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CaCl\(_2\)+ 2AgNO\(_3\)\(\)--> 2AgCl + Ca(NO\(_3\))\(_2\)
n\(_{CaCl2}\)=0.02 mol
a) theo pthh nAgCl=2nCaCl2=0.04 mol
m\(_{r\text{ắn}}\)= 0.04\(\)*143.5=5.74g
b) nCa(NO3)2=nCaCl2=0.02 mol
CM=\(\frac{0.02}{0.03+0.07}\)=0.2M
a) CaCl2 + 2AgNO3 -> Ca(NO3)2 + 2AgCl
0,02 0,04 0,02 0,04
nCaCl2 = 2,22 / 111 = 0,02 (mol)
m rắn (AgCl) = 0,04 x 143,5 = 5,74 (g)
b) V dd = 30 + 70 = 100 (ml)
Đổi : 100 ml = 0,1 l
Cm Ca(NO3)2 = 0,02 / 0,1 = 0,2 M
a) 2AgNO3+CaCl2---->2AgCl+Ca(NO3)2
n AgNO3=1,7/170=0,01(mol)
n CaCl2=2,22/111=0,02(mol)
----> CaCl2 dư
Theo pthh
n AgCl=n AgNO3=0,01(mol)
m AgCl=0,01.143,5=14,35(g)
V dd sau pư=70+30=`100ml=0,1(l)
n CaCl2 dư=0,02-0,005=0,015(mol)
CM CaCl2=0,015/0,1=0,15(M)
Theo pthh
n Ca(NO3)2=1/2 n AgCl=0,005(mol)
CM Ca(NO3)2=0,005/0,1=0,05(M)
Bài 2
BaCl2+H2SO4--->BaSO4+2HCl
a) n BaCl2=400.5,2/100=20,8(g)
n BaCl2=20,8/208=0,1(mol)
m H2SO4=100.1,14.20/100=22,8(g)
n H2SO4=22,8/98=0,232(mol)
---->H2SO4 dư
Theo pthh
n BaSO4=n BaCl2=0,1(mol)
m BaSO4=0,1.233=23,3(g)
b) m dd sau pư=400+114-23,3
=490,7(g)
Theo pthh
n HCl=2n BaCl2=0,2(mol)
C%HCl=\(\frac{0,2.36,5}{490,7}.100\%=1,88\%\)
n H2SO4 dư=0,232-0,1=0,132(mol)
C% H2SO4=\(\frac{0,132.98}{490,7}.100\%=2,64\%\)
B1:
\(n_{AgNO3}=0,01\left(mol\right);n_{CaCl2}=0,2\left(mol\right)\)
PTHH:\(2AgNO3+CaCl2\rightarrow2AgCl2\downarrow+Ca\left(NO3\right)2\)
Trước :0,01................0,02..........................................................(mol)
Pứng:\(0,01\rightarrow0,005\rightarrow0,01\rightarrow0,005\)
Dư: 0............................0,015......................................................(mol)
\(m\downarrow_{AgCL}=0,01.143,5=1,435\left(g\right)\)
Trong dd sau phản ứng chứa: \(\left\{{}\begin{matrix}Ca\left(NO3\right)2:0,005\left(mol\right)\\CaCl2:0,015\left(mol\right)\end{matrix}\right.\)
\(C_{M_{Ca\left(NO3\right)2}}=\frac{0,005}{0,1}=0,05M\)
\(C_{M_{CaCl2}}=\frac{0,015}{0,1}=0,15M\)
Bài 2:\(n_{BaCl2}=\frac{400.5,2}{100.208}=0,1\left(mol\right)\)
\(D=\frac{m_{dd}}{v_{dd}};C\%=\frac{m_{ct}}{m_{dd}}.100\Rightarrow m_{H2SO4}=\frac{D.v.d^2.C\%}{100}=22,8g\)
\(\Rightarrow n_{H2SO4}=0,23\left(mol\right)\)
\(BaCl2+HSO4\rightarrow BaSO4\downarrow+2HCl\)
0,1..............0,1............0,1.................0,2.....(mol)
\(a,m_{\downarrow}=0,1.223=23,3\left(g\right)\)
\(b,m_{dd_{saupu}}=m_{BaCl2}+m_{dd_{H2SO4}}-m_{\downarrow}_{BaSO4}\)
\(=400+1,14.100-23,3=490,7\)
\(\Rightarrow C\%_{HCl}=\frac{0,2.36,5}{490,7}.100\%=1,48\%\)
\(\%H2SO4_{du}=\frac{\left(0,23-0,1\right).98}{490,7}.100=2,59\%\)
dd sau pư gồm Ca(NO3)2 và CaCl2 dư.
V(dd sau pư) = 30+70 = 100 (ml) = 0,1 (l)
n(Ca(NO3)2) = 0,005 mol
n(CaCl2 dư) = 0,02 - 0,005 = 0,015 mol
-> CM(Ca(NO3)2) = 0,005/0,1 = 0,05 M
CM(CaCL2) = 0,015/0,1 = 0,15 M.
Gọi nNa2CO3 = x (mol)
Na2CO3 + 2HCl \(\rightarrow\) 2NaCl + H2O + CO2
x \(\rightarrow\) 2x \(\rightarrow\) 2 x (mol)
C%(NaCl) = \(\frac{2.58,5x}{200+120}\) . 100% = 20%
=> x =0,547 (mol)
mNa2CO3 = 0,547 . 106 = 57,982 (g)
mHCl = 2 . 0,547 . 36,5 =39,931 (g)
C%(Na2CO3) =\(\frac{57,892}{200}\) . 100% = 28,946%
C%(HCl) = \(\frac{39,931}{120}\) . 100% = 33,28%
a) PTHH:\(CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\)\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+H_2O+CO_2\)
b) Ta có: \(n_{CaCO_3}=\frac{60}{100}=0,6\left(mol\right)\) \(\Rightarrow n_{CH_3COOH}=1,2mol\)
\(\Rightarrow m_{CH_3COOH}=1,2\cdot60=72\left(g\right)\) \(\Rightarrow m_{ddCH_3COOH}=\frac{72}{12\%}=600\left(g\right)\)
c) Theo PTHH: \(n_{CaCO_3}=n_{\left(CH_3COO\right)_2Ca}=n_{CO_2}=0,6mol\)
\(\Rightarrow\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Ca}=0,6\cdot158=94,8\left(g\right)\\m_{CO_2}=0,6\cdot44=26,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{CaCO_3}+m_{ddCH_3COOH}-m_{CO_2}=633,6\left(g\right)\)
\(\Rightarrow C\%_{dd\left(CH_3COO\right)_2Ca}=\frac{94,8}{633,6}\cdot100\approx14,96\%\)
d) Ta có: \(n_{CO_2}=n_{BaCO_3}=0,6mol\)
\(\Rightarrow m_{BaCO_3}=0,6\cdot197=118,2\left(g\right)\)
Bài 1: \(n_{H_2SO_4}=\frac{9}{49}\left(mol\right)\)
H2SO4 + 2KOH -> K2SO4 + 2H2O
=> nKOH= 2nH2SO4 = \(\frac{18}{49}\left(mol\right)\)
=> Vdd KOH = \(\frac{18}{49}:\frac{2}{1000}=\frac{9000}{49}\left(ml\right)\)
b) nK2SO4 = nH2SO4 = \(\frac{9}{49}\left(mol\right)\)
=> mK2SO4= \(\frac{9}{49}\cdot174=\frac{1566}{49}\left(g\right)\)
mdd KOH = \(\frac{9000}{49}\cdot1,12=\frac{1440}{7}\left(g\right)\)
c) \(\%m_{K_2SO_4}=\frac{1566}{49}:\left(200+\frac{1440}{7}\right)\cdot100\%\approx7,87\%\)
bài 2: nNa2CO3 = 0,05 (mol)
PTHH:
Na2CO3 + 2HCl -> 2NaCl + H2O + CO2
=> nHCl = n NaCl = 2nNa2CO3 = 0,1 (mol)
=> mNaCl= 0,1 . 58,5 = 5,85 (g)
b) nCO2 = nNa2CO3 = 0,05 (mol)
=> mCO2 = 0,05 . 44 = 2,2 (g)
mdd HCl = 0,1 . 36,5 :20% = 18,25 (g)
=> %mNaCl = \(\frac{5,85}{53+18,25-2,2}\approx8,47\%\)
KCl + AgNO3---> KNO3 + AgCl
x------->x---------------------->x
KBr+ AgNO3---> KNO3 + AgBr
y-------->y--------------------->y
170(x+y) = 143,5x + 188y => x/y=36/53
Tự tính
PTHH: \(2AgNO_3+CaCl_2\rightarrow Ca\left(NO_3\right)_2+2AgCl\downarrow\)
Ta có: \(n_{AgNO_3}=\dfrac{1,7}{170}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{AgCl}=0,01\left(mol\right)\\n_{CaCl_2}=n_{Ca\left(NO_3\right)_2}=0,005\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCl_2}=0,005\cdot111=0,555\left(g\right)\\m_{AgCl}=0,01\cdot143,5=1,435\left(g\right)\\C_{M_{Ca\left(NO_3\right)_2}}=\dfrac{0,005}{0,07+0,03}=0,05\left(M\right)\end{matrix}\right.\)