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2Mg + O2-to-> 2MgO (1)
0,1 0,2
nMg = 7,2/24 =0,3 mol
nO2 =2,24/22,4 = 0,1 mol
(1) => O2 hết , Mg dư
mMgO = 0,2 * 40=8 g
mMg đầu = mMg dư + mMg p/ứ
7,2=mMg dư +0,2 *24 => mMg dư =2,4 g
=> B gồm Mg dư và MgO
MgO + 2HCl --> MgCl2 + H2O (2)
Mg + 2HCl --> MgCl2 + H2 (3)
0,1 0,1
n Mg du =2,4/24 = 0,1 mol
(3) => VH2 = 0,1 *22,4 =2,24 lít
\(a.n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{17,8\%.200}{36,5}=\dfrac{356}{365}\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,1}{1}< \dfrac{\dfrac{356}{365}}{2}\\ \Rightarrow Znhết,HCldư\\ n_{HCl\left(dùng\right)}=0,1.2=0,2\left(mol\right)\\ m_{HCl\left(dùng\right)}=0,2.36,5=7,3\left(g\right)\\ b.n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ c.n_{HCl\left(Dư\right)}=\dfrac{356}{365}-0,2=\dfrac{283}{365}\left(mol\right)\\ C\%_{ddZnCl_2}=\dfrac{0,1.136}{6,5+200}.100\approx6,586\%\)
\(C\%_{ddHCl\left(dư\right)}=\dfrac{\dfrac{283}{365}.36,5}{6,5+200}.100\approx13,705\%\)
a,Fe + 2HCl → FeCl + H2 (1)
FeO + 2HCl → FeCl + H2O (2)
nH2 = 3,36/ 22,4 = 0,15 ( mol)
Theo (1) nH2 = nFe = 0,15 ( mol)
mFe = 0,15 x 56 = 8.4 (g)
m FeO = 12 - 8,4 = 3,6 (g)
a, \(n_{H_2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
\(FeO+2HCl->FeCl_2+H_2O\left(2\right)\)
theo (1) \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
=> \(m_{Fe}=0,15.56=8,4\left(g\right)\)
=> \(m_{FeO}=12-8,4=3,6\left(g\right)\)
ta thấy : nFe =nH2 = 0,15
=> mFe =0,15 x 56 = 8,4g
%Fe=8,4/12 x 100 = 70%
=>%FeO = 100 - 70 = 30%
b) BTKLra mdd tìm mct of HCl
c) tìm mdd sau pứ -mH2 nha bạn
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
Gọi x, y, z là số mol Fe, Mg, Cu
=> \(56x+24y+64z=24,8\) (1)
X+ H2SO4 đặc nóng
2Fe + 6H2SO4 → Fe2(SO4)3 + 3SO2↑ + 6H2O
Mg + 2H2SO4→ MgSO4 + SO2↑ + 2H2O.
Cu + 2H2SO4→ CuSO4 + SO2↑ + 2H2O.
Các muối là \(Fe_2\left(SO_4\right)_3,MgSO_4,CuSO_4\)
=> \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{n_{Fe}}{2}=\dfrac{x.}{2};n_{MgCl_2}=n_{Mg}=y;n_{CuCl_2}=n_{Cu}=z\)
=> \(\dfrac{400x}{2}+120y+160z=132\) (2)
X + HCl dư thu được khí là H2
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
=> x+y=0,5 (mol) (3)
Từ (1), (2), (3) => x, y ,z
Xem lại đề vì hệ vô nghiệm
Theo gt ta có: $n_{Zn}=0,1(mol)$
a, $Zn+2HCl\rightarrow ZnCl_2+H_2$
b, Ta có: $n_{H_2}=0,1(mol)\Rightarrow V_{H_2}=2.24(l)$
c, Ta có: $n_{HCl}=2.n_{Zn}=0,2(mol)\Rightarrow m_{HCl}=7,3(g)$
$a\big)$
$M_A=9,4.2=18,8(g/mol)$
$\to \dfrac{n_{CO_2}}{n_{H_2}}=\dfrac{18,8-2}{44-18,8}=\dfrac{2}{3}$
Mà $n_{CO_2}+n_{H_2}=\dfrac{11,2}{22,4}=0,5(mol)$
\(\begin{array} {l} \to n_{CO_2}=0,2(mol);n_{H_2}=0,3(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ FeCO_3+2HCl\to FeCl_2+CO_2+H_2O\\ \text{Theo PT: }n_{Fe}=n_{H_2}=0,3(mol);n_{FeCO_3}=n_{CO_2}=0,2(mol)\\ \to m=0,3.56+0,2.116=40(g) \end{array}\)
$b\big)$
Đổi $400ml=0,4l$
\(\begin{array} {l} \text{Theo PT: }n_{FeCl_2}=n_{H_2}+n_{CO_2}=0,5(mol)\\ \to C_{M\,FeCl_2}=\dfrac{0,5}{0,4}=1,25M \end{array}\)
$c\big)$
\(\begin{array}{l} m_{dd\,FeCl_2}=\dfrac{400}{1,2}\approx 333,33(g)\\ \to C\%_{FeCl_2}=\dfrac{0,5.127}{333,33}.100\%=19,05\%\end{array}\)
mFe= 8,4/56= 0,15 mol
m HCl = 14,6/36,5=0,4 mol
PTHH: Fe +2HCl →FeCl2 +H2
Bđ: 0,15 0,4 0 0 mol
Pứ: o,15→0,3 0,15 0,15 mol
Sau pứ:0 0,1 0,15 0,15 mol
a. HCl dư: m =0,1.36,5=3,65 g
b. m FeCl2 = 0,15.127=19,05 g
c. m H2 = 0,15.2= 0,3 g
V H2= 0,15.22,4=3,36 (l)