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Câu 1:
a) CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
CaO + 2HCl --> CaCl2 + H2O
b)
\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_____0,4<---------0,8<-----------------0,4
=> mCaCO3 = 0,4.100 = 40(g)
=> mCaO = 62,4 - 40 = 22,4 (g)
c) \(n_{CaO}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
CaO + 2HCl --> CaCl2 + H2O
_0,4-->0,8
=> nHCl = 0,8 + 0,8 = 1,6(mol)
=> \(C_{M\left(HCl\right)}=\dfrac{1,6}{0,25}=6,4M\)
Câu 1:
\(a,CaO+2HCl\to CaCl_2+H_2O\\ CaCO_3+2HCl\to CaCl_2+H_2O+CO_2\uparrow\\ b,n_{CO_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ \Rightarrow n_{CaCO_3}=0,4(mol)\\ \Rightarrow m_{CaCO_3}=0,4.100=40(g)\\ \Rightarrow m_{CaO}=62,4-40=22,4(g)\\ c,n_{CaO}=\dfrac{22,4}{56}=0,4(mol)\\ \Rightarrow \Sigma n_{HCl}=0,4.2+0,4.2=1,6(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,25}=6,4M\)
Câu 2: Đề thiếu
Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
a)
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = \dfrac{672}{1000.22,4} = 0,03(mol)$
$n_{HCl} = 2n_{CO_2} = 0,06(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,06}{0,2} = 0,3M$
b)
$\%m_{CaCO_3} = \dfrac{0,03.100}{5}.100\% = 60\%$
$\%m_{CaSO_4}= 100\% -60\% = 40\%$
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(\Rightarrow\left\{{}\begin{matrix}84\cdot n_{MgCO_3}+100\cdot n_{CaCO_3}=18,4\\n_{MgCO_3}+n_{CaCO_3}=n_{CO_2}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{MgCO_3}=0,1mol\\n_{CaCO_3}=0,1mol\end{matrix}\right.\)
\(\%m_{CaCO_3}=\dfrac{0,1\cdot100}{18,4}\cdot100\%=54,35\%\)
\(\%m_{MgCO_3}=100\%-54,35\%=45,65\%\)
a.
Gọi \(\left\{{}\begin{matrix}n_{CaCO_3}=x\left(mol\right)\\n_{MgCO_3}=y\left(mol\right)\end{matrix}\right.\)
Theo đề có hệ phương trình: \(\left\{{}\begin{matrix}100x+84y=4,68\\x+y=\dfrac{1,2395}{24,79}=0,05\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,03\\y=0,02\end{matrix}\right.\)
\(m_{CaCO_3}=0,03.100=3\left(g\right),m_{MgCO_3}=0,02.84=1,68\left(g\right)\)
b.
\(CM_{HCl}=\dfrac{2\left(x+y\right)}{0,25}=0,4\left(M\right)\)
\(n_{CO_2}=\dfrac{1,2395}{24,79}=0,05\left(mol\right)\)
PTHH:
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
x 2x x x x
\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\)
y 2y y y y
Có hệ PT:
\(\left\{{}\begin{matrix}100x+84y=4,68\\x+y=0,05\end{matrix}\right.\)
\(\Leftrightarrow x=0,03;y=0,02\)
\(a,m_{CaCO_3}=0,03.100=3\left(g\right)\)
\(m_{MgCO_3}=4,68-3=1,68\left(g\right)\)
b, \(C_{M\left(HCl\right)}=\dfrac{0,1}{0,25}=\dfrac{2}{5}\left(M\right)\)
\(C_{M\left(CaCl_2\right)}=\dfrac{0,03}{0,25}=\dfrac{3}{25}\left(M\right)\)
\(C_{M\left(MgCl_2\right)}=\dfrac{0,02}{0,25}=\dfrac{2}{25}\left(M\right)\)