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\(n_{H_2}=\dfrac{5,6}{22,4}=0,25(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\)
\(b,\) Đặt \(n_{Fe}=x(mol);n_{Al}=y(mol)\)
\(\Rightarrow 56x+27y=8,3(1)\)
Theo PTHH: \(x+1,5y=0,25(2)\)
\((1)(2)\Rightarrow x=y=0,1(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,1.56}{8,3}.100\%=67,47\%\\ \%_{Al}=100\%-67,47\%=32,53\%\)
a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b) Gọi x,y là số mol Al, Fe
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)
=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)
\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\); \(\%m_{Fe}=100-16,55=83,45\%\)
c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)
=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
a ----> 2a --------> a -----> a
Fe + 2HCl ---> FeCl2 + H2
b ---> 2b -------> b ------> b
Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\
pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
gọi số mol Zn là x , số mol Fe là y
=> 65x+56y=43,7
=> a+b=0,7
=>a=0,5 , b =0,2
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
a)
Mg + 2HCl --> MgCl2 + H2
b)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
0,3<-----------------0,3
=> mMg = 0,3.24 = 7,2 (g)
=> mAg = 10,4 - 7,2 = 3,2 (g)
c) \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{7,2}{10,4}.100\%=69,23\%\\\%m_{Ag}=\dfrac{3,2}{10,4}.100\%=30,77\%\end{matrix}\right.\)
1. \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
2. Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 9,2 (1)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(2\right)\)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{9,2}.100\%\approx70,65\%\\\%m_{Al}\approx29,35\%\end{matrix}\right.\)
3. Theo PT: \(\left\{{}\begin{matrix}n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnSO_4}=0,1.160=16\left(g\right)\\m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\end{matrix}\right.\)
1. \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
2. Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,7 (1)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=\dfrac{66}{235}\\y=-\dfrac{29}{1410}\end{matrix}\right.\)
Tới đây thì ra số mol âm, bạn xem lại đề nhé.
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PTHH: \(n_{Mg}=n_{H_2}=0,6\left(mol\right)\)
=> \(m_{Mg}=0,6.24=14,4\left(g\right)\)
=> \(m_{Cu}=50-14,4=35,6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%Mg=\dfrac{14,4}{50}.100=28,8\%\\\%Cu=\dfrac{35,6}{50}.100=71,2\%\end{matrix}\right.\)
\(n\)H2 =\(\dfrac{13,44}{22,4}\) =0,6(mol)
PTHH:
Mg +HCl →MgCl2 + H2
0,6 mol ←0,6 mol
a) \(m\)Mg =0,6. 24 =14,4(g)
\(m\)Cu= 50- 14,4= 35,6(g)
b)\(m\)%Mg= \(\dfrac{14,4}{50}\).100%= 28,8%
\(m\)%Cu=100%- 28,8%= 71,2%
a, Cu không tác dụng với dd HCl.
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(\Rightarrow m_{Cu}=19,4-13=6,4\left(g\right)\)
c, Ta có: \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{13}{19,4}.100\%\approx67,01\%\\\%m_{Cu}\approx32,99\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{Al}=\dfrac{2}{3}.0,02=\dfrac{1}{75}\left(mol\right)\\ b,\%m_{Al}=\dfrac{\dfrac{1}{75}.27}{30}.100=1,2\%\Rightarrow\%m_{Cu}=100\%-1,2\%=98,8\%\)