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a) $2Al + 6HCl \to 2AlCl_3 + 3H_2$
b) n Al = 8,1/27 = 0,3(mol)
Theo PTHH :
n H2 = 3/2 n Al = 0,45(mol)
V H2 = 0,45.22,4 = 10,08(lít)
c) n AlCl3 = n Al = 0,3(mol)
m AlCl3 = 0,3.133,5 = 40,05(gam)
d) n HCl = 3n Al = 0,9(mol)
m dd HCl = 0,9.36,5/7,3% = 450(gam)
Sau phản ứng :
m dd = 8,1 + 450 -0,45.2 = 457,2(gam)
C% AlCl3 = 40,05/457,2 .100% = 8,76%
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
mH2SO4= \(\dfrac{300.7,35}{100}=22,05g\)
nH2SO4= \(\dfrac{22,05}{98}=0,225 mol\)
mHCl= \(\dfrac{200.7,3}{100}=14,6g\)
nHCl= \(\dfrac{14,6}{36,5}=0,4mol\)
H2SO4 + 2HCl → 2H2O + Cl2 ↑+ SO2 ↑
n trước pư 0,225 0,4
n pư 0,2 ← 0,4 → 0,4 → 0,2 → 0,2 mol
n sau pư dư 0,025 hết
a) mCl2= 0,2. 71= 14,2g
mSO2= 64. 0,2= 12,8g
mH2O= 18. 0,4=7,2g
mdd sau pư= 300 +200 -14,2 -12,8= 473g
C%dd H2O= \(\dfrac{7,2.100}{473}=1,52\)%
b) Mg + 2H2O → Mg(OH)2 + H2 ↑
x → 2x → x → x
Fe + 2H2O → Fe(OH)2 + H2↑
y → 2y → y → y
Gọi x,y lần lượt là số mol của Mg,Fe.
Ta có hệ phương trình:
24x + 56y = 8,7 x= \(\dfrac{5}{64}\)
⇒
2x + 2y = 0,4 y= \(\dfrac{39}{320}\)
VH2= 22,4. \((\dfrac{5}{64}+\dfrac{39}{320})\)= 4,48l
mhh MG(OH)2, Fe(OH)2= 8,7 +250 - 2.(\(\dfrac{5}{64}+\dfrac{39}{320}\)) = 2258,3g
mMg=24. \(\dfrac{5}{64}\)=1.875g
mFe= 8,7-1,875= 6,825g
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
Có nZn= 0,65/65=0,1(mol)
a,PTPƯ: Zn + 2HCl ---> ZnCl2 + H2
(mol) 0,1 ---> 0,05 ---> 0,1 ---> 0,1
b, Theo pt có mmuối= 0,1.136=13.6(g)
Lại có Vkhí=0,1.22,4= 2,24(l)
c, Theo pt có mHCl= 0,05.36,5=1,825(g)
=> C%=\(\dfrac{1,825}{200}\).100%=0,9125%
\(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\\ m_{H_2SO_4}=9,8\%.40=3,92\left(g\right)\\ n_{H_2SO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,02}{2}< \dfrac{0,04}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,02=0,03\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,02=0,01\left(mol\right)\end{matrix}\right.\)
\(\rightarrow V_{H_2}=0,03.22,4=0,672\left(l\right)\\ m_{dd}=0,54+40=40,54\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,01}{40,54}=8,43\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{\left(0,04-0,03\right).98}{40,54}=2,41\%\end{matrix}\right.\)
Fe+2HCl->FeCl2+H2
0,125--0,25---0,125-0,125
m HCl=9,125 g=>n HCl=\(\dfrac{9,125}{26,5}\)=0,25 mol
=>m Fe=0,125.56=7g
=>VH2=0,125.22,4=2,8l
=>C%FeCl2=\(\dfrac{0,125.127}{7+182,5-0,25}\).100=8,388%
Theo gt ta có: $n_{Al}=0,1(mol)$
a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$
b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$
c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$
d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$
$\Rightarrow \%C_{AlCl_3}=6,02\%$
`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`
`2/15` `0,4` `2/15` `0,2` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`n_[HCl]=[7,3.200]/[100.36,5]=0,4(mol)`
Có: `[0,2]/1 > [0,4]/6->Al` dư
`@V_[H_2]=0,2.22,4=4,48(l)`
`@m_[AlCl_3]=2/15.133,5=17,8(g)`
`@C%_[AlCl_3]=[17,8]/[5,4+200-0,2.2].100=8,68%`