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\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
nH2=4,48/22,4=0,2(mol)
=>nFe=0,2(mol)=>mFe=0,2.56=11,2(g)
=>mFeO=18,4-11,2=7,2(g)
b)nH2SO4=nH2=0,2(mol)
=>mH2SO4 7%=0,2.98=19,6(g)
=>mH2SO4 =19,6:7%=280(g)
c)mFeSO4=0,2.152=30,4(g)
mdd sau pư=18,4+280-0,2.2=298(g)
=>C%FeSO4=\(\frac{30,4}{298}.100\%\)=10,2%
FeO + H2SO4\(\rightarrow\)FeSO4 + H2 (1)
CuO + H2SO4\(\rightarrow\)CuSO4 + H2 (2)
a;
\(m_{H_2SO_4}=100\dfrac{19,6}{100}=19,6\left(g\right)\)
Đặt \(n_{FeO}\)là a
\(n_{CuO}\)là b
Ta có hệ pt:
\(\left\{{}\begin{matrix}72a+80b=15,2\\98a+98b=19,6\end{matrix}\right.\)
Giải hệ pt ta có:
a=0,1;b=0,1
\(m_{FeO}=72.0,1=7,2\left(g\right)\)
\(m_{CuO}=0,1.80=8\left(g\right)\)
b;
Theo PTHH 1 và 2 ta có:
\(n_{FeO}=n_{FeSO_4}=0,1\left(mol\right)\)
\(n_{CuO}=n_{CúSO_4}=0,1\left(mol\right)\)
\(m_{FeSO_4}=154.0,1=15,4\left(g\right)\)
\(m_{CuSO_4}=162.0,1=16,2\left(g\right)\)
\(C\%\)dd FeSO4 là:\(\dfrac{15,4}{100+15,2-0,1.2}.100\%\approx13,4\%\)
C% dd CuSO4 là:\(\dfrac{16,2}{100+15,2-0,1.2}\approx14\%\)
a) PTHH: CuO + H2SO4 ---> CuSO4 + H2O
b)
n Cu = 1,6 / 80 = 0,02 mol
m H2SO4 = 20 . 100 / 100 = 20 g
=> n H2SO4 = 20 / 98 = 0,204 mol
TPT:
1 mol : 1 mol
0,02 mol : 0,204 mol
=> Tỉ lệ: 0,02/1 < 0,204/1
=> H2SO4 dư, tính toán theo CuO
m dd sau p/ư = m dd H2SO4 + m CuO = 100 + 1,6 = 101,6 g
TPT: n CuSO4 = n CuO = 0,02 mol
=> m CuSO4 = 0,02 . 160 = 3,2 g
=> C% CuSO4 = 3,2 / 101,6 . 100% = 3,15%
n H2SO4 dư = 0,204 - 0,02 = 0,182 mol
=> m H2SO4 dư = 0,182 . 98 =17,836 g
=> C% H2SO4 = 17,836 / 101,6 . 100% = 17,83%
1.
\(PTHH:2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
\(n_{Mg}=\frac{7,2}{24}=0,3\left(mol\right)\)
\(m_{CH3COOH}=\frac{120.20}{100}=24\left(g\right)\Rightarrow n_{CH3COOH}=0,4\left(mol\right)\)
Theo PT:
\(n_{\left(CH3COO\right)2Mg}=\frac{1}{2}n_{CH3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{\left(CH3COO\right)2Mg}=28,4\left(g\right)\)
\(\Rightarrow m_{dd_{spu}}=7,2+120-0,4=126,8\left(g\right)\)
\(\Rightarrow C\%_{CH3COOMg}=22,3\%\)
2.
\(PTHH:CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Ta có :
\(m_{CH3COH}=\frac{15.120}{100}=18\left(g\right)\Rightarrow n_{CH3COOH}=0,3\left(mol\right)\)
\(m_{NaOH}=\frac{20.100}{100}=20g\left(g\right)\)
\(\Rightarrow n_{NaOH}=0,5\left(mol\right)\)
Theo PT thì NaOH dư
\(n_{CH3COONa}=n_{CH3COOH}=0,3\left(mol\right)\)
\(\Rightarrow m_{CH3COONa}=24,6\left(g\right)\)
\(m_{dd\left(spu\right)}=120+100=220\left(g\right)\)
\(\Rightarrow C\%_{CH3COONa}=11,2\%\)
3.
\(n_{CaO}=\frac{14}{56}=0,25\left(mol\right)\)
\(m_{CH3COOH}=\frac{200.18}{100}=36\left(g\right)\)
\(\Rightarrow n_{CH3COOH}=\frac{36}{60}=0,6\left(mol\right)\)
\(PTHH:2CH_3COOH+CaO\rightarrow\left(CH_3COO\right)_2Ca+H_2O\)
Lập tỉ lệ: \(\frac{0,25}{1}< \frac{0,6}{2}\)
\(\Rightarrow\) CaO hết. CH3COOH dư
\(n_{CH3COOH_{dư}}=0,6-0,25.2=0,1\left(mol\right)\)
\(m_{dd\left(thu.duoc\right)}=14+200=214\left(g\right)\)
\(C\%_{\left(CH3COO\right)2Na}=\frac{0,25.158}{214}.100\%=18,46\%\)
\(C\%_{CH3COOH_{dư}}=\frac{0,1.60}{214}.100\%=2,8\%\)
4.
\(m_{Na2CO3}=\frac{42,4.10}{100}=4,24\left(g\right)\)
\(n_{Na2CO3}=\frac{4,24}{106}=0,04\left(mol\right)\)
\(n_{CO2}=\frac{0,448}{22,4}=0,02\left(mol\right)\)
\(PTHH:2CH_2COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\)
_______0,04 ___________ 0,02 ____________ 0,04 __________ 0,02
Sau phản ứng Na2CO3 dư.
\(n_{Na2CO3_{dư}}=0,04-0,02=0,02\left(mol\right)\)
\(m_{dd\left(CH3COOH\right)}=\frac{2,4.100}{5}.100\%=48\left(g\right)\)
\(m_{dd\left(Spu\right)}=m_{dd\left(Na2CO3\right)}+m_{dd_{Axit}}-m_{CO2}\)
\(=42,4+48-0,02.44=89,52\left(g\right)\)
\(m_{CH3COOH}=0,04.60=2,4\left(g\right)\)
\(C\%_{Na2CO3\left(dư\right)}=\frac{0,02.106}{89,52}.100\%=2,37\%\)
\(C\%_{CH3COONa}=\frac{0,04.82}{89,52}.100\%=3,66\%\)
Theo đề bài ta có : ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol){VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol)
nFe = 1,68/56 = 0,03 mol
a) Ta có PTHH :
2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1mol......0,05mol
=> CMH2SO4 = 0,05/0,05=1(M)
nH2SO4 =0,4 (mol)
nCuO = 0,2 (mol)
CuO + H2So4 -> CuSO4 + H2O
0,2........0,2 0,2 (mol)
H2SO4 dư 0,2 mol
\(C\%_{H2SO\text{4}}=\frac{0,2.98}{16+200}.100\%=9,\left(074\right)\%\)
C%CuSO4 = \(\frac{0,2.160}{16+200}.100\%=14,\left(814\right)\%\)
a) PTHH: Na2O + H20 -> 2NaOH
số mol Na20 = 0,25 (mol)
=> số mol NaOH = 0,5 mol.
Nôngd độ mol NaOH = 0,5 / 0,5 = 1 M
b) PTHH: H2SO4 + 2NaOH -> Na2SO4 + 2H2O
số mol H2SO4 = 1/2 số mol NaOH = 0,25 mol
C% H2SO4 = mH2SO4 / m ddH2SO4 . 100%
=> m ddH2SO4= 122,5 g
D=m/V => V= 107,5 ml
Số mol Na2O = 15,5:62 = 0,25 mol
a) Khi cho Na2O xảy ra phản ứng, tạo thành phản ứng dung dịch có chất tan là NaOH.
Na2O + H2O → 2NaOH
Phản ứng: 0,25 → 0,05 (mol)
500 ml = = 0,5 lít; CM, NaOH =
= 1M.
b) Phương trình phản ứng trung hòa dung dịch:
2NaOH + H2SO4 → Na2SO4 + 2H2O
Phản ứng: 0, 5 → 0,25 0,25 (mol)
mH2SO4 = 0,25x98 = 24,5 g
mdd H2SO4 = = 122,5 g
mdd, ml = =
≈ 107,5 ml
mHCl=(7,3*300)/100=21,9 g =>nHCl=0,6 mol
mH2SO4=(100*19,6)/100=19,6g =>nH2SO4=0,2 mol
PT HCl+NaOH-> NaCl+ H2O
mol 0,6 0,6 0,6
2NaOH+ H2SO4->Na2SO4+ H2O
mol 0,4 0,2 0,2
m NaOH=(0,4+0,6)*40=40g =>mdd NaOH=(40*100)/5=800g
C%NaCl=(0,6*58,5*100%)/(300+800+100)=2,925%
C%Na2SO4=(0,2*142*100%)/(300+800+100)=2,367%