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a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,2 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H2SO4 dư
\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
b) Vdd sau pứ = 0,2 + 0,15 = 0,35 (l)
\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,1 0,1 0,1
a) \(n_{H2SO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,1}{2}=0,05\left(l\right)\)
b) \(n_{FeSO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(C_{M_{FeSO4}}=\dfrac{0,1}{0,05}=2\left(M\right)\)
Chúc bạn học tốt
a,\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
b,\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c,\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
d,\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{6}\left(mol\right)\Rightarrow m_{Al}=\dfrac{1}{6}.27=4,5\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,25\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,25}{0,2}=1,25\left(M\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=\dfrac{1}{12}\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{12}.342=28,5\left(g\right)\)
\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)
\(a)n_{MnO_2}=\dfrac{69,6}{87}=0,8mol\\ MnO_2+4HCl\xrightarrow[nhẹ]{đun}MnCl_2+Cl_2+H_2O\)
0,8 3,2 0,8 0,8 0,8
\(V_A=V_{Cl_2}=0,8.22,4=17,92l\\ b)Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)
0,8 1,6 0,8 0,8
\(V_{ddNaOH}=\dfrac{1,6}{1}=1,6l\\ C_{M_{NaCl}}=\dfrac{0,8}{1,6}=0,5M\\ C_{M_{NaClO}}=\dfrac{0,8}{1,6}=0,5M\)
\(2Fe+6H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
Gọi 0,375a là mol Fe \(\Rightarrow\) nH2SO4= a mol
\(n_{Fe_{pu}}=\frac{a}{3}\left(mol\right)\)
Nên dư a/24 mol Fe. Tạo a/6 mol Fe2(SO4)3
\(Fe+Fe_2\left(SO_4\right)_3\rightarrow3FeSO_4\)
\(\Rightarrow\) nFeSO4= a/8 mol. Dư a/8 mol Fe2(SO4)3.
m muối= 8,28g
\(\Rightarrow\frac{152a}{8}+\frac{400a}{8}=8,28\)
\(\Rightarrow a=0,12\)
nFe phản ứng= 0,375a= 0,045 mol
\(\Rightarrow m_{Fe}=2,52\left(g\right)\)
\(n_{H2SO4}=0,12\left(mol\right)\Rightarrow n_{SO2}=0,06\left(mol\right)\)
\(n_{NaOH}=0,1\left(mol\right)\)
\(\frac{n_{NaOH}}{n_{SO2}}=1,67\Rightarrow\) Tạo 2 muối
\(NaOH+SO_2\rightarrow NaHSO_3\)
\(2NaOH+SO_2\rightarrow Na_2SO_3+H_2O\)
Gọi x là mol NaHSO3, y là mol Na2SO3
\(\left\{{}\begin{matrix}x+2y=0,1\\x+y=0,06\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,04\end{matrix}\right.\)
\(CM_{NaHSO3}=\frac{0,02}{0,1}=0,2M\)
\(CM_{Na2SO3}=\frac{0,04}{0,1}=0,4M\)