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1.
a )\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{H2}=\frac{5,6}{22,4}=0,25\left(mol\right)\)
\(n_{Zn}=n_{H2}=0,25\left(mol\right)\)
\(\rightarrow,m_{Zn}=0,25.65=16,25\left(g\right);m_{Cu}=30-16,25=13,75\left(g\right)\)
b)
\(\%m_{Zn}=\frac{16,25}{30}.100\%=54,17\%\)
\(\%m_{Cu}=100\%-54,17\%=45,83\%\)
c)
\(n_{HCl}=2n_{H2}=0,5\left(mol\right)\)
\(C\%_{HCl}=\frac{0,5.36,5}{200}.100\%=9,125\%\)
2.
a)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)\(m_{Fe}=0,15.65=8,4\left(g\right),m_{Ag}=15-8,4=6,6\left(g\right)\)
b)
\(\%m_{Fe}=\frac{8,4}{15}.100\%=56\%\)
\(\%m_{Ag}=100\%-56\%=44\%\)
c)
\(n_{HCl}=2n_{H2}=0,3\left(mol\right)\)
\(\rightarrow m_{dd_{HCL}}=\frac{0,3.36,5}{15,6\%}=70,19\left(g\right)\)
a, Ta có: 24nMg + 56nFe = 9,2 (g) (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BT e, có: 2nMg + 2nFe = 2nH2 = 0,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,15\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\%\approx39,13\%\\\%m_{Fe}\approx60,87\%\end{matrix}\right.\)
b, BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
a)
Gọi $n_{Zn} = a(mol) ; n_{Al} = b(mol) \Rightarrow 65a + 27b = 11,9(1)$
$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1; b = 0,2
$m_{Zn} = 0,1.65 = 6,5(gam)$
$m_{Al} = 0,2.27 = 5,4(gam)$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$C\%_{HCl} = \dfrac{0,8.36,5}{125}.100\% = 23,36\%$
a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)
mdd sau pứ = 5,1+250-0,15.2 = 254,8(g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)
\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)
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a)
$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + H_2O$
$2Fe + 6H_2SO_4 \to Fe_2(SO_4)_3 + 3SO_2 + 6H_2O$
b) n Cu =a (mol) ; n Fe = b(mol)
=> 64a + 56b = 12(1)
n SO2 = a + 1,5b = 5,6/22,4 = 0,25(2)
(1)(2) suy ra a = b = 0,1
%m Cu = 0,1.64/12 .100% = 53,33%
%m Fe = 100% -53,33% = 46,67%
c)
n CuSO4 = a = 0,1(mol)
n Fe2(SO4)3 = 0,5a = 0,05(mol)
m muối = 0,1.160 + 0,05.400 = 36(gam)
d) n H2SO4 = 2n SO2 = 0,5(mol)
V H2SO4 = 0,5/2 = 0,25(lít)
a) n Fe = a(mol) ; n Cu = b(mol)
=> 56a + 64b = 4,8(1)
n SO2 = 2,24/22,4 = 0,1(mol)
Bảo toàn e :
3n Fe + 2n Cu = 2n SO2
<=> 3a + 2b = 0,2(2)
Từ (1)(2) suy ra a = b = 0,04
%m Fe = 0,04.56/4,8 .100% = 46,67%
%m Cu = 100% -46,67% = 53,33%
b)
n KOH = 0,15
Ta có :
1 < n KOH / n SO2 = 0,15/0,1 = 1,5 < 2 nên muối sinh ra là Na2SO3(x mol) và NaHSO3(y mol)
2NaOH + SO2 $\to$ Na2SO3 + H2O
NaOH + SO2 $\to$ NaHSO3
Theo PTHH :
n SO2 = a + b = 0,1
n NaOH = 2a + b = 0,15
Suy ra a= 0,05 ; b = 0,05
m muối = 0,05.126 + 0,05.104 = 11,5 gam
Bài 2 :
- Gọi số mol Fe và Cu lần lượt là a, b mol
Ta có : mhh = mFe + mCu = 56a + 64b = 4,8
Bte : 3a + 2b = 0,2
=> a = b =0,04mol
a, Ta có : mFe =n.M = 2,24g ( 46,7% )
=> %Cu = 53,3%
b, Ta thấy sau phản ứng thu được K+, SO3-2 xmol, HSO3- y mol
BtS : x + y = 0,1
BTĐT : 2x + y = 0,15
=> x =y = 0,05 mol
=> mM = mK2SO3 + mKHSO3 = 13,9g
a,
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{H2}=\frac{5,6}{22,4}=0,25\left(mol\right)\)
\(n_{Zn}=n_{H2}=0,25\left(mol\right)\)
\(m_{Zn}=0,25.65=16,25\left(g\right)\)
\(m_{Cu}=30-16,25=13,75\left(g\right)\)
b)
\(\%m_{Zn}=\frac{16,25}{30}.100\%=54,17\%\)
\(\%m_{Cu}=100\%-54,17\%=45,83\%\)
c)
\(n_{HCl}=2n_{H2}=0,5\left(mol\right)\)
\(\Rightarrow CM_{HCl}=\frac{0,5.36,5}{200}.100\%=9,125\%\)