5}{2}=0,25l\)
c. \(n_{CO_2}=n_{MgCO_3}=0,25mol\)
\(n_{CaCO_3}=n_{CO_2}=0,25mol\)
\(\Rightarrow m_{CaCO_3}=0,25.100=25g\)
nNa2CO3 = 10,6 / 106 = 0,1 (mol)
Na2CO3 + 2CH3COOH -> 2CH3COONa + H2O + CO2
0,1 0,2 0,2 0,1
mdd CH3COOH = 0,2 * 60 / 5 * 100 = 240 (gam)
CO2 + Ca(OH)2 -> CaCO3 + H2O
0,1 0,1
mCaCO3 = 0,1 * 100 = 10 (gam)
mdd = 240 + 10,6 - 0,1 * 44 = 246,2 (gam)
C% = 82 * 0,2 / 246,2 * 100% = 6,66%
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH:
Na2CO3 + 2CH3COOH ---> 2CH3COONa + CO2 + H2O
0,1---------->0,2----------------->0,2--------------->0,1
CO2 + Ca(OH)2 ---> CaCO3 + H2O
0,1------------------------->0,1
=> \(\left\{{}\begin{matrix}m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240\left(g\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\end{matrix}\right.\)
\(m_{dd}=10,6+240-0,1.44=246,2\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{82.0,2}{246,2}.100\%=6,66\%\)
nAl= 0,5(mol)
a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2
nHCl= 6/2 . 0,5= 1,5(mol)
=>mHCl= 1,5.36,5=54,75(mol)
=> mddHCl= (54,75.100)/18,25=300(g)
b) nH2= 3/2. 0,5=0,75(mol)
=>V(H2,đktc)=0,75.22,4=16,8(l)
c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)
mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)
=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)
\(a,n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ b,n_{MgCl_2}=n_{H_2}=n_{Mg}=0,2\left(mol\right)\\ b,V_{H_2\left(25\text{đ}\text{ộ}C,1bar\right)}=0,2.24,79=4,958\left(l\right)\\ c,n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{\text{dd}HCl}=\dfrac{0,4.36,5.100}{10}=146\left(g\right)\\ m_{\text{dd}A}=m_{Mg}+m_{\text{dd}HCl}-m_{H_2}=4,8+146-0,2.2=150,4\left(g\right)\\ d,C\%_{\text{dd}MgCl_2}=\dfrac{95.0,2}{150,4}.100\approx12,633\%\)
\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=\left(0,1+0,2\right).22,4=6,72l\\ b)V_{ddHCl}=\dfrac{0,2+0,4}{2}=0,3l\\ c)m_{muối}=0,1.127+95.0,2=31,7g\)
\(PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ CuO+H_2SO_4\to CuSO_4+H_2O\\ \Rightarrow n_{Zn}=n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ \Rightarrow m_{Zn}=0,2.65=13(g)\\ \Rightarrow \%_{Zn}=\dfrac{13}{21}.100\%=61,9\%\\ \Rightarrow \%_{CuO}=100\%-61,9\%=38,1\%\\ \Rightarrow n_{CuO}=\dfrac{21-13}{80}=0,1(mol)\\ \Rightarrow \Sigma n_{H_2SO_4}=0,1+0,2=0,3(mol)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{0,3}{0,5}=0,6(l)\)
Na2CO3 + 2HCl \(\rightarrow\)2NaCl + CO2 + H2O (1)
Ca(OH)2 + CO2 \(\rightarrow\)CaCO3 + H2O (2)
nNa2CO3=\(\dfrac{10,6}{106}=0,1\left(mol\right)\)
Theo PTHH 1 ta có:
2nNa2CO3=nHCl=0,2(mol)
V dd HCl=\(\dfrac{0,2}{0,5}=0,4\left(lít\right)\)
b;
Theo PTHH 1 ta có:
nNa2CO3=nCO2=0,1(mol)
Theo PTHH 2 ta có:
nCO2=nCaCO3=0,1(mol)
mCaCO3=100.0,1=10(g)