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mHCl= 10,95/36,5=0,3(mol)
Vì Cu ko phản ứng vs HCl nên suy ra
Mg+2HCl--->MgCl2+H2
0,15<-- 0,3 --> 0,15.(Mol)
mMg=0,15x24=3,6(g)
%Mg=3,6.100%/10=36%
%Cu=100%-36%=64%
b, mdd=10+300=310 g
mMgCl2=0,15x24=3,6 g
C%MgCl2 =3,6/310x100%≈1,16%
Bài 2
mol HCl=3.0,1=0,3mol(100ml=0,1l)
CuO+2HCl->CuCl2+H2O (1)
xmol 2xmol
ZnO+2HCl->ZnCl2+H2O(2)
ymol 2ymol
Từ 1 và 2 ta co hệ phương trình
2x+2y=0,3 ->x=0,05=molCuO
80x+81y=12,1 ->y=0,1=molZnO
=>mCuO=0,05.80=4g
->%CuO=(4.100)/12,1=33,075%
->%ZnO=100-33,075=66,943%
b. CuO+H2SO4->CuSO4+H2O (3)
Theo ptpu 3 taco nH2SO4=nCuO=0,05 mol
ZnO+H2SO4->ZnSO4+H2O (4)
Theo ptpu 4 ta co nH2SO4=nZnO=0,1mol
=>nH2SO4=0.05+0,1=0,15mol
->mH2SO4=0,15.98=14,7g
=>mddH2SO4=(14,7.100)/20=73,5g
Bài 1
a/. Phương trình phản ứng hoá học:
Fe + 2HCl --> FeCl2 + H2
b/. nH2 = V/22,4 = 3,36/22,4 = 0,15 (mol)
....... Fe.....+ 2HCl --> Fecl2 + H2
TPT 1 mol....2 mol.................1 mol
TDB x mol....y mol................0,15 mol
nFe = x = (0,15x1)/1 = 0,15 (mol)
mFe = n x M = 0,15 x 56 = 8,4 (g)
c/. nHCl = y = (0,15x2)/1 = 0,3 (mol)
CMHCl = n/V = 0,3/0,05 = 6 (M)
1. Fe+2HCl-> FeCl2 + H2 (1)
CuO + 2HCl -> CuCl2 + H2O(2)
a.nH2=0,02(mol)=>nFe=0,02(mol)=> mFe=1,12(g)
=> nHCl(1)=0,04(mol)
nHCl dùng=\(\dfrac{15\cdot14,6}{100}=2,19\left(g\right)\)
=> nHCl=0,06(mol)
=>nHCl(2)=0,02(mol)=> nCuO=0,01(mol)
=> mCuO=0,8(g)
b. mddA=1,12+0,8+15-0,02*2=16,88(g)
mFeCl2=0,02*127=2,54(g)
mCuCl2=0,01*135=1,35(g)
C% FeCl2=\(\dfrac{2,54\cdot100}{16,88}=15,047\%\)
C% CuCl2=\(\dfrac{1,35\cdot100}{16,88}=7,9976\%\)
Fe2O3 + 3H2SO4 \(\rightarrow\) Fe2(SO4)3 + 3H2O
a, n Fe2O3 = \(\dfrac{2,4}{160}\) = 0,015 mol
m H2SO4 = \(\dfrac{11,76.25}{100}\) = 2,94 g
n H2SO4 = \(\dfrac{2,94}{98}\) = 0,03 mol
Ta có : \(\dfrac{0,015}{1}< \dfrac{0,3}{3}\) \(\Rightarrow H2SO4\) dư
Theo PTHH :
n Fe2(SO4)3 = n Fe2O3 = 0,015 mol
\(\Rightarrow\) m Fe2(SO4)3 = 0,015 . 400 = 6 g
m dd thu đc sau pứ
= m Fe2O3 + m dd H2SO4
= 2,4 + 11,76 = 14,16 g
C% Fe2(SO4)3 = \(\dfrac{6}{14,16}.100\%\) = 42,4 %
b, 2Fe(OH)3 \(\rightarrow\) Fe2O3 + 3H2O
Theo PTHH :
n Fe(OH)3 = 2. n Fe2O3
= 2 . 0,015 = 0,03 mol
m Fe(OH)3 = 0,03 . 107 = 3,21 g
\(n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,05 0,1 0,05 0,05
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,2 0,4 0,2
a) \(n_{Mg}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(m_{Mg}=0,05.24=1,2\left(g\right)\)
\(m_{MgO}=9,2-1,2=8\left(g\right)\)
0/0Mg = \(\dfrac{1,2.100}{9,2}=13,04\)0/0
0/0MgO = \(\dfrac{8.100}{9,2}=86,96\)0/0
b) Có : \(m_{MgO}=8\left(g\right)\)
\(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,1+0,4=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{14,6}=125\left(g\right)\)
c) \(n_{MgCl2\left(tổng\right)}=0,05+0,2=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,25.95=23,75\left(g\right)\)
\(m_{ddspu}=9,2+125-\left(0,05.2\right)=134,1\left(g\right)\)
\(C_{MgCl2}=\dfrac{23,75.100}{134,1}=17,71\)0/0
Chúc bạn học tốt
a)\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,05 0,1 0,05 0,05
PTHH: MgO + 2HCl → MgCl2 + H2O
Mol: 0,2 0,4 0,2
\(\%m_{Mg}=\dfrac{0,05.24.100\%}{9,2}=13,04\%;\%m_{MgO}=100-13,04=86,96\%\)
\(n_{MgO}=\dfrac{9,2-0,05.24}{40}=0,2\left(mol\right)\)
b,\(m_{HCl}=\left(0,1+0,4\right).36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{14,6}=125\left(g\right)\)
c,mdd sau pứ = 9,2+125-0,05.2 = 134,1 (g)
\(C\%_{ddMgCl_2}=\dfrac{\left(0,05+0,2\right).95.100\%}{134,1}=17,71\%\)
Fe2O3 + 6HCl → 2FeCl3 + 3H2O (1)
CuO + 2HCl → CuCl2 + H2O (2)
a) \(m_{CuO}=20\times20\%=4\left(g\right)\)
\(\Rightarrow m_{Fe_2O_3}=20-4=16\left(g\right)\)
b) \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT1: \(n_{HCl}=6n_{Fe_2O_3}=6\times0,1=0,6\left(mol\right)\)
Theo PT2: \(n_{HCl}=2n_{CuO}=2\times0,05=0,1\left(mol\right)\)
\(\Rightarrow\Sigma n_{HCl}=0,1+0,6=0,7\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,7\times36,5=25,55\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{25,55}{5,475\%}=466,67\left(g\right)\)
c) Dung dịch sau phản ứng gồm: CuCl2 và FeCl3
Theo PT1: \(n_{FeCl_3}=2n_{Fe_2O_3}=2\times0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=0,2\times162,5=32,5\left(g\right)\)
Theo PT2: \(n_{CuCl_2}=n_{CuO}=0,05\left(mol\right)\)
\(\Rightarrow m_{CuCl_2}=0,05\times135=6,75\left(g\right)\)
\(\Sigma m_{dd}=20+466,67=486,67\left(g\right)\)
\(\Rightarrow C\%_{FeCl_3}=\dfrac{32,5}{486,67}\times100\%=6,68\%\)
\(C\%_{CuCl_2}=\dfrac{6,75}{486,67}\times100\%=1,39\%\)