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PTHH: \(3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
Ta có: \(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
\(\Rightarrow n_{FeCl_3}=n_{Fe\left(OH\right)_3}=\dfrac{1}{12}\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{FeCl_3}=\dfrac{1}{12}\cdot162,5\approx13,54\left(g\right)\\m_{Fe\left(OH\right)_3}=\dfrac{1}{12}\cdot107\approx8,92\left(g\right)\end{matrix}\right.\)
nNaOH = m/M = 10/(23 +16 + 1) = 0,25 (mol)
Ta có PTHH: 3NaOH + FeCl3 ------> Fe(OH)3 + 3NaCl
Theo PT: 3 - 1 - 1 (mol)
BC: 0.25 - 0.083 - 0.083 (mol)
Suy ra: mFeCl3 = n x M = 0.083 x (56 + 35,5 x 3) = 13,4875 (g)
mFe(OH)3 = n x M = 0,083 x (56+17 x 3) = 8,881 (g)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
b) $n_{HCl} = 2n_{H_2} = 0,3(mol)$
$\Rightarrow m_{HCl} = 0,3.36,5 = 10,95(gam)$
c)
Cách 1 : $n_{FeCl_2} = n_{H_2} = 0,15(mol) \Rightarrow m_{FeCl_2} = 0,15.127 = 19,05(gam)$
Cách 2 : Bảo toàn khối lượng, $m_{FeCl_2} = 8,4 + 10,95 - 0,15.2 = 19,05(gam)$
\(HCl+NaOH\rightarrow NaCl+H_2O\\ n_{HCl}=n_{NaCl}=n_{NaOH}=1,5.0,1=0,15\left(mol\right)\\ a,m_{HCl}=0,15.36,5=5,475\left(g\right)\\ b,m_{NaCl}=58,5.0,15=8,775\left(g\right)\)
\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)
\(Fe+\dfrac{3}{2}Cl_2\underrightarrow{^{^{t^0}}}FeCl_3\)
\(0.1.......0.15..........0.1\)
\(V_{Cl_2}=0.15\cdot22.4=3.36\left(l\right)\)
\(m_{FeCl_3}=0.1\cdot162.5=16.25\left(g\right)\)
a) nNaOH= 6/40=0,15(mol)
nFeCl3=32,5/162,5= 0,2(mol)
PTHH: 3 NaOH + FeCl3 -> Fe(OH)3 + 3 NaCl
0,15________0,05____0,05________0,15(mol)
Ta có: 0,2/1 > 0,15/3
=> NaOH hết, FeCl3 dư
=> nFeCl3(dư)= 0,2-0,05=0,15(mol)
=> mFeCl3= 162,5.0,15=24,375(g)
b)m(kết tủa)= mFe(OH)3= 0,05.107= 5,35(g)
a) PTHH: FeCl3 + 3KOH → Fe(OH)3 + 3KCl
b) Theo ĐLBTKL ta có:
\(m_{FeCl_3}+m_{KOH}=m_{Fe\left(OH\right)_3}+m_{KCl}\)
\(\Leftrightarrow m_{FeCl_3}=m_{Fe\left(OH\right)_3}+m_{KCl}-m_{KOH}=2,14+4,47-3,36=3,25\left(g\right)\)
số mol NaOH là:\(n_{NaOH}=\frac{10}{23+16+1}=0,25\left(mol\right)\)
PTHH\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(m_{FeCl_3}=n.M=\frac{0.25}{3}\cdot\left(56+35,5\cdot3\right)\approx13,54\left(g\right)\)
\(m_{Fe\left(OH\right)_3}=n.M=\frac{0.25}{3}\cdot\left(56+\left(16+1\right)\cdot3\right)\approx8,91\left(g\right)\)
\(m_{NaCl}=n.M=0.25\cdot\left(23+35.5\right)=14.625\left(g\right)\)