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\(a.Ca+H_2O\rightarrow Ca\left(OH\right)_2+H_2\\ CaO+H_2O\rightarrow Ca\left(OH\right)_2\\ b.n_{H_2}=n_{Ca}=0,1\left(mol\right)\\ \Rightarrow m_{Ca}=0,1.40=4\left(g\right)\\ \Rightarrow m_{CaO}=9,6-4=5,6\left(g\right)\\ c.n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ \Sigma n_{Ca\left(OH\right)_2}=n_{Ca}+n_{CaO}=0,1+0,1=0,2\left(mol\right)\\ \Rightarrow m_{Ca\left(OH\right)_2}=0,2.74=14,8\left(g\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ pthh:Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\)
0,1 0,1 0,1
\(CaO+H_2O\rightarrow Ca\left(OH\right)_2\)(2)
\(m_{Ca}=0,1.40=4\left(g\right)\\
m_{CaO}=9,6-4=5,6\left(g\right)\)
\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
n_{Ca\left(OH\right)_2\left(2\right)}=n_{CaO}=0,1\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=\left(0,1+0,1\right).74=14,8\left(g\right)\)
a) nH2=0,05(mol)
Na + H2O -> NaOH + 1/2 H2
0,1_______________0,05(mol)
Na2O + H2O -> 2 NaOH
b) => mNa=0,1.23=2,3(g)
=>nNa2O= 14,7 - 2,3= 12,4(g)
\(n_{Na}=\dfrac{m}{M}=\dfrac{3,45}{23}=0,15\left(mol\right)\\ n_{Na_2O}=\dfrac{m}{M}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ PTHH:2Na+2H_2O->2NaOH+H_2\left(1\right)\)
tỉ lệ 2 : 2 : 2 ; 1
n(mol) 0,15---->0,15------->0,15----->0,075
\(m_{NaOH\left(1\right)}=n\cdot M=0,15\cdot40=6\left(g\right)\)
\(PTHH:Na_2O+H_2O->2NaOH\left(2\right)\)
tỉ lệ 1 ; 1 ; 2
n(mol) 0,1----->0,1------->0,2
\(m_{NaOH\left(2\right)}=n\cdot M=0,2\cdot40=8\left(g\right)\\ =>m_{NaOH}=m_{NaOH\left(1\right)}+m_{NaOH\left(2\right)}=6+8=14\left(g\right)\)
\(n_{H_2O}=\dfrac{14,4}{18}=0,8mol\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,8 0,8 0,8 ( mol )
\(m_{Na}=0,8.23=18,4g\)
\(m_{NaOH}=0,8.40=32g\)
Số mol của nước là:
nH2O=14,4/18=0,8(mol)
PTHH: Na+H2O→NaOH+1/2H2
0,8 0,8 0,8 0,4 ( mol)
a) Thể tích khí Hidro tạo thành(ĐKTC) là:
VH2=0,4*22,4= 8,96(l)
b) Khối lượng Natri là:
mNa=0,8*23 =18,4(g)
Khối lượng Bazơ tạo thành sau phản ứng là:
mNaOH=0,8*40=32(g)
Bài 2 :
\(n_{Fe_3O_4} = \dfrac{52,2}{232} = 0,225(mol)\\ Fe_3O_4 + 8HCl \to 2FeCl_3 + FeCl_2 + 4H_2O\\ n_{FeCl_2} = n_{Fe_3O_4} = 0,225(mol) \Rightarrow m_{FeCl_2} = 0,225.127 = 28,575(gam)\\ n_{FeCl_3} = 2n_{Fe_3O_4} = 0,45(mol) \Rightarrow m_{FeCl_3} = 0,45.162,5 = 73,125(gam)\)
Bài 3 :
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,1(mol)\\ Fe_3O_4 + 4H_2SO_4 \to Fe_2(SO_4)_3 + FeSO_4 + 4H_2O\\ n_{FeSO_4} = n_{Fe_2(SO_4)_3} = n_{Fe_3O_4} = 0,1(mol)\\ \Rightarrow m_{FeSO_4} = 0,1.152 = 15,2(gam)\\ m_{Fe_2(SO_4)_3} = 0,1.400 = 40(gam)\)
a. PTHH 1 : Ba + H2O -> Ba(OH)2 + H2
0,025 0,025
PTHH 2 : BaO + H2O -> Ba(OH)2
\(n_{H_2}=\dfrac{0.56}{22,4}=0,025\left(mol\right)\)
\(m_{Ba}=0,025.137=3,425\left(g\right)\)
\(m_{BaO}=6,485-3,425=3,06\left(g\right)\)
\(n_{BaO}=\dfrac{3.06}{153}=0,02\left(mol\right)\)
b. \(\%m_{BaO}=\dfrac{3,06}{6,485}.100=47,2\%\)
\(\%m_{Ba}=100\%-47,2\%=52,8\%\)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(2Zn+O_2\underrightarrow{^{^{t^0}}}2ZnO\)
LTL : \(\dfrac{0.2}{2}< \dfrac{0.4}{1}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.4-0.1\right)\cdot32=9.6\left(g\right)\)
\(m_{ZnO}=0.2\cdot81=16.2\left(g\right)\)
2Na+2H2O->2NaOH+H2
x-------------------x----------0,5x mol
Ba+2H2O->Ba(OH)2+H2
y---------------------y----------y mol
aTa có :)\(\left\{{}\begin{matrix}23x+137y=2,06\\0,5x+y=0,025\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,03\\y=0,01\end{matrix}\right.\)
=>mbazo=0,03.40+0,01.171=2,91g
=>m Na=0,03.23=0,69g
=>m Ba=0,01.137=1,27g
a)\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,2 0,1
\(NaO+H_2O\rightarrow2NaOH\)
b)\(m_{Na}=0,2\cdot23=4,6g\)
\(m_{NaO}=m_{hh}-m_{Na}=40,5-4,6=35,9g\)
c)\(n_{NaO}=\dfrac{35,9}{39}=0,92mol\Rightarrow n_{NaOH}=2n_{NaO}=1,84mol\)
\(\Rightarrow m_{NaOH}=1,84\cdot40=73,6g\)
Na2O mới đúng chứ