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\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)
\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(3.........2\)
\(0.225......0.1875\)
Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)
\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)
nP= 7,44/31=0,24(mol)
nO2=6,16/22,4=0,275(mol)
PTHH:4 P + 5 O2 -to->2 P2O5
Ta có: 0,24/4 > 0,275/5
=> O2 hết, P dư, tính theo nO2
nP(p.ứ)= 0,275 x 4/5= 0,22(mol)
=>nP(dư)=0,24-0,22=0,02(mol)
=>mP(dư)=0,02.31= 0,62(g)
nP2O5= 2/5 x 0,275= 0,11(mol)
=> mP2O5= 142 x 0,11= 15,62(g)
\(n_P=\dfrac{7,44}{31}=0,24\left(mol\right)\)
\(n_{O_2}=\dfrac{6,16}{22,4}=0,275\left(mol\right)\)
PTHH : \(4P+5O_2\rightarrow2P_2O_5\)
Ban đầu : 0,24 0,275 (mol)
Phản ứng : 0,22 0,275 0,11 (mol)
Sau phản ứng : 0,02 0 0,11 (mol)
\(m_P=0,02.31=0,62\left(g\right)\)
\(m_{P_2O_5}=0,11.142=15,62\left(g\right)\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
\(4........5\)
\(0.2.........0.4\)
Lập tỉ lệ : \(\dfrac{0.2}{4}< \dfrac{0.4}{5}\Rightarrow O_2dư\)
\(n_{P_2O_5}=0.2\cdot\dfrac{2}{4}=0.1\left(mol\right)\)
\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)
\(m_{P_2O_5\left(tt\right)}=14.2\cdot80\%=11.36\left(g\right)\)
Bài 1:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{3}< \dfrac{0,1}{2}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,1-\dfrac{1}{15}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\dfrac{1}{30}.32\approx1,067\left(g\right)\\V_{O_2\left(dư\right)}=\dfrac{1}{30}.2,24\approx0,746\left(l\right)\end{matrix}\right.\)
b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
Bài 2:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}.232\approx15,467\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow V_{O_2}=\dfrac{2}{15}.22,4\approx2,9867\left(l\right)\)
c, PT: \(2N_2+5O_2\underrightarrow{t^o}2N_2O_5\)
Ta có: \(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{2}>\dfrac{\dfrac{2}{15}}{5}\), ta được N2 dư.
Theo PT: \(n_{N_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{4}{75}\left(mol\right)\)
\(\Rightarrow m_{N_2O_5}=\dfrac{4}{75}.108=5,76\left(g\right)\)
Bạn tham khảo nhé!
Bài 1 :
\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{2.24}{224}=0.1\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(Bđ:0.1......0.1\)
\(Pư:0.1.......\dfrac{1}{15}...\dfrac{1}{30}\)
\(Kt:0........\dfrac{1}{30}....\dfrac{1}{30}\)
\(V_{O_2\left(dư\right)}=\dfrac{1}{30}\cdot22.4=0.747\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7.73\left(g\right)\)
Bài 2 :
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(0.2.......0.3.......\dfrac{1}{15}\)
\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{15}\cdot232=15.47\left(g\right)\)
\(n_{N_2}=\dfrac{2.8}{28}=0.1\left(mol\right)\)
\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)
\(0.12......0.3........0.12\)
\(m_{N_2O_5}=0.12\cdot108=12.96\left(g\right)\)
$a) CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
b) $n_{CH_4} = \dfrac{3,92}{22,4} = 0,175(mol)$
$n_{O_2} = \dfrac{3,84}{32} = 0,12(mol)$
Ta thấy : $n_{CH_4} : 1 > n_{O_2} : 2$ nên $CH_4$ dư
$n_{CH_4\ pư} = \dfrac{1}{2}n_{O_2} = 0,06(mol)$
$\Rightarrow m_{CH_4\ dư} = (0,175 - 0,06).16 = 1,84(gam)$
c) $2NaOH + CO_2 \to Na_2CO_3 + H_2O$
Theo PTHH :
$n_{Na_2CO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_4} = 0,06(mol)$
$m_{Na_2CO_3} = 0,06.106 = 6,36(gam)$
\(n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ a.PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
4 3 2
0,4 0,3 0,2
\(m_{Al_2O_3}=n.M=0,2.\left(27.2+16.3\right)=20,4\left(g\right)\\ c.V_{O_2}=n.24,79=0,3.24,79=7,437\left(l\right)\)
\(d.n_{O_2}=\dfrac{m}{M}=\dfrac{12,8}{\left(16.2\right)}=0,4\left(mol\right)\\ PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
4 3 2
0,53 0,4 0,27
Tỉ lệ: \(\dfrac{0,53}{4}< \dfrac{0,4}{3}< \dfrac{0,27}{2}\Rightarrow Al_2O_3\) dư và dư \(m_{Al_2O_3}=n.M=0,27.\left(27.2+16.3\right)=27,54\left(g\right).\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\Rightarrow m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)
c, \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
d, \(n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,4}{4}< \dfrac{0,4}{3}\), ta được O2 dư.
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
Ta có PTHH:
\(2Cu+O_2\rightarrow2CuO\)
Ta có số mol của các chất :
\(n_{Cu}=\frac{m_{Cu}}{M_{Cu}}=\frac{12,8}{64}=0,2\left(mol\right)\)
\(n_{O_2}=\frac{V_{O_2}}{22,4}=\frac{11,2}{22,4}=0,5\left(mol\right)\)
\(\Rightarrow\frac{n_{Cu}}{2}=\frac{0,2}{2}< \frac{0,5}{1}=\frac{n_{O_2}}{1}\)
\(\Rightarrow\)Cu hết, O2 dư
\(\Rightarrow\)Tính theo Cu
Ta viết lại PTHH theo tỉ số các chất ;
\(2Cu+O_2\rightarrow2CuO\)
Ban đầu: \(0,2\) \(0,5\) \(0\)
Phản ứng: \(0,2\) \(0,1\) \(0,2\)
Sau phản ứng: \(0\) \(0,4\) \(0,2\)
\(\Rightarrow\)Khối lượng chất tạo thành là :
\(m_{CuO}=n_{CuO}.M_{CuO}=0,2.80=16\left(g\right)\)
3Fe+2O2-to>Fe3O4
0,1----1\15--------1\30
n Fe=\(\dfrac{5.6}{56}\)=0,1 mol
n O2=\(\dfrac{2,24}{22,4}\)=0,1 mol
=>O2 dư
=>m O2du=(0,1-\(\dfrac{1}{15}\)).32=1,067g
=>m Fe3O4=\(\dfrac{1}{30}.232=7,73g\)
phần nào là a phần nào là b phần nào là c ạ