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a) $CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$
b) $n_{Cu(OH)_2} = n_{CuSO_4} = \dfrac{16}{160} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$
c) $n_{NaOH} = 2n_{CuSO_4} = 0,2(mol) \Rightarrow C_{M_{NaOH}} = \dfrac{0,2}{0,1} = 2M$
PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2\left(M\right)\\m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\end{matrix}\right.\)
a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
b. Đổi 100ml = 0,1 lít
Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)
=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
a)
$Fe + CuSO_4 \to FeSO_4 + Cu$
Theo PTHH : $n_{Cu} = n_{CuSO_4} = 0,3.1 = 0,3(mol)$
$m_{Cu} = 0,3.64 = 19,2(gam)$
b) $n_{FeSO_4} = n_{CuSO_4} = 0,3(mol)$
$\Rightarrow m_{FeSO_4} = 0,3.152 = 45,6(gam)$
c) $FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4$
$n_{Fe(OH)_2} = n_{FeSO_4} = 0,3(mol)$
$m_{Fe(OH)_2} = 0,3.90 = 27(gam)$
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
a, \(n_{CuCl_2}=\dfrac{48,5}{135}=\dfrac{97}{270}\left(mol\right)\)
\(n_{NaOH}=\dfrac{24}{40}=0,6\left(mol\right)\)
PT: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
Xét tỉ lệ: \(\dfrac{\dfrac{97}{270}}{1}>\dfrac{0,6}{2}\), ta được CuCl2 dư.
Theo PT: \(n_{CuCl_2\left(pư\right)}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,3\left(mol\right)\)
\(\Rightarrow m_{CuCl_2\left(dư\right)}=48,5-0,3.135=8\left(g\right)\)
b, \(m_{Cu\left(OH\right)_2}=0,3.98=29,4\left(g\right)\)
$n_{NaOH} = \dfrac{8}{40} = 0,2(mol)$
$CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$
Ta thấy :
$n_{NaOH} : 2 < n_{CuSO_4} : 1$ nên $CuSO_4$ dư
$n_{Cu(OH)_2} = \dfrac{1}{2}n_{NaOH} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$