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\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ n_{Zn} = \dfrac{13}{65} = 0,2 < n_{H_2SO_4} = \dfrac{200.24,5\%}{98} = 0,5 \to H_2SO_4\ dư\\ n_{H_2SO_4\ pư} =n_{Zn} = 0,2(mol)\\ \Rightarrow m_{H_2SO_4\ dư} = (0,5 - 0,2).98 = 29,4(gam)\\ c) n_{FeSO_4} = n_{H_2} = n_{Zn} = 0,2(mol)\\ m_{FeSO_4} = 0,2.152 = 30,4(gam)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\)
\(nAl=\dfrac{8,1}{27}=0,3\left(mol\right)\)
\(nHCl=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
2 6 2 3 (mol)
0,2 0,6 0,2 0,3 (mol)
LTL : 0,3 / 2 > 0,6/6
=> Al dư sau pứ , HCl đủ vs pứ
\(mAl_{\left(dư\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\)
\(mAlCl_3=0,2.98=19,6\left(g\right)\)
\(H_2+CuO\rightarrow Cu+H_2O\)
1 1 1 1 (mol)
0,3 0,3 0,3 0,3 (mol)
=> \(mCu=0,3.64=19,2\left(g\right)\)
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\\
n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\
pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
\(LTL:\dfrac{0,3}{2}>\dfrac{0,6}{6}\)
=> Al dư HCl hết
theo pthh : \(n_{Al\left(p\text{ư}\right)}=\dfrac{1}{3}n_{HCl}=0,2\left(mol\right)\\ m_{Al\left(d\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\)
theo pthh : \(n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,1\left(mol\right)\\
m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
theo pthh : \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\)
pthh: \(CuO+H_2\underrightarrow{t^o}H_2O+Cu\)
0,3 0,3
\(m_{Cu}=0,3.64=19,2\)
a. PTHH: 2Al(OH)3 + 3H2SO4 ---> Al2(SO4)3 + 6H2O
b. Ta có: \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)
Ta thấy: \(\dfrac{0,75}{2}>\dfrac{0,5}{3}\)
Vậy \(Al\left(OH\right)_3\) dư.
\(m_{dư}=0,75.78-98.0,5=9,5\left(g\right)\)
c. Theo PT: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}.n_{H_2SO_4}=\dfrac{1}{3}.0,5=\dfrac{1}{6}\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{6}.342=57\left(g\right)\)
a, \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right);n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)
PTHH: 2Al(OH)3 + 3H2SO4 → Al2(SO4)3 + 6H2O
Mol: \(\dfrac{1}{3}\) 0,5 \(\dfrac{1}{6}\)
b, Ta có: \(\dfrac{0,75}{2}>\dfrac{0,5}{3}\) ⇒ Al(OH)3 dư, H2SO4 hết
⇒ \(m_{Al\left(OH\right)_3}=\left(0,75-\dfrac{1}{3}\right).78=32,5\left(g\right)\)
c, \(m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{6}.342=57\left(g\right)\)
Ta có: \(n_{Al\left(OH\right)_3}=\dfrac{58,5}{78}=0,75\left(mol\right)\)
a. PTHH: 2Al(OH)3 + 3H2SO4 ---> Al2(SO4)3 + 6H2O
b. Không có chất dư (hoặc có thể bn cho sai 49(g) dung dịch là 49(g) H2SO4)
c. Theo PT: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.n_{Al\left(OH\right)_3}=\dfrac{1}{2}.0,75=0,375\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=0,375.342=128,25\left(g\right)\)
a)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
b)
Ta có :
\(n_{Fe} = \dfrac{8,4}{56} = 0,15(mol)\\ n_{O_2} = \dfrac{96}{32} = 3(mol)\)
Ta thấy : \(\dfrac{n_{Fe}}{3} = 0,05 < \dfrac{n_{O_2}}{2} = 1,5\) do đó O2 dư.
Theo PTHH :
\(n_{O_2\ pư} = \dfrac{2}{3}n_{Fe} = 0,1(mol)\\ \Rightarrow n_{O_2\ dư} = 3 - 0,1 = 2,9(mol)\\ \Rightarrow m_{O_2\ dư} = 92,8(gam)\)
c)
\(n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,05(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,05.232 = 11,6(gam)\)
\(a)PTHH:FeCl_3+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
mol 1 2 1
mol
\(b)\)Số mol \(FeCl_3\) là: \(n_{FeCl_3}=\dfrac{m_{FeCl_3}}{M_{FeCl_3}}=\dfrac{8,4}{162,5}=0,052\left(mol\right)\)
Số mol \(O_2\) là: \(n_{O_2}=\dfrac{m_{O_2}}{M_{O_2}}=\dfrac{96}{32}=3\left(mol\right)\)
Lập tỉ lệ: \(\dfrac{1}{0,052}>\dfrac{2}{3}\Rightarrow FeCl_3dư\)
Số mol \(FeCl_3\) phản ứng là:
Từ PTHH\(\Rightarrow\) \(n_{FeCl_3}=\dfrac{0,052\times3}{3}=0,035\left(mol\right)\)
Số mol \(FeCl_3\) dư là: \(n_{FeCl_3dư}=n_{FeCl_3đầu}-n_{FeCl_3p/ứng}=0,052-0,035=0,018\left(mol\right)\)
Khối lượng \(FeCl_3\) dư là: \(m_{FeCl_3dư}=n_{FeCl_3dư}\times M_{FeCl_3}=0,018\times162,5=2,925\left(g\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{25,55}{36,5}=0,7\left(mol\right)\\a. 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b.Vì:\dfrac{0,2}{2}< \dfrac{0,7}{6}\\ \Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,7-\dfrac{6}{2}.0,2=0,1\left(mol\right)\\ n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ m_{H_2}=0,3.2=0,6\left(g\right)\\ m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\\ m_{AlCl_3}=133,5.0,2=26,7\left(g\right)\)
\(a,n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
b, LTL: \(\dfrac{0,4}{4}>\dfrac{0,6}{3}\) => O2 dư
Theo pthh: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{3}{4}n_{Al}=\dfrac{3}{4}.0,4=0,3\left(mol\right)\\n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\end{matrix}\right.\)
=> VO2 (dư) = (0,6 - 0,3).22,4 = 6,72 (l)
c, mAl2O3 = 0,2.102 = 20,4 (g)
\(n_{Al}=\dfrac{10,8}{27}=0,4mol\)
\(n_{O_2}=\dfrac{13,44}{22,4}=0,6mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
Xét: \(\dfrac{0,4}{4}\) < \(\dfrac{0,6}{3}\) ( mol )
0,4 0,3 0,2 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,6-0,3\right).32=9,6g\)
\(m_{Al_2O_3}=0,2.102=20,4g\)
\(n_K=\dfrac{3,8}{39}=\dfrac{19}{195}mol\)
\(n_{H_2O}=\dfrac{101,8}{18}=\dfrac{509}{90}mol\)
\(2K+2H_2O\rightarrow2KOH+H_2\)
19/195 < 509/90 ( mol )
19/195 19/195 19/195 ( mol )
Chất dư là H2O
\(m_{H_2O\left(dư\right)}=\left(\dfrac{509}{90}-\dfrac{19}{195}\right).18\approx100,04g\)
\(m_{KOH}=\dfrac{19}{195}.56\approx5,45g\)
10 1,8 g nước :)?