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a)
4Al + 3O2 --to--> 2Al2O3
2Mg + O2 --to--> 2MgO
b) Gọi số mol Al, Mg là a, b (mol)
=> 27a + 24b = 7,8 (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
a--->0,75a----->0,5a
2Mg + O2 --to--> 2MgO
b--->0,5b------->b
=> 102.0,5a + 40b = 14,2
=> 51a + 40b = 14,2 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
nO2 = 0,75a + 0,5b = 0,2 (mol)
=> VO2 = 0,2.22,4 = 4,48 (l)
=> Vkk = 4,48 : 20% = 22,4 (l)
c)
mAl = 0,2.27 = 5,4 (g)
mMg = 0,1.24 = 2,4 (g)
a)
4Al + 3O2 --to--> 2Al2O3
2Mg + O2 --to--> 2MgO
b) Gọi số mol Al, Mg là a, b (mol)
=> 27a + 24b = 7,8 (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
a--->0,75a----->0,5a
2Mg + O2 --to--> 2MgO
b--->0,5b------->b
=> 102.0,5a + 40b = 14,2
=> 51a + 40b = 14,2 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
nO2 = 0,75a + 0,5b = 0,2 (mol)
=> VO2 = 0,2.22,4 = 4,48 (l)
=> Vkk = 4,48 : 20% = 22,4 (l)
c)
mAl = 0,2.27 = 5,4 (g)
mMg = 0,1.24 = 2,4 (g)
a)
2CO + O2 --to--> 2CO2
2H2 + O2 --to--> 2H2O
b) \(n_{H_2O}=\dfrac{12,6}{18}=0,7\left(mol\right)\); \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,6<--0,3<------0,6
2H2 + O2 --to--> 2H2O
0,7<--0,35<------0,7
=> \(\left\{{}\begin{matrix}V_{CO}=0,6.22,4=13,44\left(l\right)\\V_{H_2}=0,7.22,4=15,68\left(l\right)\end{matrix}\right.\)
VO2 = (0,3 + 0,35).22,4 = 14,56 (l)
c) \(M_A=\dfrac{0,6.28+0,7.2}{0,6+0,7}=14\left(g/mol\right)\)
=> \(d_{A/O_2}=\dfrac{14}{32}=0,4375\)
a, Ta có: \(n_{Al}=\dfrac{13,5}{27}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
Xét tỉ lệ: \(\dfrac{0,5}{4}>\dfrac{0,3}{3}\), ta được Al dư.
Theo PT: \(\left\{{}\begin{matrix}n_{Al_2O_3}=\dfrac{2}{3}n_{O_2}=0,2\left(mol\right)\\n_{Al\left(pư\right)}=\dfrac{4}{3}n_{O_2}=0,4\left(mol\right)\end{matrix}\right.\)
⇒ nAl (dư) = 0,5 - 0,4 = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2O_3}=0,2.102=20,4\left(g\right)\\m_{Al\left(dư\right)}=0,1.27=2,7\left(g\right)\end{matrix}\right.\)
b, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,15\left(mol\right)\)
\(\Rightarrow V_{H_2}=\dfrac{0,015.0,082.\left(25+273\right)}{0,986}\approx3,7274\left(l\right)\)
a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)
\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)
\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)
b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)
\(\rightarrow V_{kk}=4,48.5=11,2l\)
c. Có \(n_{Mg}=2n_{O_2}=0,2l\)
\(\rightarrow m_{Mg}=0,2.24=4,8g\)
\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)
\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)
\(a,Đặt:n_{CH_4}=a\left(mol\right);n_{C_4H_{10}}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ 2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\\ \Rightarrow\left\{{}\begin{matrix}16a+58b=7,4\\22,4a+22,4.4b=22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6\left(g\right)\\m_{C_4H_{10}}=0,1.58=5,8\left(g\right)\end{matrix}\right.\\ b,n_{O_2}=2a+\dfrac{13}{2}b=2.0,1+6,5.0,1=0,85\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,85.22,4=19,04\left(l\right)\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1mol\)
\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(n_{O_2}=\dfrac{26,88:5}{22,4}=0,24mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
0,1 0,05 0,1 ( mol )
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,2 0,15 0,1 ( mol )
\(n_{O_2\left(td\right)}=0,05+0,15=0,2mol\)
=> Hỗn hợp A cháy hết
\(\left\{{}\begin{matrix}m_{MgO}=0,05.40=2g\\m_{Al_2O_3}=0,1.102=10,2g\end{matrix}\right.\)