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Gọi a,b lần lượt là số mol của Al, Fe trong hỗn hợp ban đầu
=> 27a+56b=8,3 (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\)
Ta có quá trình trao đổi elcetron
\(Al^0\rightarrow Al^{+3}+3e\)
a----------------3a--(mol)
\(Fe^0\rightarrow Fe^{+2}+2e\)
b----------------2b--(mol)
\(2H^{-1}+2e\rightarrow H_2^0\)
----------0,5------0,25-(mol)
Áp dụng định luật bảo toàn e ta có: 3a+2b=0,5 (2)
Giải hệ phương trình gồm (1) và (2) ta được: \(\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\left[{}\begin{matrix}m_{Al}=0,1\cdot27=2,7g\\m_{Fe}=0,1\cdot56=5,6g\end{matrix}\right.\)
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\(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe}=5,6\left(g\right)\)
\(\Rightarrow m_{Fe_2O_3}=16\left(g\right)\)
\(\Rightarrow n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)=n_{FeCl_3}\)
Lại có : \(n_{HCl}=2n_{H_2}+3n_{FeCl_3}=0,8\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=292\left(g\right)\)
\(\Rightarrow V=\dfrac{2920}{11}\left(ml\right)=\dfrac{73}{275}\left(l\right)\)
\(\Rightarrow C_{MFeCl_3}=\dfrac{0,2}{\dfrac{73}{275}}=\dfrac{55}{73}\left(M\right)\)
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\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=8,3\\ 1,5a+b=\dfrac{5,6}{22,4}=0,25\\ a=b=0,1\\ m_{Al}=27\cdot0,1=2,7g\\ m_{Fe}=8,3-2,7=5,6g\\ a=\dfrac{3a+2b}{500}\cdot36,5=3,65\%\\ m_{ddsau}=508,3-0,25\cdot2=507,8g\\ C\%_{AlCl_3}=\dfrac{133,5a}{507,8}=2,63\%\\ C\%_{FeCl_2}=\dfrac{127b}{507,8}=2,50\%\)
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nH2 = 6,72/22,4 = 0,3 (mol)
PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2
nAl = 0,3 : 3 . 2 = 0,2 (mol)
nHCl (Al) = 0,3 . 2 = 0,6 (mol)
mAl = 0,2 . 27 = 5,4 (g)
%mAl = 5,4/25,65 = 20,05%
%mZnO = 100% - 20,05% = 79,95%
mZnO = 25,65 - 5,4 = 20,25 (g)
nZnO = 20,25/81 = 0,25 (mol)
PTHH: ZnO + 2HCl -> ZnCl2 + H2O
nHCl (ZnO) = 0,25 . 2 = 0,5 (mol)
nHCl (đã dùng) = 0,6 + 0,5 = 1,1 (mol)
CMddHCl = 1,1/0,1008 = 10,9M
C% = (10,9 . 36,5)/(10 . 1,19) = 33,43%
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$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$
$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$
$\Rightarrow n_{Al}=0,15(mol)$
$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$
$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$
$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$
$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$
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a) \(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=2.\dfrac{11,16}{62}=0,32\left(mol\right)\)
\(C\%_{NaOH}=\dfrac{0,32.40}{11,16+88,84}.100=12,8\%\)
b) \(n_{Fe}=\dfrac{4,48}{56}=0,08\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=n_{Fe}=0,08\left(mol\right)\\ \Rightarrow V_{H_2}=0,08.22,4=1,792\left(lít\right)\)
\(n_{HCl}=2n_{Fe}=0,16\left(mol\right)\)
\(m_{ddHCl}=\dfrac{0,16.36,5}{7,3\%}=80\left(g\right)\)
\(n_{FeCl_2}=n_{Fe}=0,08\left(mol\right)\\ m_{ddsaupu}=4,48+80-0,08.2=84,32\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{0,08.127}{84,32}.100=12,05\%\)
\(Đặt:n_{Al}=a\left(mol\right),n_{Fe}=b\left(mol\right)\)
\(m_{hh}=27a+56b=8.3\left(g\right)\left(1\right)\)
\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Tathấy:\)
\(n_{HCl}=2n_{H_2}=2\cdot0.25=0.5\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0.5}{0.2}=2.5\left(l\right)\)
\(n_{H_2}=1.5a+b=0.25\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=b=0.1\)
\(C_{M_{AlCl_3}}=\dfrac{0.1}{2.5}=0.04\left(M\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.1}{2.5}=0.04\left(M\right)\)
Chúc em học tốt !!!
a, Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{0,5}{0,2}=2,5\left(l\right)\)
b, Giả sử: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
⇒ 27x + 56y = 8,3 (1)
Các quá trình:
\(Al^0\rightarrow Al^{+3}+3e\)
x___________ 3x (mol)
\(Fe^0\rightarrow Fe^{+2}+2e\)
y____________2y (mol)
\(2H^++2e\rightarrow H_2^0\)
______0,5__0,25 (mol)
Theo ĐLBT mol e, có: 3x + 2y = 0,5 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
BTNT Al và Fe, có: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\n_{FeCl_3}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow C_{M_{AlCl_3}}=C_{M_{FeCl_3}}=\dfrac{0,1}{2,5}=0,04M\)
Bạn tham khảo nhé!