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\(a)ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ b)n_{ZnO}=\dfrac{8,1}{81}=0,1mol\\ n_{HCl}=\dfrac{300.3,65}{100.36,5}=0,3mol\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,3}{2}\Rightarrow HCl.dư\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,2 0,1 0,1
\(m_{ZnCl_2}=0,1.136=13,6g\\ m_{HCl.dư}=\left(0,3-0,2\right).36,5=3,65g\\ m_{H_2O}=0,1.18=1,8g\\ c)C_{\%ZnCl_2}=\dfrac{13,6}{8,1+300}\cdot100=4,41\%\\ C_{\%HCl.dư}=\dfrac{3,65}{8,1+300}\cdot100=1,18\%\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(m_{HCl}=3,65\%.300=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
a) PTHH : \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,3 0,1
b) Xét tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{2}\Rightarrow HCldư\)
Sau phản ứng gồm có : ZnCl2 và dd HCl dư
\(m_{ZnCl2}=0,1.136=13,6\left(g\right)\)
\(m_{HCl\left(dư\right)}=\left(0,3-0,1.2\right).36,5=3,65\left(g\right)\)
c) \(m_{ddspu}=8,1+300=308,1\left(g\right)\)
\(C\%_{ddHCldư}=\dfrac{3,65}{308,1}.100\%=1,18\%\)
\(C\%_{ZnCl2}=\dfrac{13,6}{308,1}.100\%=4,41\%\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(m_{ct}=\dfrac{14,6.200}{100}=29,2\left(g\right)\)
\(n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
Pt : \(ZnO+2HCl\rightarrow ZnCl_2+H_2O|\)
1 2 1 1
0,1 0,8 0,1
Lập tỉ số so sánh : \(\dfrac{0,1}{1}< \dfrac{0,8}{2}\)
⇒ ZnO phản ứng hết , HCl dư
⇒ Tính toán dựa vào số mol của ZnO
\(n_{ZnCl2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,1.136=13,6\left(g\right)\)
\(n_{HCl\left(dư\right)}=0,8-\left(0,1.2\right)=0,6\left(mol\right)\)
⇒ \(m_{HCl\left(dư\right)}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddspu}=8,1+200=208,1\left(g\right)\)
\(C_{ZnCl2}=\dfrac{13,6.100}{208,1}=6,54\)0/0
\(C_{HCl\left(dư\right)}=\dfrac{21,9.100}{208,1}=10,52\)0/0
Chúc bạn học tốt
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
a/ \(n_{KOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,3.1=0,3\left(mol\right)\)
PTHH: 2KOH + H2SO4 → K2SO4 + 2H2O
Mol: 0,2 0,1 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ KOH hết, H2SO4 dư
b/ \(m_{H_2SO_4dư}=\left(0,3-0,1\right).98=19,6\left(g\right)\)
c/ Vdd sau pứ = 0,2 + 0,3 = 0,5 (l)
d/ \(C_{M_{ddK_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,5}=0,4M\)
a. PTHH: H2SO4 + 2NaOH ---> Na2SO4 + 2H2O
b. Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{300}.100\%=19,6\%\)
=> \(m_{H_2SO_4}=58,8\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{58,8}{98}=0,6\left(mol\right)\)
Ta lại có: \(C_{\%_{NaOH}}=\dfrac{m_{NaOH}}{200}.100\%=20\%\)
=> mNaOH = 40(g)
=> \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)
Ta thấy: \(\dfrac{0,6}{1}>\dfrac{1}{2}\)
Vậy H2SO4 dư.
=> \(m_{dd_{Na_2SO_4}}=300+40=340\left(g\right)\)
Theo PT: \(n_{Na_2SO_4}=\dfrac{1}{2}.n_{NaOH}=\dfrac{1}{2}.1=0,5\left(mol\right)\)
=> \(m_{Na_2SO_4}=0,5.142=71\left(g\right)\)
=> \(C_{\%_{Na_2SO_4}}=\dfrac{71}{340}.100\%=20,88\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(m_{ct}=\dfrac{19,6.200}{100}=39,2\left(g\right)\)
\(n_{H2SO4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
a) Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)
2 3 1 3
0,2 0,4 0,1 0,3
b) Lap ti so so sanh : \(\dfrac{0,2}{2}< \dfrac{0,4}{3}\)
⇒ Al phan ung het , H2SO4 du
⇒ Tinh toan dua vao so mol cua Al
\(n_{Al2\left(SO4\right)3}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,1.342=34,2\left(g\right)\)
\(n_{H2SO4\left(du\right)}=0,4-\left(\dfrac{0,2.3}{2}\right)=0,1\left(mol\right)\)
⇒ \(m_{H2SO4\left(du\right)}=0,1.98=9,8\left(g\right)\)
\(m_{ddspu}=5,4+200-\left(0,3.2\right)=204,8\left(g\right)\)
\(C_{Al2\left(So4\right)3}=\dfrac{34,2.100}{204,8}=16,7\)0/0
\(C_{H2SO4\left(du\right)}=\dfrac{9,8.100}{204,8}=4,78\)0/0
Chuc ban hoc tot
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
b) $n_{Fe} = \dfrac{14}{56} = 0,25(mol)$
Theo PTHH : $n_{H_2SO_4} = n_{Fe} = 0,25(mol)$
$\Rightarrow m_{dd\ H_2SO_4} = \dfrac{0,25.98}{10\%} = 245(gam)$
c)
$n_{H_2} = n_{Fe} = 0,25(mol)$
Sau phản ứng, $m_{dd} = 14 + 245 - 0,25.2 = 258,5(gam)$
$C\%_{FeSO_4} = \dfrac{0,25.152}{258,5}.100\% = 14,7\%$
\(n_{Fe_2O_3}=\dfrac{10}{160}=0,0625\left(mol\right)\\ n_{HCl}=\dfrac{200.18,25\%}{36,5}=1\left(mol\right)\\ Fe_2O_3+6HCl\xrightarrow[]{}2FeCl_3+3H_2O\\ TC:\dfrac{0,0625}{1}< \dfrac{1}{6}\Rightarrow HCl.dư\\ n_{FeCl_3}=0,0625.2=0,125\left(mol\right)\\ n_{HCl}=0,0625.6=0,375\left(mol\right)\\ m_{dd}=10+200=210\left(g\right)\\ C_{\%FeCl_3}=\dfrac{0,125.162,5}{210}\cdot100\approx9,67\%\\ C_{\%HCl\left(dư\right)}=\dfrac{\left(1-0,375\right).36,5}{210}\cdot100\approx10,86\%\)
nZnO=8.1/81=0.1
nH2SO4=(mdd.C%)/(100.M)=(200.10)/(100.98)=0.2
a)ZnO + H2SO4 --> ZnSO4 + H2O
0.1 ---->0.1---->0.1--->0.1
LTL: 0.1/1 < 0.2/1 ==> H2SO4 dư
áp dụng định luật bảo toàn khối lượng ta có
mddZnSO4=mZnO+mddH2SO4=8.1+200=208.1g
==>C%ZnSO4=(0,1.160).100/208.1=7.69%
nH2SO4 dư = 0.2-0.1=0.1
C%H2SO4dư=(0,1.98).100/208.1=4.71%
nZnO= 8,1/81=0.1(mol)
nH2SO4= 200.10/100.98=0.2(mol)
ZnO + H2SO4 -> ZnSO4 +H2O
đề 0,1 0,2
pứ 0,1 0,1 0,1
dư 0 0,1
mddspu = 8,1+200=208,1(g)
C%ZnSO4=0,1.161.100/208,1=7,74%
C%H2SO4 dư= 0.1.98.100/208,1=4,71%