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a)
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15<---------0,3<------------------------0,15
=> \(C\%_{dd.CH_3COOH}=\dfrac{0,3.60}{200}.100\%=9\%\)
b)
\(m_{dd.Na_2CO_3}=\dfrac{0,15.106.100}{15}=106\left(g\right)\)
c)
PTHH: 2CH3COOH + Ba(OH)2 --> (CH3COO)2Ba + 2H2O
0,3--------->0,15
=> \(V_{dd.Ba\left(OH\right)_2}=\dfrac{0,15}{0,5}=0,3\left(l\right)=300\left(ml\right)\)
a, \(n_{CO_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{CH_3COOH}=2n_{CO_2}=0,05\left(mol\right)\)
\(\Rightarrow C\%_{CH_3COOH}=\dfrac{0,05.60}{100}.100\%=3\%\)
b, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,025\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,025.106=2,65\left(g\right)\)
\(n_{CH_3COONa}=2n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
c, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,05\left(mol\right)\)
Mà: H = 80%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,05}{80\%}=0,0625\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,0625.46=2,875\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{2,875}{0,8}=3,59375\left(ml\right)\)
\(\Rightarrow V_{C_2H_5OH\left(10^o\right)}=\dfrac{3,59375}{10}.100=35,9375\left(ml\right)\)
\(a)n_{CH_3COOH} = 0,2.2 = 0,4(mol)\\ Mg + 2CH_3COOH \to (CH_3COO)_2Mg + H_2\\ n_{Mg} = \dfrac{1}{2}n_{CH_3COOH} = 0,2(mol)\\ m_{Mg} = 0,2.24 = 4,8(gam)\\ b)\\ CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\\ n_{CH_3COOH\ pư} = n_{este} = \dfrac{24,64}{88} = 0,28(mol)\\ H = \dfrac{0,28}{0,4}.100\% = 70\%\)
2C2H5OH+Na->2C2H5ONa +H2
0,3------------------------------------0,15
2CH3COOH+Na->2CH3COONa+H2
0,1-------------------------------------->0,05
NaOH+CH3COOH->CH3COONa+H2O
0,1-------0,1 mol
n khí =4,48 \22,4=0,2 mol
n NaOH=0,5.0,2=0,1 mol
=>nH2 pt2=0,05
=>n H2 pt1=0,15
=>mC2H5OH=0,3.46=13,8g
=>m CH3COOH=0,1.60=6g
a)
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1--------->0,2------------->0,2------------>0,1
=> mCH3COOH = 0,2.60 = 12 (g)
\(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
b) \(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{0,2.80}{100}=0,16\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
0,16------------------------------------->0,16
=> \(m_{CH_3COOC_2H_5}=0,16.88=14,08\left(g\right)\)
a.b.\(n_{Mg}=\dfrac{4,8}{24}=0,2mol\)
\(2Mg+2CH_3COOH\rightarrow2\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,2 0,2 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,2}=1M\)
\(m_{\left(CH_3COO\right)_2Mg}=0,2.142=28,4g\)
c.Sửa đề: thu được 9,2g este
\(n_{CH_3COOC_2H_5}=\dfrac{9,2}{88}=0,1mol\)
\(CH_3COOH+C_2H_5OH\rightarrow CH_3COOC_2H_5+H_2O\)
Thực tế: 0,2 0,1 ( mol )
Lý thuyết: 0,1 0,1 ( mol )
\(H=\dfrac{0,1}{0,2}.100=50\%\)
Số mol của Mg là 4,8:24=0,2 (mol).
Mg (0,2 mol) + 2CH3COOH (0,4 mol) \(\rightarrow\) Mg(OOCCH3)2 (0,2 mol) + H2.
a) Nồng độ mol cần tìm là 0,4:0,2=2 (mol/l).
b) Khối lượng của magie axetat là 0,2.142=28,4 (g).
Bạn kiểm tra lại giúp mình câu c nhé!
\(a,m_{CH_3COOH}=\dfrac{200.10}{100}=20\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{20}{60}=\dfrac{1}{3}\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
\(\dfrac{1}{3}\)-------------->\(\dfrac{1}{6}\)
b, => mNa2CO3 = \(\dfrac{1}{6}.106=\dfrac{53}{3}\left(g\right)\)
tk
a,mCH3COOH=200.10/100=20(g)→nCH3COOH=20/60=13(mol)a,mCH3COOH=200.10100=20(g)→nCH3COOH=20/60=13(mol)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
1313-------------->1616
b, => mNa2CO3 = 16.106=533(g)