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https://hoc24.vn/cau-hoi/cho-324-g-al-tac-dung-voi-oxi-vua-du-th-duoc-al2o3-a-tinh-vo2-b-tinh-m-al2o3-c-trong-vkk-can-dung-biet-vo2-21-vkk-d-tinh-khoi-luong-kmno.7651142171785
\(n_{H_2}=\dfrac{V}{24,79}=\dfrac{11,2}{24,79}\approx0,45\left(mol\right)\)
a) \(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
2 1 2
0,45 0,225 0,45
b) \(m_{O_2}=n.M=0,225.\left(16.2\right)=7,2\left(g\right)\\ V_{O_2}=n.24,79=0,225.24,79=5,57775\left(l\right)\)
c) \(PTHH:2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
2 1 1 1
0,45 0,225 0,225 0,225
\(m_{KMnO_4}=n.M=0,45.\left(39+55+16.4\right)=71,1\left(g\right).\)
a, \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{O_2}=0,25.32=8\left(g\right)\)
\(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,5\left(mol\right)\Rightarrow m_{KMnO_4}=0,5.158=79\left(g\right)\)
a.\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\)
0,1 0,05 ( mol )
\(V_{kk}=\left(0,05.22,4\right).5=5,6l\)
b.\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
1/30 0,05 ( mol )
\(m_{KClO_3}=\dfrac{1}{30}.122,5=4,08g\)
a, PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
Ta có: \(n_{Al}=\dfrac{10,2}{27}=\dfrac{17}{45}\left(mol\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=\dfrac{17}{60}\left(mol\right)\)
\(\Rightarrow V_{O_2}=\dfrac{17}{60}.22,4\approx6,347\left(l\right)\)
c, Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{17}{90}\left(mol\right)\)
\(\Rightarrow m_{Al_2O_3}=\dfrac{17}{90}.102\approx19,267\left(g\right)\)
d, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=\dfrac{17}{30}\left(mol\right)\)
\(\Rightarrow m_{KMnO_3}=\dfrac{17}{30}.158\approx89,53\left(g\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
a) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$
Theo PTHH : $n_{O_2} = \dfrac{3}{4}n_{Al} = 0,15(mol)$
$V_{O_2} = 0,15.22,4 = 3,36(lít)$
b) $2 KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,1(mol)$
$m_{KClO_3} = 0,1.122,5 = 12,25(gam)$
\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)
tỉ lệ: 4 : 3 : 2
n(mol) 0,2---->0,15---->0,1
\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ PTHH:2KClO_3-^{t^o}>2KCl+3O_2\)
tỉ lệ: 2 : 2 : 3
n(mol) 0,1<-------------------------0,15
\(m_{KClO_3}=n\cdot M=0,1\cdot\left(39+35,5+16\cdot3\right)=12,25\left(g\right)\)
PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
Ta có: \(n_{Al}=\dfrac{3,24}{27}=0,12\left(mol\right)\)
a, \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,09\left(mol\right)\) \(\Rightarrow V_{O_2}=0,09.22,4=2,016\left(l\right)\)
b, \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,06\left(mol\right)\) \(\Rightarrow m_{Al_2O_3}=0,06.102=6,12\left(g\right)\)
c, \(V_{kk}=\dfrac{2,016}{21\%}=9,6\left(l\right)\)
d, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,18\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=0,18.158=28,44\left(g\right)\)
a.\(n_{Al_2O_3}=\dfrac{30,6}{102}=0,3mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,6 0,45 0,3 ( mol )
\(m_{Al}=0,6.27=16,2g\)
\(V_{O_2}=0,45.22,4=10,08l\)
\(V_{kk}=10,08.5=50,4l\)
b.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,3 0,45 ( mol )
\(m_{KClO_3}=0,3.122,5=36,75g\)
c.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,3 0,45 ( mol )
\(n_{KClO_3}=\dfrac{0,3}{75\%}=0,4mol\)
\(m_{KClO_3}=0,4.122,5=49g\)
\(n_{Al}=\dfrac{6,75}{27}=0,25mol\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
0,25 0,15 0
0,2 0,15 0,1
0,05 0 0,1
\(m_{dư}=m_{Aldư}=0,05\cdot27=1,35g\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,3 0,15
\(m_{KMnO_4}=0,3\cdot158=47,4g\)