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a)
\(n_{H_2}=\dfrac{0,336}{22,4}=0,015\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2
0,03<------------0,03<----0,015
=> \(\%m_{Na}=\dfrac{0,03.23}{1,31}.100\%=52,67\%\)
=> \(\%m_{Na_2O}=100\%-52,67\%=47,33\%\)
b)
\(n_{Na_2O}=\dfrac{1,31.47,33\%}{62}=0,01\left(mol\right)\)
PTHH: Na2O + H2O --> 2NaOH
0,01----------->0,02
=> nNaOH = 0,03 + 0,02 = 0,05 (mol)
mdd sau pư = 1,31 + 18,72 - 0,015.2 = 20 (g)
=> \(C\%_{dd.NaOH}=\dfrac{0,05.40}{20}.100\%=10\%\)
\(V_{dd.NaOH}=\dfrac{20}{1,2}=\dfrac{50}{3}\left(ml\right)=\dfrac{1}{60}\left(l\right)\)
\(C_{M\left(dd.NaOH\right)}=\dfrac{0,05}{\dfrac{1}{60}}=3M\)
\(a)n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\\ PTHH:2Na+2H_2O\xrightarrow[]{}2NaOH+H_2\\ n_{H_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b)n_{Na}=n_{NaOH}=0,4mol\\ m_{NaOH}=0,4.40=16\left(g\right)\\ m_{H_2}=0,2.2=0,4\left(g\right)\\ m_{ddNaOH}=9,2+191,2-0,4=200\left(g\right)\\ C_{\%NaOH}=\dfrac{16}{200}.100\%=8\%\)
a)Quy \(\left\{{}\begin{matrix}Na:x\left(mol\right)\\Ba:y\left(môl\right)\\O:z\left(mol\right)\end{matrix}\right.\underrightarrow{+H_2O}\left\{{}\begin{matrix}NaOH:x\left(mol\right)\\Ba\left(OH\right)_2:y\left(mol\right)\\O^{2-}:z\left(mol\right)\end{matrix}\right.+H_2\)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\)
\(n_{Ba\left(OH\right)_2}=\dfrac{20,52}{171}=0,12mol\Rightarrow y=0,12mol\)
Ta có hệ: \(\left\{{}\begin{matrix}BTKL:23x+137y+16z=21,9\\y=0,12\\BTe:x+2y=2z+2n_{H_2}\Rightarrow x-2z=-0,14\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,14\\y=0,12\\z=0,14\end{matrix}\right.\)
\(n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,14+2\cdot0,12=0,38mol\)
\(n_{CO _2}=\dfrac{6,72}{22,4}=0,3mol\Rightarrow n_{CO_3^{2-}}=0,38-0,3=0,08mol\)
\(\Rightarrow m_{CO_3^{2-}\downarrow}=0,08\cdot197=15,76g\)
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
mH2SO4= \(\dfrac{300.7,35}{100}=22,05g\)
nH2SO4= \(\dfrac{22,05}{98}=0,225 mol\)
mHCl= \(\dfrac{200.7,3}{100}=14,6g\)
nHCl= \(\dfrac{14,6}{36,5}=0,4mol\)
H2SO4 + 2HCl → 2H2O + Cl2 ↑+ SO2 ↑
n trước pư 0,225 0,4
n pư 0,2 ← 0,4 → 0,4 → 0,2 → 0,2 mol
n sau pư dư 0,025 hết
a) mCl2= 0,2. 71= 14,2g
mSO2= 64. 0,2= 12,8g
mH2O= 18. 0,4=7,2g
mdd sau pư= 300 +200 -14,2 -12,8= 473g
C%dd H2O= \(\dfrac{7,2.100}{473}=1,52\)%
b) Mg + 2H2O → Mg(OH)2 + H2 ↑
x → 2x → x → x
Fe + 2H2O → Fe(OH)2 + H2↑
y → 2y → y → y
Gọi x,y lần lượt là số mol của Mg,Fe.
Ta có hệ phương trình:
24x + 56y = 8,7 x= \(\dfrac{5}{64}\)
⇒
2x + 2y = 0,4 y= \(\dfrac{39}{320}\)
VH2= 22,4. \((\dfrac{5}{64}+\dfrac{39}{320})\)= 4,48l
mhh MG(OH)2, Fe(OH)2= 8,7 +250 - 2.(\(\dfrac{5}{64}+\dfrac{39}{320}\)) = 2258,3g
mMg=24. \(\dfrac{5}{64}\)=1.875g
mFe= 8,7-1,875= 6,825g
Ủa đề gì kì cục vậy em !
Góc là cốc ấy anh ạTT Tại đọc nhanh nên mới thành góc TT