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\(n_{Na_2SO_4}=\dfrac{142.10}{100.142}=0,1(mol)\\ Na_2SO_4+Ba(OH)_2\to BaSO_4\downarrow+2NaOH\\ \Rightarrow n_{BaSO_4}=n_{Ba(OH)_2}=0,1(mol);n_{NaOH}=0,2(mol)\\ a,m_{BaSO_4}=0,1.233=23,3(g)\\ b,m_{dd_{Ba(OH)_2}}=\dfrac{0,1.171}{15\%}=114(g)\\ c,C\%_{NaOH}=\dfrac{0,2.40}{142+114-23,3}.100\%=3,44\%\)
Ta có: \(n_{Na_2SO_4}=\dfrac{\dfrac{10\%.142}{100\%}}{142}=0,1\left(mol\right)\)
\(PTHH:Na_2SO_4+Ba\left(OH\right)_2--->BaSO_4\downarrow+2NaOH\)
a. Theo PT: \(n_{BaSO_4}=n_{Ba\left(OH\right)_2}=n_{Na_2SO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)
b. Ta có: \(m_{Ba\left(OH\right)_2}=0,1.171=17,1\left(g\right)\)
Mà: \(C_{\%_{Ba\left(OH\right)_2}}=\dfrac{17,1}{m_{dd_{Ba\left(OH\right)_2}}}.100\%=15\%\)
\(\Leftrightarrow m_{dd_{Ba\left(OH\right)_2}}=114\left(g\right)\)
c. Ta có: \(m_{dd_{NaOH}}=114+14,2-23,3=104,9\left(g\right)\)
Theo PT: \(n_{NaOH}=2.n_{Ba\left(OH\right)_2}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,2.40=8\left(g\right)\)
\(\Rightarrow C_{\%_{NaOH}}=\dfrac{8}{104,9}.100\%=7,63\%\)
Bài 1 :
nNaOH = 0,6 (mol)
NaOH + HCl -> NaCl + H2O
0,6...........0,6........0,6 (mol)
mdd HCl = \(\frac{0,6.36,5}{7,3\%}=300\left(g\right)\)
\(C\%_{NaCl}=\frac{0,6.58,5}{300+200}.100\%=7,02\%\)
a.
\(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
b.
\(n_{BaCO_3}=n_{Na_2CO_3}=0,2.1=0,2\left(mol\right)\\ m_{kt}=197.0,2=39,4\left(g\right)\)
c.
\(n_{Ba\left(OH\right)_2}=n_{Na_2CO_3}=0,2\left(mol\right)\\ C\%_{Ba\left(OH\right)_2}=\dfrac{0,2.171.100\%}{200}=17,1\%\)
PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)
\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)
b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)
a, \(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Ba(OH)2 + CO2 → BaCO3 + H2O
Mol: 0,3 0,3 0,3
b, \(C_{M_{ddBa\left(OH\right)_2}}=\dfrac{0,3}{0,2}=1,5M\)
c, \(m_{BaCO_3}=0,3.197=59,1\left(g\right)\)
\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
nZnO=8,1/81=0,1(mol)
PTHH: ZnO + H2SO4 -> ZnSO4 + H2O
0,1________0,1_____0,1(mol)
a) mH2SO4=0,1.98=9,8(g)
=> mddH2SO4=(9,8.100)/10=98(g)
b) mZnSO4=0,1.161=16,1(g)
mddZnSO4=mZnO+ mddH2SO4= 8,1+98= 106,1(g)
=> C%ddZnSO4= (16,1/106,1).100= 15,174%
500ml=0.5l
nBaOH2 =0.5 x1=0.5 mol
MH2SO4=500.15%=75g
nH2SO4= xấp xỉ 0.8mol
H2SO4 dư tính theo BaOH2
pthh: Ba(OH)2 + H2SO4 => BaSO4+H2O
Theo pthh nBaSO4= nBa(OH)2=0.5mol
=>m kết tủa= 0.5x233=116.5g
theo pthh nH2SO4 phản ứng=nBaOH2= 0.5 mol
=> nH2SO4 Dư=0.8-0.5=0.3 mol
=>
m dư=0.3x98=29.4g
mH2SO4 đã dùng là m phản ứng? nếu thế thì m đã dung là 75-29.4=45.6
còn nếu m đã dùng là m chất tan thi là 75g như trên =))