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a) \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,2<--------------------0,2
=> mFe = 0,2.56 = 11,2 (g)
=> \(\%m_{Fe}=\dfrac{11,2}{24}.100\%=46,67\%\)
=> \(\%m_{Cu}=\dfrac{24-11,2}{24}.100\%=53,33\%\)
b) \(n_{Cu}=\dfrac{24-11,2}{64}=0,2\left(mol\right)\)
PTHH: 2Fe + 3Cl2 --to--> 2FeCl3
0,2-->0,3
Cu + Cl2 --to--> CuCl2
0,2-->0,2
=> \(V_{Cl_2}=\left(0,3+0,2\right).22,4=11,2\left(l\right)\)
a)\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0,2\) \(\leftarrow\) \(0,2\)
\(m_{Fe}=0,2\cdot56=11,2g\)
\(\%m_{Fe}=\dfrac{11,2}{24}\cdot100\%=46,67\%\)
\(\%m_{Cu}=100\%-46,67\%=53,33\%\)
b)\(n_{Fe}=0,2mol\)
\(\Rightarrow m_{Cu}=24-0,2\cdot56=12,8g\Rightarrow n_{Cu}=0,2mol\)
\(2Fe+3Cl_2\rightarrow2FeCl_3\)
0,2 0,3
\(Cu+Cl_2\rightarrow CuCl_2\)
0,2 0,2
\(\Sigma n_{Cl_2}=0,3+0,2=0,5mol\)
\(V=0,5\cdot22,4=11,2l\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right);n_{SO_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
0,2------------------------>0,2
\(2Fe+6H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
0,2---------------------------------------->0,3
\(Cu+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}CuSO_4+SO_2+2H_2O\)
0,15<--------------------------------0,15
=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{0,2.56+0,15.64}.100\%=53,85\%\\\%m_{Cu}=100\%-53,85\%=46,15\%\end{matrix}\right.\)
15
a)\(Fe+H2SO4-->FeSO4+H2\)
\(n_{H2}=\frac{33,6}{22,4}=1,5\left(mol\right)\)
\(n_{Fe}=n_{H2}=1,5\left(mol\right)\)
\(m_{Fe}=1,5.56=84\left(g\right)\)
b)\(n_{FeSO4}=n_{H2}=1,5\left(mol\right)\)
\(m=m_{FeSO4}=1,5.152=228\left(g\right)\)
c)\(n_{H2SO4}=n_{H2}=1,5\left(mol\right)\)
\(C_{M\left(H2SO4\right)}=\frac{1,5}{0,5}=3\left(M\right)\)
16.
n\(_{H2}=\frac{2,24}{22,4}=0,1\left(mol\right)\)
Gọi \(n_{Mg}=x,n_{Fe}=y\)
\(Mg+2HCl--.MgCl2+H2\)
x-------------------------x----------x(mol)
\(Fe=2HCl-->FeCl2+H2\)
y----------------------------y------y(mol)
Theo bài ta có hpt
\(\left\{{}\begin{matrix}24x+56y=4\\x+y=0,1\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)
\(m_{MgCl2}=0,05.95=4,75\left(g\right)\)
\(m_{FeCl2}=0,05.127=6,35\left(g\right)\)
17.
\(n_{H2}=\frac{13,44}{22,4}=0,6\left(mol\right)\)
\(Fe+2HCl--.FeCl2+H2\)
x----------------------------------x(mol)
\(2Al+6HCl--.2AlCl3+3H2\)
y----------------------------------------1,5y(mol)
theo bài ta có hpt
\(\left\{{}\begin{matrix}56x+27y=22,2\\x+1,5y=0,6\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\frac{0,3.56}{22,2}.100\%=75,68\%\%\)
\(\%m_{Al}=100-75,68=24,32\%\)
18.
\(Mg+2HCl--.MgCl2+H2\)
\(Fe+2HCl--.FeCl2+H2\)
Chất rắn k tan là Cu = 2,54(g)
=>\(m_{Mg+Fe}=10,54-02,54=10\left(g\right)\)
\(n_{H2}=\frac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow m_{H2}=0,4\left(g\right)\)
\(n_{HCl}=n_{H2}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m=m_{Fe+Mg}+m_{HCl}-m_{H2}=10+14,6-0,4=24,2\left(g\right)\)
\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\
Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(n_{Fe_2O_3}=\dfrac{21,6-56.0,1}{160}=0,1mol\\
Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2\)
0,1 0,6 0,2 0,3
\(V_{ddHCl}=\dfrac{0,2+0,6}{1}=0,8l\\
b.C_{M_{FeCl_2}}=\dfrac{0,1}{0,8}=0,125M\\
C_{M_{FeCl_3}}=\dfrac{0,2}{0,8}=0,25M\)
úi ùi ms lm dc 2 ceo:>
1.
a,\(BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
b, \(3Cu+8HNO_3\rightarrow3Cu\left(NO_3\right)_2+2NO\uparrow+H_2O\)
c, \(2NaOH+Ca\left(HSO_3\right)_2\rightarrow CaSO_3\downarrow+Na_2SO_3+2H_2O\)