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a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
\(n_{C_2H_2}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ a,2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\\ b,n_{CO_2}=0,125.2=0,25\left(mol\right)\\ m_{CO_2}=0,25.44=11\left(g\right)\\ c,n_{O_2}=\dfrac{5}{2}.0,125=0,3125\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,3125.22,4=7\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=\dfrac{100}{20}.7=35\left(l\right)\)
CH4+2O2-to>CO2+2H2O
0,2-----0,4------0,2
n CH4=0,2 mol
=>mCO2=0,2.44=8,8g
=>VO2=0,4.22,4=8,96l
=>Vkk=8,96.5=44,8l
nCH4 = 4,48:22,4 = 0,2 (mol)
pthh : CH4 + 2O2 -t-> CO2 + 2H2O
0,2 0,4 0,2
mCO2 = 0,2 . 44 = 8,8 (G)
VO2 = 0,4 . 22,4 = 8,96 (L)
=> Vkk = VO2 : 20% = 8,96 : 20% = 44,8 (L)
a)
$n_{Br_2} = \dfrac{160.15\%}{160} = 0,15(mol)$
$C_2H_4 + Br_2 \to C_2H_4Br_2$
Ta thấy : $n_{C_2H_4} = 0,2 > n_{Br_2} = 0,15$ nên $C_2H_4$ dư
$n_{C_2H_4Br_2} = n_{Br_2} = 0,15(mol) \Rightarrow m_{C_2H_4Br_2} = 0,15.188 = 28,2(gam)$
b) $n_{C_2H_4\ dư} = 0,2 - 0,15 = 0,05(mol) \Rightarrow V_{C_2H_4} = 0,05.22,4 = 1,12(lít)$
$C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O$
Theo PTHH :
$V_{CO_2} =2 V_{C_2H_4} = 2,24(lít)$
$V_{O_2} = 3V_{C_2H_4} = 3,36(lít) \Rightarrow V_{kk} = 5V_{O_2} = 16,8(lít)$
\(n_{P_2O_5}=\dfrac{28,4}{142}=0,2\left(mol\right)\)
\(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,4<--------------0,2
S + O2 --to--> SO2
0,25<----------0,25
=> \(\left\{{}\begin{matrix}\%m_P=\dfrac{0,4.31}{0,4.31+0,25.32}.100\%=60,78\%\\\%m_S=\dfrac{0,25.32}{0,4.31+0,25.32}.100\%=39,22\%\end{matrix}\right.\)
a) PTHH: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
b) Đặt \(n_{CH_4}=x\left(mol\right);n_{C_2H_4}=y\left(mol\right)\). Khi đó \(22,4x+22,4y=4,48\) \(\Leftrightarrow x+y=0,2\)
Từ PTHH \(\Rightarrow n_{O_2\left(1\right)}=2x\left(mol\right)\)\(;n_{O_2\left(2\right)}=3y\left(mol\right)\). Khi đó \(2x.22,4+3y.22,4=11,2\) \(\Leftrightarrow2x+3y=0,5\)
Vậy ta có \(\left\{{}\begin{matrix}x+y=0,2\\2x+3y=0,5\end{matrix}\right.\Leftrightarrow x=y=0,1\left(mol\right)\)
\(\Rightarrow\%V_{CH_4}=\%V_{C_2H_4}=50\%\)
\(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
C2H4 + 3O2 ----to---> 2CO2 + 2H2O
0,4 1,2 0,8
\(m_{H_2O}=0,8.18=14,4\left(g\right)\)
\(V_{kk}=5V_{O_2}=5.1,2.22,4=134,4\left(l\right)\)
Bài 2.
\(n_{C_2H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,2 > 0,3 ( mol )
0,3 0,24 0,12 ( mol )
\(m_{CO_2}=0,24.44=10,56g\)
\(m_{H_2O}=0,12.18=2,16g\)
PTHH: 2CO + O2→2CO2
C2H4 + 3O2→ 2CO2 +2 H2O
nH2O= mM=\(\dfrac{1,8}{18}\)=0,1(mol)
nC2H4=\(\dfrac{1}{2}\).nH2O=\(\dfrac{1}{2}\).0,1=0,05(mol)
=> VC2H4=n.22,4=0,05.22,4=1,12(lít)
->VCO=4,48 − 1,12= 3,36(lít)
b) nCO2 (1)=nCO=\(\dfrac{3,36}{22,4}\)=0,15(mol)
mCO2 (1)=n.M=0,15.44=6,6(g)
nCO2 (2)=2.nC2H4=2.0,05=0,1(mol)
mCO2 (2)=n.M=0,1.44=4,4(g)
mCO2 sau pư=6,6 + 4,4= 11(g)