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\(n_{NaOH}=0.015\cdot2=0.03\left(mol\right)\)
\(n_{H_2SO_4}=0.015\cdot1.5=0.0225\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.03..........0.015...........0.015\)
\(n_{H_2SO_4\left(dư\right)}=0.0225-0.015=0.0075\left(mol\right)\)
\(C_{M_{Na^+}}=\dfrac{0.015\cdot2}{0.015+0.015}=1\left(M\right)\)
\(C_{M_{H^+}}=\dfrac{0.0075\cdot2}{0.015+0.015}=0.5\left(M\right)\)
\(C_{M_{SO_4^{2-}}}=\dfrac{0.015+0.0075}{0.015+0.015}=0.75\left(M\right)\)
\(n_{NaOH}=\dfrac{12}{40}=0.3\left(mol\right)\)
\(n_{H_2SO_4}=0.1\cdot1=0.1\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
\(0.2..............0.1................0.1\)
\(m_A=m_{Na_2SO_4}+m_{NaOH\left(dư\right)}=0.1\cdot142+\left(0.3-0.2\right)\cdot40=18.2\left(g\right)\)
câu 1 : ta có : \(\dfrac{2NaOH}{0,03}\dfrac{+}{ }\dfrac{H_2SO_4}{0,0225}\dfrac{\rightarrow}{ }\dfrac{Na_2SO_4}{ }\dfrac{+}{ }\dfrac{2H_2O}{ }\)
\(\Rightarrow NaOH\) phản ứng hết và \(H_2SO_4\) dư \(0,0075\left(mol\right)\)
\(\Rightarrow\dfrac{H_2SO_4}{0,0075}\dfrac{\rightarrow}{ }\dfrac{2H^+}{0,015}\dfrac{+}{ }\dfrac{SO_4^{2-}}{ }\) \(\Rightarrow\left[H^+\right]=\dfrac{0,015}{0,03}=0,5\)
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câu 2 : ta có : \(\dfrac{2KOH}{0,1}\dfrac{+}{ }\dfrac{H_2SO_4}{0,05}\dfrac{\rightarrow}{ }\dfrac{k_2SO_4}{0,05}\dfrac{+}{ }\dfrac{2H_2O}{0,1}\)
\(\Rightarrow m_{chấtrắng}=m_{K_2SO_4}+m_{KOH_{dư}}\) \(\Leftrightarrow m_{KOH_{dư}}=m_{chấtrắng}-m_{K_2SO_4}\)
\(\Leftrightarrow m_{KOH_{dư}}=11,5-0,05.174=2,8\)
\(\Rightarrow m_{KOH}=0,1.56+2,8=3,36\) \(\Rightarrow n_{KOH}=\dfrac{3,36}{56}=0,06\)
\(\Rightarrow C_M=\dfrac{0,06}{0,15}=0,4\left(M\right)\)
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