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a) 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{200.12\%}{60}=0,4\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
0,4------->0,2------------------------->0,2
=> \(m_{Na_2CO_3}=0,2.106=21,2\left(g\right)\)
=> \(m_{dd.Na_2CO_3}=\dfrac{21,2.100}{50}=42,4\left(g\right)\)
c) \(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
a, \(n_{KOH}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PT: \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{KOH}=0,15\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\)
b, \(n_{Na_2CO_3}=0,2.0,5=0,1\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,1}{1}\), ta được Na2CO3 dư.
Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{CH_3COOH}=0,075\left(mol\right)\Rightarrow V_{CO_2}=0,075.22,4=1,68\left(l\right)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,2--------->0,4--------------->0,4------->0,2
=> VCO2 = 0,2.22,4 = 4,48 (l)
b) \(m_{dd.CH_3COOH}=\dfrac{0,4.60}{12\%}=200\left(g\right)\)
c) mdd sau pư = 21,2 + 200 - 0,2.44 = 212,4 (g)
=> \(C\%_{muối}=\dfrac{0,4.82}{212,4}.100\%=15,44\%\)
CH3COOH + NaOH => CH3COONa + H2O
500 ml dd = 0.5 l dd
mNaOH = 20x30/100 = 6 (g)
nNaOH = m/M = 6/40 = 0.15 (mol)
Theo phương trình => nCH3COOH = 0.15 (mol)
CM dd CH3COOH = n/V = 0.15/0.5 = 0.3M
2CH3COOH + Na2CO3 => 2CH3COONa + CO2 + H2O
nNa2CO3 = 0.5x0.2 = 0.1 (mol)
Theo phương trình ==> nCO2 = 0.1 (mol)
VCO2 = n x 22.4 = 0.1 x 22.4 = 2.24 (l)
a) \(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1-------->0,2------------->0,2
=> \(V_{dd.CH_3COOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
b) \(m_{CH_3COONa}=0,2.82=16,4\left(g\right)\)
a)
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1--------->0,2------------->0,2------------>0,1
=> mCH3COOH = 0,2.60 = 12 (g)
\(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
b) \(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{0,2.80}{100}=0,16\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
0,16------------------------------------->0,16
=> \(m_{CH_3COOC_2H_5}=0,16.88=14,08\left(g\right)\)
Câu 9 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
a) Pt : \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,4 0,2 0,2
→ \(V_{H2\left(dtkc\right)}=0,2.22,4=4,48\left(l\right)\)
b) \(V_{ddCH3COOH}=\dfrac{0,4}{2}=0,2\left(l\right)\)
c) \(m_{\left(CH3COO\right)2Mg}=0,2.101=20,2\left(g\right)\)
d) Pt : \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,4 0,4
\(C_{MddKOH}=\dfrac{0,4}{0,2}=2\left(M\right)\)
Chúc bạn học tốt
a: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
b: \(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
=>\(n_{CH_3COO_H}=0,2\left(mol\right)\)
500ml=0,5(lít)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0.2}{0.5}=0,4\)