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Fe + 2HCl -> FeCl2 + H2
0.2 0.1
FeO + 2HCl -> FeCl2 + H2O
0.1 0.2
a.\(nH2=\dfrac{2.24}{22.4}=0.1mol\)
\(\%mFe=\dfrac{0.1\times56\times100}{12.8}=43.8\%\)
\(\%mFeO=100-43.8=56.2\%\)
b.\(nFeO=\dfrac{12.8-\left(0.1\times56\right)}{56+16}=0.1mol\)
\(V_{HCl}=\dfrac{0.2+0.2}{2}=0.2l\)
\(n_{H2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
a) Pt : \(2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2|\)
2 2 2 2 3
0,2 0,2 0,3
\(Al_2O_3+2NaOH\rightarrow2NaAlO_2+H_2O|\)
1 2 2 1
0,1 0,2
b) \(n_{Al}=\dfrac{0,3.2}{3}=0,2\left(mol\right)\)
\(m_{Al}=0,2.27=5,4\left(g\right)\)
\(m_{Al2O3}=15,6-5,4=10,2\left(g\right)\)
c) Có : \(m_{Al2O3}=10,2\left(g\right)\)
\(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
\(n_{NaOH\left(tổng\right)}=0,2+0,2=0,4\left(mol\right)\)
\(V_{ddNaOH}=\dfrac{0,4}{1}=0,4\left(l\right)=400\left(ml\right)\)
Chúc bạn học tốt
2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2
0,4-----------------0,2----------------------------------------0,2
2CH3COOH+CaO->(CH3COO)2Ca+H2O
0,1----------------0,05
n CO2=0,2 mol
=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)
=>%m CaO=12,28%
=>n CaO=0,05 mol
=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)
a)
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: CaCO3 + 2CH3COOH --> (CH3COO)2Ca + CO2 + H2O
0,2<---------0,4<------------------------------0,2
=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)
=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)
b)
\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)
PTHH: CaO + 2CH3COOH --> (CH3COO)2Ca + H2O
0,05---->0,1
=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)
c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)
=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)
Đặt \(n_{Mg}=x(mol);n_{Al}=y(mol)\Rightarrow 24x+27y=7,8(1)\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,4(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ a,m_{Mg}=0,1.24=2,4(g)\\ m_{Al}=7,8-2,4=5,4(g)\\ b,\Sigma n_{HCl}=2x+3y=0,8(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,8}{2}=0,4(l)\)
\(c,PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow+2NaCl\\ AlCl_3+3NaOH\to Al(OH)_3\downarrow+3NaCl\\ n_{MgCl_2}=n_{Mg(OH)_2}=x=0,1(mol)\\ n_{Al(OH)_3}=n_{AlCl_3}=y=0,2(mol)\\ \Rightarrow m_{Mg(OH)_2}=0,1.58=5,8(g)\\ m_{Al(OH)_3}=0,2.78=15,6(g)\\ m_{kết tủa}=5,8+15,6=21,4(g)\)
Mg + 2HCl → MgCl2 + H2 (1)
Al2O3 + 6HCl → 2AlCl3 + 3H2O (2)
nH2 = 2,8/22,4 = 0,125 mol
Theo tỉ lệ phản ứng (1) => nMg = nH2 = 0,125 mol
<=> mMg = 0,125 .24 = 3 gam và mAl2O3 = 8,1 - 3 =5,1 gam
%mMg = \(\dfrac{3}{8,1}\).100% = 37,03% => %mAl2O3 = 100 - 37,03 = 62,97%
b) nAl2O3 = \(\dfrac{5,1}{102}\)= 0,05 mol
=> nHCl pư = 2nMg + 6nAl2O3 = 0,55 mol
mHCl = 0,55.36,5 = 20,075 gam
=> mdung dịch HCl 18% = \(\dfrac{20,075}{18\%}\)= 111,53 gam
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\) (2)
a) Ta có: \(\Sigma n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)
Gọi số mol của Mg là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)
Gọi số mol của Fe là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=b\)
Ta lập được hệ phương trình:
\(\left\{{}\begin{matrix}a+b=0,8\\24a+56b=25,6\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,6\\b=0,2\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,6mol\\n_{Fe}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,6\cdot24=14,4\left(g\right)\\m_{Fe}=11,2\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{14,4}{25,6}\cdot100\%=56,25\%\\\%m_{Fe}=43,75\%\end{matrix}\right.\)
b) Theo PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=1,2mol\\n_{HCl\left(2\right)}=2n_{Fe}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=1,6mol\) \(\Rightarrow V_{ddHCl}=\dfrac{1,6}{2}=0,8\left(l\right)=800ml\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
\(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\downarrow\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,6mol\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe\left(OH\right)_2}=0,2\cdot90=18\left(g\right)\\m_{Mg\left(OH\right)_2}=0,6\cdot58=34,8\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{kếttủa}=18+34,8=52,8\left(g\right)\)
Tiếp bài của creeper nhé:
c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)
Theo PT(1): \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)
Theo PT(2): \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)
=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)
=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)
=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)
Theo đề, ta có:
\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)
=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)
a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2<---0,6<--------------0,3
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,2.27}{15,6}.100\%=34,615\%\\\%Al_2O_3=\dfrac{15,6-0,2.27}{15,6}.100\%=65,385\%\end{matrix}\right.\)
b) \(n_{Al_2O_3}=\dfrac{15,6-0,2.27}{102}=0,1\left(mol\right)\)
PTHH: Al2O3 + 6HCl --> 2AlCl3 + 3H2O
______0,1--->0,6
=> nHCl = 0,6+0,6 = 1,2(mol)
=> \(V_{dd}=\dfrac{1,2}{2}=0,6\left(l\right)\)