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\(n_{Br_2}=\dfrac{8}{160}=0.05\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(0.05......0.05\)
\(V_{C_2H_4}=0.05\cdot22.4=1.12\left(l\right)\)
\(V_{CH_4}=20-1.12=18.88\left(l\right)\left(mol\right)\)
\(\%V_{C_2H_4}=\dfrac{1.12}{20}\cdot100\%=5.6\%\)
\(\%V_{CH_4}=100-5.6=94.4\%\)
Ta có: m dd Br2 tăng = mC2H4 = 2,8 (g)
\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)
⇒ m hh = mCH4 + mC2H4 = 0,05.16 + 0,1.28 = 3,6 (g)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<--0,05
=> \(V_{C_2H_4}=0,05.22,4=1,12\left(l\right)\)
=> \(V_{CH_4}=4,48-1,12=3,36\left(l\right)\)
b) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{1,12}{4,48}.100\%=25\%\\\%V_{CH_4}=\dfrac{3,36}{4,48}.100\%=75\%\end{matrix}\right.\)
\(n_{hh}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{Br_2}=\dfrac{48}{160}=0,3mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,2\\2x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,1}{0,2}.100=50\%\\\%V_{C_2H_4}=100\%-50\%=50\%\end{matrix}\right.\)
\(a,C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{C_2H_4}=n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\\ b,\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,667\%\\ \%V_{CH_4}\approx100\%-66,667\%\approx33,333\%\)
\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,05
Suy ra:
\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)
b)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{4}{160}=0,025(mol)\\ \%V_{C_2H_4} = \dfrac{0,025.22,4}{5,6}.100\% = 10\%\\ \%V_{CH_4}= 100\%-10\%=90\%\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<--0,1
=> \(\%V_{C_2H_4}=\dfrac{0,1.22,4}{22,4}=10\%\)
=> %VCH4 = 100% - 10% = 90%
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