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a, \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=4,4-2,4=2\left(g\right)\)
c, \(n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Mg}+n_{MgO}=0,15\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{14,7}{19,6\%}=75\left(g\right)\)
\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)
Fe + H2SO4 → FeSO4 + H2
2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Gọi x,y lần lượt là số mol Fe, Al
\(\left\{{}\begin{matrix}56x+27y=11\\x+\dfrac{3}{2}y=0,4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=>\(\%m_{Fe}=\dfrac{0,1.56}{11}.100=50,91\%\)
=> %m Al = 100 - 50,91 =49,09 %
b)Theo PT: \(n_{H_2}=n_{H_2SO_4}=0,4\left(mol\right)\)
=> \(V_{H_2}=0,4.22,4=8,96\left(l\right)\)
c) \(CM_{FeSO_4}=\dfrac{0,1}{0,2}=0,5M\)
\(CM_{Al_2\left(SO_4\right)_3}=\dfrac{\dfrac{0,2}{2}}{0,2}=0,5M\)
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a_______a_______a_____a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2b______3b__________b_____3b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a) nH2SO4=0,4(mol)
Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)
PTHH: Fe + H2SO4 -> FeSO4 + H2
x________x______x______x(mol)
2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
y____1,5y_______0,5y_______1,5y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=> mFe=0,1.56=5,6(g)
=>%mFe=(5,6/11).100=50,909%
=>%mAl= 49,091%
b) V(H2,đktc)=0,4.22,4=8,96(l)
c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)
nFeSO4=x=0,1(mol)
Vddsau=VddH2SO4=0,2(l)
=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)
CMddFeSO4=0,1/0,2=0,5(M)
\(n_{H2}=\dfrac{22,4}{22,4}=1\left(mol\right)\)
a) Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)
2 3 1 3
a 0,6 1,5a
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
b 0,4 1b
b) Gọi a là số mol của Al
b là số mol của Mg
\(m_{Al}+m_{Mg}=20,4\left(g\right)\)
⇒ \(n_{Al}.M_{Al}+n_{Mg}.M_{Mg}=20,4g\)
⇒ 27a + 24b = 20,4g (1)
The phương trình : 1,5a + 1b = 1(2)
Từ(1),(2), ta có hệ phương trình :
27a + 24b = 20,4g
1,5a + 1b = 1
⇒ \(\left\{{}\begin{matrix}a=0,4\\b=0,4\end{matrix}\right.\)
\(m_{Al}=0,4.27=10,8\left(g\right)\)
\(m_{Mg}=0,4.24=9,6\left(g\right)\)
c) \(n_{H2SO4\left(tổng\right)}=0,6+0,4=1\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{1}{0,2}=5\left(l\right)\)
Chúc bạn học tốt
a, Ta có: 27nAl + 56nFe = 0,83 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow n_{Al}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%\approx32,53\%\\\%m_{Fe}\approx67,47\%\end{matrix}\right.\)
b, nH2SO4 = nH2 = 0,025 (mol)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,025.98}{20\%}=12,25\left(g\right)\)
thôi thì mình làm cho bn vậy, câu a ko làm dc đâu, làm câu b thôi, làm sao biết dc chất nào dư khi chỉ có số mol 1 chất?
nK2SO3=0.1367(mol)
mddH2SO4=Vdd.D=200.1,04=208(g)
K2SO3+H2SO4-->K2SO4+H2O+SO2
0.1367----0.1367----0.1367---------0.1367 (mol)
mddspu=100+208-0,1367.64=299.2512(g) ; mK2SO4=0,1367.174=23.7858(g)
==>C%=23.7858.100/299.512=7.94%
2)pt bn tự ghi nhé
ta có hệ pt: 56a+27b=11 và a+3b/2=8.96/22.4==>a=0.1, b=0.2
==>%Fe=0.1x56x100/11=50.9%
%Al=100%-50.9%=49.1%
b)nH2SO4= 0.7(mol)==>VddH2SO4=0.7/2=0.35(L)
\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)
\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)
a) B là \(Al_2\left(SO_4\right)_3\), C là \(Cu\)
\(b)n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(m_{hh}=0,2.27+3,2=8,6g\\ \%m_{Cu}=\dfrac{3,2}{8,6}\cdot100=37,21\%\\ \%m_{Al}=100-37,21=62,79\%\\ c)C_{M_{H_2SO_4}}=\dfrac{0,3}{0,25}=1,2M\)
a) 2Al + 3H2SO4 → Al2(SO4)3 + 3H2 (1)
Fe + H2SO4 → FeSO4 + H2 (2)
\(n_{H_2}=\frac{1,12}{22,4}=0,05\left(mol\right)\)
Gọi x,y lần lượt là số mol của Al và Fe
Ta có: \(27x+56y=1,66\) (*)
Theo PT1: \(n_{H_2}=1,5n_{Al}=1,5x\left(mol\right)\)
Theo pt2: \(n_{H_2}=n_{Fe}=y\left(mol\right)\)
Ta có: \(1,5x+y=0,05\) (**)
Tù (*)(**) ta có: \(\left\{{}\begin{matrix}27x+56y=1,66\\1,5x+y=0,05\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,02\end{matrix}\right.\)
Vậy \(n_{Al}=0,02\left(mol\right)\Rightarrow m_{Al}=0,02\times27=0,54\left(g\right)\)
\(n_{Fe}=0,02\left(mol\right)\Rightarrow m_{Fe}=0,02\times56=1,12\left(g\right)\)
b) \(\%m_{Al}=\frac{0,54}{1,66}\times100\%=32,53\%\)
\(\%m_{Fe}=\frac{1,12}{1,66}\times100\%=67,47\%\)
c) Theo pT1: \(n_{H_2SO_4}=\frac{3}{2}n_{Al}=\frac{3}{2}\times0,02=0,03\left(mol\right)\)
Theo pt2: \(n_{H_2SO_4}=n_{Fe}=0,02\left(mol\right)\)
\(\Rightarrow\Sigma n_{H_2SO_4}=0,03+0,02=0,05\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\frac{0,05}{0,2}=0,25\left(M\right)\)
a) 2Al + 3H2SO4 → Al2(SO4)3 + 3H2 (1)
Fe + H2SO4 → FeSO4 + H2 (2)
nH2=\(\frac{1,12}{22,4}=0,05\left(mol\right)\)
Gọi x,y(mol) lần lượt là số mol của Al và Fe.ĐK: x,y>0.
Ta có: 27x+56y=1,66 (*)
Theo PT1: nH2=1,5nAl=1,5x(mol)
Theo pt2: nH2=nFe=y(mol)
Ta có: 1,5x+y=0,05 (**)
Tù (*)(**) ta có=>x=y=0,02(TM)
Vậy nAl=0,02(mol)⇒mAl=0,02×27=0,54(g)
nFe=0,02(mol)⇒mFe=0,02×56=1,12(g)
b) %mAl=0,541,66×100%=32,53%
%mFe=1,121,66×100%=67,47%
c) Theo pT1: nH2SO4=32nAl=32×0,02=0,03(mol)
Theo pt2: nH2SO4=nFe=0,02(mol)
⇒nH2SO4=0,03+0,02=0,05(mol)
⇒CMH2SO4=0,05/0,2=0,25(M)