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PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)
\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)
b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)
nZnO=8,1/81=0,1(mol)
PTHH: ZnO + H2SO4 -> ZnSO4 + H2O
0,1________0,1_____0,1(mol)
a) mH2SO4=0,1.98=9,8(g)
=> mddH2SO4=(9,8.100)/10=98(g)
b) mZnSO4=0,1.161=16,1(g)
mddZnSO4=mZnO+ mddH2SO4= 8,1+98= 106,1(g)
=> C%ddZnSO4= (16,1/106,1).100= 15,174%
\(n_{BaCl_2}=\dfrac{31,2}{208}=0,15mol\)
\(BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
0,15 0,15 0,15 0,3
a)\(m_{BaSO_4}=0,15\cdot233=34,95\left(g\right)\)
b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{14,7}{19,6}\cdot100=75\left(g\right)\)
c)\(m_{HCl}=0,3\cdot36,5=10,95\left(g\right)\)
\(m_{ddsau}=31,2+75-34,95=71,25\left(g\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{10,95}{71,25}\cdot100\%=15,37\%\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2a______3a__________a_______3a (mol)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
b_______b________b______b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27\cdot2a+24b=7,8\\3a+b=\dfrac{200\cdot19,6\%}{98}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1\cdot24=2,4\left(g\right)\\m_{Al}=5,4\left(g\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)=n_{MgSO_4}\\n_{H_2}=0,4\left(mol\right)\Rightarrow m_{H_2}=0,4\cdot2=0,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=207\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1\cdot342}{207}\cdot100\%\approx16,52\%\\C\%_{MgSO_4}=\dfrac{0,1\cdot120}{207}\cdot100\%\approx5,8\%\end{matrix}\right.\)
a)
$Mg + H_2SO_4 \to MgSO_4 + H-2$
b) $n_{H_2SO_4} = n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)$
$C\%_{H_2SO_4} = \dfrac{0,2.98}{200}.100\% = 9,8\%$
$n_{H_2} = n_{Mg} = 0,2(mol)$
$\Rightarrow m_{dd\ A} = 4,8 + 200 - 0,2.2 = 204,4(gam)$
$C\%_{MgSO_4} = \dfrac{0,2.120}{204,4}.100\% = 11,7\%$
c) $V_{H_2} = 0,2.22,4 = 4,48(lít)$
\(n_{Mg}=\dfrac{4,8}{40}=0,12\left(mol\right)\\ MgO+H_2SO_4\rightarrow MgSO_4+H_2O\\n_{MgO}=n_{MgSO_4}=0,12\left(mol\right)\\ m_{ddMgSO_4}=m_{Mg}+m_{ddH_2SO_4}=4,8+200=204,8\left(g\right)\\ m_{MgSO_4}=0,12.120=14,4\left(g\right)\\ C\%_{ddMgSO_4}=\dfrac{14,4}{204,8}.100\approx7,03\%\\ \Rightarrow C\)
Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
a. PTHH: Mg + H2SO4 ---> MgSO4 + H2↑
Theo PT: \(n_{H_2}=n_{Mg}=0,4\left(mol\right)\)
=> \(V_{H_2}=0,4.22,4=8,96\left(lít\right)\)
b. Theo PT: \(n_{H_2SO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{39,2}{m_{dd_{H_2SO_4}}}.100\%=10\%\)
=> \(m_{dd_{H_2SO_4}}=392\left(g\right)\)
c. Ta có: \(m_{H_2}=0,4.2=0,8\left(g\right)\)
=> \(m_{dd_{MgSO_4}}=9,6+392-0,8=400,8\left(g\right)\)
Theo PT: \(n_{MgSO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{MgSO_4}=0,4.120=48\left(g\right)\)
=> \(C_{\%_{MgSO_4}}=\dfrac{48}{400,8}.100\%=11,98\%\)
a) 2NaOH + H2SO4 -- Na2SO4 + 2H2O
b) \(n_{NaOH}=\dfrac{100.20}{100.40}=0,5\left(mol\right)\)
PTHH: 2NaOH + H2SO4 -- Na2SO4 + 2H2O
______0,5----->0,25------>0,25
=> mH2SO4 = 0,25.98 = 24,5 (g)
=> \(m_{ddH_2SO_4}=\dfrac{24,5.100}{19,6}=125\left(g\right)\)
c) mNa2SO4 = 0,25.142 = 35,5 (g)
mdd sau pư = 100 + 125 = 225 (g)
=> \(C\%\left(Na_2SO_4\right)=\dfrac{35,5}{225}.100\%=15,778\%\)
a. \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
b. \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
=> \(C\%_{H_2SO_4}=\dfrac{0,3.98.100}{200}=14,7\%\)
