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PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
a) \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,25-------------------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b)
PTHH: CuO + H2 --to--> Cu + H2O
0,25--->0,25
=> mCu = 0,25.64 = 16 (g)
a) \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,25----------------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,25}{1}\) => CuO hết, H2 dư
PTHH: CuO + H2 --to--> Cu + H2O
0,2-------------->0,2
=> mCu = 0,2.64 = 12,8 (g)
Zn+2HCl->Zncl2+H2
0,4----0,8----0,4----0,4
n Zn=0,4 mol
VH2=0,4.22,4=8,96l
m ZnCl2=0,4.136=54,4g
2H2+O2-to>2H2O
0,4------0,2----0,4
n O2=0,2 mol
=>pứ hết
=>m H2O=0,4.18=7,2g
a.b.\(n_{Zn}=\dfrac{26}{65}=0,4mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,4 0,4 0,4 ( mol )
\(m_{ZnCl_2}=0,4.136=54,4g\)
\(V_{H_2}=0,4.22,4=8,96l\)
c.\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(2H_2+O_2\rightarrow\left(t^o\right)2H_2O\)
0,4 = 0,2 ( mol )
0,4 0,2 0,4 ( mol )
\(m_{H_2O}=0,4.18=7,2g\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
c, \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Theo PT: \(n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Cu}=0,1.64=6,4\left(g\right)\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,2_____0,4____0,2____0,2 (mol)
a, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
c, \(m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
___0,2____0,2 (mol)
\(\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 0,2
\(\rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\V_{H_2}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
LTL: \(\dfrac{0,2}{2}< 0,2\rightarrow\) O2 dư
\(V_{O_2\left(dư\right)}=\left(0,2-0,1\right).22,4=2,24\left(l\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,2 0,2 0,2
\(m_{Cu}=0,2.654=12,8\left(g\right)\)