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a) \(Pt:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b) \(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(Theopt:n_{H_2}=\dfrac{3}{2}n_{Al}=0,3mol\)
\(\Rightarrow V_{H_2}=0,3.22,4=6,72lít\)
c) \(Theopt:n_{HCl}=3n_{Al}=0,6mol\)
\(\Rightarrow C_Mdd_{HCl}=\dfrac{0,6}{0,2}=3M\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
\(a.Mg+2HCl->MgCl_2+H_2\\ b.n_{Mg}=\dfrac{2,4}{24}=0,1mol\\ n_{HCl}=\dfrac{109,5.10\%}{36,5}=0,3mol\\ n_{Mg}:1< n_{HCl}:2\\ Mg:hết\\ m_{ddsau}=2,4+109,5-2.0,1=111,7g\\ C\%_{HCl\left(dư\right)}=\dfrac{36,5.0,1}{111,7}.100\%=3,27\%\\ C\%_{MgCl_2}=\dfrac{95.0,1}{111,7}.100\%=8,50\%\)
nH2SO4 = 49/98 = 0.5 (mol)
CMH2SO4 = 0.5/0.15 = 3.3 (M)
Zn + H2SO4 => ZnSO4 + H2
...........0.5.............0.5.........0.5
VH2 = 0.5 * 22.4 = 11.2 (l)
CMZnSO4 = 0.5 / 0.15 = 10/3 (M)
C%ZnSO4 = CM*M / 10D = 10/3 * 161 / 10 * 1.25 = 42.9 %
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)
c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)
d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\\
C\%_{HCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%
nZn=0,1mol
nH2SO4=0,2.0,2=0,04mol
PTHH: Zn+H2SO4=>ZnSO4+H2
0,1:0,04 => nZn dư
p/ư: 0,04<-0,04--->0,04--->0,04
=> Vh2=0,04.22,4=0,896lit
mZnSO4=0,04.161=6,44g
theo định luật bảo toàn khói lựng
mZnSO4=6,5+0,04.98-0,04.2=10,34g
=> C%=6,44:10,34.100=62,3%
mddZnSO4=