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a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
Pt: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(n_{\left(CH_3COO\right)_2Zn}=\dfrac{14,2}{183}\approx0.077mol\)
Theo pt: nH2 = n(CH3COO)2Zn = 0,077mol
=> VH2 = 1,7248l
b) Theo pt: nCH3COOH = 2n(CH3COO)2Zn = 0,154 mol
=> CMCH3COOH = 0,154 : 0,25 = 0,616M
Câu 5 :
\(n_{K2SO3}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
Pt : \(K_2SO_3+2HCl\rightarrow2KCl+SO_2+H_2O|\)
1 2 2 1 1
0,1 0,2 0,2 0,2
a) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(m_{ddHCl}=\dfrac{7,3.100}{8}=91,25\left(g\right)\)
b) \(n_{KCl}=\dfrac{0,2.2}{2}=0,2\left(mol\right)\)
⇒ \(m_{KCl}=0,2.74,5=14,9\left(g\right)\)
\(m_{ddspu}=15,8+91,25-\left(0,1.64\right)=100,65\left(g\right)\)
\(C_{KCl}=\dfrac{14,9.100}{100,65}=14,80\)0/0
c) \(n_{SO2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
\(V_{SO2\left(dktc\right)}=0,1.22,4=2,24\left(l\right)\)
Chúc bạn học tốt
\(m_{CH_3COOH}=150.12\%=18g\)
\(n_{CH_3COOH}=\dfrac{18}{60}=0,3mol\)
\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
0,3 0,15 0,3 0,15 ( mol )
\(m_{ddNa_2CO_3}=\left(0,15.106\right):10,6\%=150g\)
\(V_{CO_2}=0,15.22,4=3,36l\)
\(m_{CH_3COONa}=0,3.82=24,6g\)
\(m_{ddspứ}=150+150-0,15.44=293,4g\)
\(C\%_{CH_3COONa}=\dfrac{24,6}{293,4}.100=8,28\%\)
\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
0,6 0,3 0,6 0,3
=> VCO2 = 0,3.22,4 = 6,72 (l)
\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)
=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)
mCO2 = 0,3.44 = 13,2 (g)
\(m_{dd}=150+150-13,2=286,8\left(g\right)\)
\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
\(n_{CaCO_3}=\dfrac{6}{100}=0,06mol\)
\(n_{CH_3COOH}=\dfrac{200}{60}=3,33mol\)
\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
3,33 > 0,06 ( mol )
0,06 0,06 0,06 ( mol )
\(V_{CO_2}=0,06.22,4=1,344l\)
\(m_{\left(CH_3COO\right)_2Ca}=0,06.158=9,48g\)
\(m_{ddspứ}=200+6-0,06.12=205,28g\)
\(C\%_{\left(CH_3COO\right)_2Ca}=\dfrac{9,48}{205,28}.100=4,61\%\)
\(n_{CaCO_3}=\dfrac{6}{100}=0,06\left(mol\right)\\
n_{CH_3C\text{OO}H}=\dfrac{200}{60}=3,3\left(G\right)\\
pthh:CaCO_3+2CH_3C\text{OO}H\rightarrow Ca\left(CH_3C\text{OO}\right)_2+H_2O+CO_2\)
LTL : \(\dfrac{0,06}{1}< \dfrac{3,3}{2}\)
=> CaCO3 hết
theo pthh : \(n_{CO_2}=n_{CaCO_3}=0,06\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,06.22,4=1,344\left(l\right)\)
\(\Rightarrow C\%=\dfrac{6}{200}.100\%=3\%\dfrac{\dfrac{ }{ }C\dfrac{ }{ }\dfrac{ }{ }\dfrac{ }{ }\dfrac{ }{ }}{ }\%\)
Bài 5
Fe + 2CH3COOH \(\rightarrow\) (CH3COO)2Fe + H2(1)
nCH3COOH = \(\dfrac{4,5}{60}=0,075mol\)
a) THeo pt: n(CH3COO)2Fe = \(\dfrac{1}{2}.nCH_3COOH=0,0375mol\)
=> m = 6,525g
c) Theo pt (1) nH2 = 1/2nCH3COOH = 0,0375 mol
2H2 + O2 \(\xrightarrow[]{t^o}\) 2H2O
Theo pt: nO2 = 0,5nH2 = 0,01875mol
=> VO2 = 0,42 lít
=> Vkk = 0,42.5 = 2,1 lít
mdd sau p ứng bạn tính sau v