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`n_[Al]=[2,7]/27=0,1(mol)`
`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`
`0,1` `0,3` `0,1` `0,15` `(mol)`
`a)V_[H_2]=0,15.22,4=3,36(l)`
`b)V_[dd HCl]=[0,3]/2=0,15(l)`
`=>C_[M_[AlCl_3]]=[0,1]/[0,15]~~0,67(M)`
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,3 0,1 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ V_{HCl}=\dfrac{0,3}{2}=0,15\left(l\right)\\ C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}M\)
\(n_{Al}=\frac{10,8}{27}=0,4\left(mol\right)\)
\(2Al+6HCl->2AlCl_3+3H_2\) (1)
theo (1) \(n_{H_2}=\frac{3}{2}n_{Al}=0,6\left(mol\right)\)
=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)
Cho 10,08 g nhom tac dung vua du voi dung dich axit HCl.2M
a) viet phuong trinh phan ung va tinh the tich H2(dktc)
b) tinh the tich dung dich axit HCl.2M da dung
\(n_{Al}=\dfrac{4.5}{27}=\dfrac{1}{6}\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\dfrac{1}{6}.....0.5.......\dfrac{1}{6}.......0.25\)
\(m_{HCl}=0.5\cdot36.5=18.25\left(g\right)\)
\(m_{AlCl_3}=\dfrac{1}{6}\cdot133.5=22.25\left(g\right)\)
\(V_{H_2}=0.25\cdot22.4=5.6\left(l\right)\)
a) 2Al + 6HCl -----> 2AlCl3 + 3H2
Theo pt: 2 : 6 : 2 : 3 (mol)
Theo đb: 0,4 : 1,2 (mol)
Số mol H2 là:
nH2 = \(\frac{0,4\cdot3}{2}=0,6\left(mol\right)\)
Thể tích khí H2 (đktc) là:
VH2 = n.22,4 = 0,6 . 22,4 = 13,44 (lít)
b) Số mol HCl là:
nHCl = \(\frac{0,4\cdot6}{2}=1,2\left(mol\right)\)
Khối lượng chất tan HCl là:
mct HCl = n.M = 1,2 . 36.5 = 43,8 (g)
Khối lượng dd HCl là:
mdd HCl = \(\frac{43,8\cdot100\%}{10,95\%}=400\left(g\right)\)
Khối lượng chất tan AlCl3 là:
mct AlCl3 = n.M = 0,4.133,5 = 53,4 (g)
Khối lượng dd AlCl3 là:
mdd AlCl3 = mAl + mHCl - mH2 = 10,8 + 400 - 1,2 = 409,6 (g)
Nồng độ phần trăm dd AlCl3 là:
C% = \(\frac{53,4}{409,6}\cdot100\%\approx13,04\%\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
câu 1 PTHH:Fe+2HCl\(\xrightarrow[]{}\)FeCl2+H2
nFe=\(\dfrac{5,6}{56}\)=0,1 mol
a) theo đầu bài ta có
nFe=nH2=0,1 mol
lượng khí H2 tạo ra ở điều kiện tiêu chuẩn là
V=n.22,4
VH2=0,1.22,4= 2,24 (l)
Cau 2
Ta có pthh
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Theo đề bài ta có
nAl=\(\dfrac{10,8}{27}=0,4mol\)
a, Theo pthh
nH2=\(\dfrac{3}{2}nAl=\dfrac{3}{2}.0,4=0,6mol\)
\(\Rightarrow\) VH2=0,6.22,4=13,44 l
b, Theo pthh
nHCl=\(\dfrac{6}{2}.nAl=\dfrac{6}{2}.0,4=1,2mol\)
\(\Rightarrow mHCl=1,2.36,5=43,8g\)
\(\Rightarrow m\text{dd}_{HCl}=\dfrac{mct.100\%}{C\%}=\dfrac{43,8.100\%}{10,95\%}=400g\)
Theo pthh
nAlCl3=nAl=0,4 mol
\(\Rightarrow\) mAlCl3=0,4.133,5=53,4 g
mdd\(_{AlCl3}\)= mAl + m\(_{\text{dd}HCl}\) - mck = 10,8 +400 - ( 0,6.2)=409,6 g
\(\Rightarrow\) Nồng độ % của chất sau phản ứng là :
C%=\(\dfrac{mct}{m\text{dd}}.100\%=\dfrac{53,4}{409,6}.100\%\approx13,04\%\)
\(n_{Al}=\dfrac{6,75}{27}=0,25\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,25 0,75 0,25 0,375
\(a,V_{H_2}=0,375.22,4=8,4\left(l\right)\)
\(b,m_{HCl}=0,75.36,5=27,375\left(g\right)\)
\(m_{ddHCl}=\dfrac{27,375.100}{10,95}=250\left(g\right)\)
\(c,m_{AlCl_3}=0,25.133,5=33,375\left(g\right)\)
\(m_{ddAlCl_3}=6,75+250-\left(0,375.2\right)=256\left(g\right)\)
\(C\%_{AlCl_3}=\dfrac{33,375}{256}.100\%\approx13,04\left(\%\right)\)
\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)