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a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(Cu+2H_2SO_{4\left(đ\right)}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
\(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(n_{SO_2}=\dfrac{2,9748}{24,79}=0,12\left(mol\right)\)
\(n_{Cu}=n_{SO_2}=0,12\left(mol\right)\)
\(\Rightarrow m=m_{Zn}+m_{Cu}=0,1.65+0,12.64=14,18\left(g\right)\)
Có: \(n_{H_2SO_{4\left(đ\right)}}=2n_{SO_2}=0,24\left(mol\right)\Rightarrow x=m_{ddH_2SO_4\left(đ\right)}=\dfrac{0,24.98}{98\%}=24\left(g\right)\)
a) mCu = 3,2 (g)
=> mFe = 6 - 3,2 = 2,8 (g)
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,05->0,1--->0,05--->0,05
=> V1 = 0,05.22,4 = 1,12 (l)
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
PTHH: 2Fe + 6H2SO4(đ/n) --> Fe2(SO4)3 + 3SO2 + 6H2O
0,05--------------------------------->0,075
Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
0,05------------------------>0,05
=> V2 = (0,075 + 0,05).22,4 = 2,8 (l)
b)
nHCl(dư) = 0,5.2 - 0,1 = 0,9 (mol)
=> \(\left\{{}\begin{matrix}C_{M\left(HCl.dư\right)}=\dfrac{0,9}{0,5}=1,8M\\C_{M\left(FeCl_2\right)}=\dfrac{0,05}{0,5}=0,1M\end{matrix}\right.\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Zn+2HCl\to ZnCl_2+H_2\\ b,n_{ZnCl_2}=0,1(mol)\\ \Rightarrow m_{ZnCl_2}=0,1.136=13,6(g)\\ c,n_{Zn}=0,1(mol)\\ \Rightarrow \%_{Zn}=\dfrac{0,1.65}{20}.100\%=32,5\%\\ \Rightarrow \%_{Ag}=100\%-32,5\%=67,5\%\)
a) PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2
x___________3x______________1,5x(mol)
Fe +2 HCl -> FeCl2 + H2
y___2y____y______y(mol)
b) Ta có: m(rắn)= mCu=0,4(g)
=> m(Al, Fe)=1,5-mCu=1,5-0,4=1,1(g)
nH2= 0,04(mol)
Ta lập hpt:
\(\left\{{}\begin{matrix}27x+56y=1,1\\1,5x+y=0,04\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
=> mAl=27.0,02=0,54(g)
mFe=56.0,01=0,56(g)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH:
\(Fe+H_2SO_4--->FeSO_4+H_2\uparrow\left(1\right)\)
\(Cu+H_2SO_4--\times-->\)
Theo PT(1): \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe}=m_{Cu}=0,1.56=5,6\left(g\right)\)
PTHH: \(Cu+2H_2SO_{4_{đặc}}\overset{t^o}{--->}CuSO_4+SO_2\uparrow+2H_2O\left(2\right)\)
Ta có: \(n_{Cu}=\dfrac{5,6}{64}=0,0875\left(mol\right)\)
Theo PT(2): \(n_{SO_2}=n_{Cu}=0,0875\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,0875.22,4=1,96\left(lít\right)\)
Cau 1 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,1
a) Chat trong dung dich A thu duoc la : sat (II) clorua
Chat ran B la : dong
Chat khi C la : khi hidro
b) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
\(m_{Cu}=10-5,6=4,4\left(g\right)\)
0/0Fe = \(\dfrac{5,6.100}{10}=56\)0/0
0/0Cu = \(\dfrac{4,4.100}{10}=44\)0/0
c) Co : \(m_{Cu}=4,4\left(g\right)\)
\(n_{Cu}=\dfrac{4,4}{64}=0,06875\left(mol\right)\)
Pt : \(Cu+2H_2SO_{4dac}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O|\)
1 2 1 1 2
0,06875 0,06875
\(n_{SO2}=\dfrac{0,06875.1}{1}=0,06875\left(mol\right)\)
\(V_{SO2\left(dktc\right)}=1,54\left(l\right)\)
Chuc ban hoc tot
Minh xin loi ban nhe , ban bo sung vao cho :
\(V_{SO2\left(dktc\right)}=0,06875.22,4=1,54\left(l\right)\)
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