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a. PTHH:
\(Cu+H_2SO_4--\times-->\)
\(CuO+H_2SO_4--->CuSO_4+H_2O\left(1\right)\)
\(Cu+2H_2SO_{4_{đặc}}\overset{t^o}{--->}CuSO_4+SO_2+2H_2O\left(2\right)\)
Ta có: \(n_{SO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT(2): \(n_{Cu}=n_{SO_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
\(\Rightarrow\%_{m_{Cu}}=\dfrac{3,2}{10}.100\%=32\%\)
\(\%_{m_{CuO}}=100\%-32\%=68\%\)
Cau 1 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,1
a) Chat trong dung dich A thu duoc la : sat (II) clorua
Chat ran B la : dong
Chat khi C la : khi hidro
b) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=0,1.56=5,6\left(g\right)\)
\(m_{Cu}=10-5,6=4,4\left(g\right)\)
0/0Fe = \(\dfrac{5,6.100}{10}=56\)0/0
0/0Cu = \(\dfrac{4,4.100}{10}=44\)0/0
c) Co : \(m_{Cu}=4,4\left(g\right)\)
\(n_{Cu}=\dfrac{4,4}{64}=0,06875\left(mol\right)\)
Pt : \(Cu+2H_2SO_{4dac}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O|\)
1 2 1 1 2
0,06875 0,06875
\(n_{SO2}=\dfrac{0,06875.1}{1}=0,06875\left(mol\right)\)
\(V_{SO2\left(dktc\right)}=1,54\left(l\right)\)
Chuc ban hoc tot
Minh xin loi ban nhe , ban bo sung vao cho :
\(V_{SO2\left(dktc\right)}=0,06875.22,4=1,54\left(l\right)\)
Bài 1 :
Đặt :
nCuO = x mol
nZnO = y mol
<=> 80x + 81y = 12.1 (1)
nHCl = 0.3 mol
CuO + 2HCl --> CuCl2 + H2O
x______2x
ZnO + 2HCl --> ZnCl2 + H2O
y_______2y
<=> x + y = 0.15 (2)
(1) , (2) :
x = 0.05
y = 0.1
mCuO = 4 g
mZnO = 8.1 g
%CuO = 33.05%
%ZnO = 66.95%
ZnO + H2SO4 --> ZnSO4 + H2O
0.1_____0.1
CuO + H2SO4 --> CuSO4 + H2O
0.05____0.05
mH2SO4 = 14.7 g
nCuCl2 : nZnCl2 = 0.05 : 0.1 = 1 : 2
Bài 2 :
Đặt :
nH2 = 0.2 mol
nAl = x mol
nFe = y mol
mAl + mFe = 7 - 1.5 = 5.5 g
<=> 27x + 56y = 5.5 (1)
2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
x__________________________1.5x
Fe + H2SO4 --> FeSO4 + H2
y_____________________y
<=> 1.5x + y = 0.2 (2)
(1) , (2) :
x = 0.1
y = 0.05
mAl = 2.7 g
mFe = 2.8 g
mCu = 1.5 g
%Al = 38.57%
%Fe = 40%
%Cu = 21.43%
\(n_{CuO}=x;n_{ZnO}=y\)
\(PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\\ PTHH:ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(\Rightarrow hpt:\left\{{}\begin{matrix}80x+81y=12,1\\2\left(x+y\right)=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\frac{0,05.80}{12,1}.100\%=33,1\left(\%\right)\\\%m_{ZnO}=100-33,1=66,9\left(\%\right)\end{matrix}\right.\)
\(PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ PTHH:ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)
\(m_{H_2SO_4}=98.\left(0,05+0,1\right)=14,7\left(g\right)\)
\(\frac{n_{CuCl_2}}{n_{ZnCl_2}}=\frac{0,05}{0,1}=\frac{1}{2}\)
2Al+3H2SO4\(\rightarrow\)Al2(SO4)3+3H2
MgO+H2SO4\(\rightarrow\)MgSO4+H2O
nH2=\(\frac{3,36}{22,4}\)=0,15(mol)
\(\rightarrow\)nAl=\(\frac{0,15.2}{3}\)=0,1(mol)
mAl=0,1.27=2,7(g)\(\rightarrow\)\(\text{mMgO=12,7-2,7=10(g)}\)
b)
nH2SO4=\(\frac{3}{2}\)xnAl+nMgO=0,15+\(\frac{10}{40}\)=0,4(mol)
mddH2SO4=\(\frac{\text{0,4.98}}{20\%}\)=196(g)
c)
\(\text{ mdd=12,7+196-0,15.2=208,4(g)}\)
C%Al2(SO4)3=\(\frac{\text{0,05.342}}{208,4}.100\%\)=8,2%
C%MgSO4=\(\frac{\text{0,25.120}}{208,4}.100\%\)=14,4%
Tác dụng với H2SO4 loãng chỉ có CuO phản ứng
\(\rightarrow\)CuO + H2SO4\(\rightarrow\) CuSO4 + H2O
Sau đó rắn còn lại là Cu
Cu + 2H2SO4 \(\rightarrow\)CuSO4 + SO2 + H2O
Ta có : nSO2=0,05 mol =nCu \(\rightarrow\) mCu=0,05.64=3,2 gam
\(\rightarrow\) %Cu=\(\frac{3,2}{10}\)=32% \(\rightarrow\)%CuO=100%-32%=68%
THANKS cậu nhiều ❤❤❤