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nZn=19,5/65=0,3(mol)
mHCl=18,25/36,5=0,5(mol)
pt: Zn+2HCl--->ZnCl2+H2
1______2
0,3_____0,5
Ta có: 0,3/1>0,5/2
=>Zn dư
mZn dư=0,05.65=3,25(mol)
Theo pt: nH2=1/2nHCl=1/2.0,5=0,25(mol)
=>VH2=0,25.22,4=5,6(l)
nZn = 0,3 mol
nHCl = 0,5 mol
Zn + 2HCl → ZnCl2 + H2
Đặt tỉ lệ ta có
0,3 < \(\dfrac{0,52}{2}\)
⇒ Zn dư và dư 3,25 gam
⇒ VH2 = 0,25.22,4 = 5,6 (l)
a) \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH : Zn + 2HCl -> ZnCl2 + H2
0,25 0,5 0,5 0,5
Xét tỉ lệ : \(\dfrac{0,3}{1}>\dfrac{0,5}{2}\) => Zn dư , HCl đủ
b) \(m_{Zn\left(dư\right)}=\left(0,3-0,25\right).65=3,25\left(g\right)\)
c) \(m_{ZnCl_2}=0,25.136=34\left(g\right)\)
\(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ a,Zn+2HCl\rightarrow ZnCl_2+H_2\\b, Vì:\dfrac{0,5}{2}< \dfrac{0,3}{1}\Rightarrow Zndư\\ n_{Zn\left(dư\right)}=0,3-\dfrac{0,5}{2}=0,05\left(mol\right)\\ \Rightarrow m_{Zn\left(dư\right)}=0,05.65=3,25\left(g\right)\\ c,n_{ZnCl_2}=n_{H_2}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,25.136=34\left(g\right)\\ V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
1.
a, \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,15 0,3
b, Ta có: \(\dfrac{0,15}{1}< \dfrac{0,5}{2}\) ⇒ Mg pứ hết, HCl dư
\(m_{HCldư}=\left(0,5-0,3\right).36,5=7,3\left(g\right)\)
c, \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
2.
a, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
PTHH: 4P + 5O2 ---to→ 2P2O5
Mol: 0,2 0,25 0,1
b, \(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
d, \(V_{kk}=5,6.5=28\left(l\right)\)
nZn=m/M=19,5/65=0,3(mol)
PT:
Zn + 2HCl -> ZnCl2 +H2↑↑
1...........2.............1............1(mol)
0,3->0,6 -> 0,3 -> 0,3 (mol)
mZnCl2=n.M=0,3.136=40,8(g)
(mH2=m.M=0,3.2=0,6(g))
c) nFe2O3=m/M=128/160=0,8(mol)
PT:
Fe2O3 + 3H2 -> 2Fe +3H2O
1..............3...........2..............3 (mol)
0,1 <- 0,3 -> 0,2 -> 0,3(mol)
Chất dư là Fe2O3
Số mol Fe2O3 dư là : 0,8-0,1=0,7(mol)
=> mFe2O3 dư=n.M=0,7.160=112(gam)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right);n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,6}{2}\Rightarrow Zn.dư\\ n_{H_2}=n_{Zn\left(p.ứ\right)}=\dfrac{0,6}{2}=0,3\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,n_{Zn\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{Zn\left(dư\right)}=0,1.65=6,5\left(g\right)\)
`n_(Zn)=m/M=(26)/65=0,4(mol)`
`n_(HCl)=m/M=(21,9)/36,5=0,6(mol)`
`PTHH:Zn+2HCl->ZnCl_2 +H_2`
tỉ lệ: 1 ; 2 : 1 : 1
n(mol) 0,3<----0,6---->0,3----->0,3
\(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\left(\dfrac{0,4}{1}>\dfrac{0,6}{2}\right)\)
`=>` `Zn` dư, `HCl` hết, tính theo `HCl`
`V_(H_2)=n*22,4=0,3*22,4=6,72(l)`
`n_(Zn(dư))=0,4-0,3=0,1(mol)`
`m_(Zn(dư))=n*M=0,1*65=6,5(g)`
nZn = 0,3 mol
nHCl = 0,5 mol
Zn + 2HCl → ZnCl2 + H2
Đặt tỉ lệ ta có
0,3 < \(\dfrac{0,5}{2}\)
⇒ Zn dư và dư 3,25 gam
⇒ VH2 = 0,25.22,4 = 5,6 (l)
nZn=19,5/65=0,3(mol)
mHCl=18,25/36,5=0,5(mol)
pt: Zn+2HCl--->ZnCl2+H2
1______2
0,3_____0,5
Ta có: 0,3/1>0,5/2
=>Zn dư
mZn dư=0,05.65=3,25(mol)
Theo pt: nH2=1/2nHCl=1/2.0,5=0,25(mol)
=>VH2=0,25.22,4=5,6(l)