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1)
a, \(n_{Al}=\dfrac{15,3}{102}=0,15\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,15 0,9 0,3
\(m_{ddHCl}=\dfrac{0,9.36,5.100}{20}=164,25\left(g\right)\)
b, mdd sau pứ = 15,3 + 164,25 = 179,55 (g)
c, \(C\%_{ddAlCl_3}=\dfrac{0,3.133,5.100\%}{179,55}=22,31\%\)
2)
a, \(m_{HCl}=54,75.20\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,05 0,3 0,1
\(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
b, mdd sau pứ = 5,1 + 54,75 = 59,85 (g)
\(C\%_{ddAlCl_3}=\dfrac{0,1.133,5.100\%}{59,85}=22,31\%\)
nAl2O3= 10,2/102= 0,1(mol)
a) PTHH: Al2O3 + 6 HCl -> 2 AlCl3 + 3 H2O
0,1_______0,6_______0,2_________0,3(mol)
mHCl=0,6.36,5= 21,9(g)
=>mddHCl= (21,9.100)/7,3=300(g)
b) mddsau= mAl2O3 + mddHCl= 10,2+300=310,2(g)
c) mAlCl3= 133,5.0,2=26,7(g)
=>C%ddAlCl3= (26,7/310,2).100=8,607%
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Fe có số mol là \(n_{Fe}=\frac{m}{M}=\frac{11,2}{56}=0,2mol\)
\(H_2SO_4\) có số mol là \(n_{H_2SO_4}=\frac{0,2.1}{1}=0,2mol\)
Có \(V=200ml=0,2l\)
\(\rightarrow C_M=\frac{n_{H_2SO_4}}{V_{H_2SO_4}}=\frac{0,2}{0,2}=1M\)
FeSO\(_4\) có số mol là \(n_{FeSO_4}=\frac{0,2.1}{1}=0,2mol\)
Thể tích của \(FeSO_4\) là \(V_{FeSO_4}=V_{H_2SO_4}\rightarrow C_M=\frac{n}{V}=\frac{0,2}{0,2}=1M\)
\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 0,25.........0,5.........0,25.......0,25\left(mol\right)\\ a.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b.m_{HCl}=0,5.36,5=18,25\left(g\right)\\ c.n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\ Fe_2O_3+3H_2\underrightarrow{^{to}}2Fe+3H_2O\\ Vì:\dfrac{0,25}{3}< \dfrac{0,1}{1}\\ \Rightarrow Fe_2O_3dư\\ n_{Fe}=\dfrac{2}{3}.0,25=\dfrac{1}{6}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{1}{6}.56\approx9,333\left(g\right)\)
a,\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,25 0,5 0,25
\(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b,\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
c,\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,25 \(\dfrac{1}{6}\)
Ta có: \(\dfrac{0,1}{1}>\dfrac{0,25}{3}\)⇒ Fe2O3 dư, H2 hết
\(m_{Fe}=\dfrac{1}{6}.56=9,33\left(g\right)\)
\(m_{ct}=\dfrac{20.98}{100}=19,6\left(g\right)\)
\(n_{H2SO4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)
1 1 1 1
0,2 0,2 0,2
a) \(n_{CuO}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CuO}=0,2.80=16\left(g\right)\)
b) \(n_{CuSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CuSO4}=0,2.160=32\left(g\right)\)
c) \(m_{ddspu}=16+98=114\left(g\right)\)
\(C_{CuSO4}=\dfrac{32.100}{114}=28,7\)0/0
Chúc bạn học tốt
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)
