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14/
\(2KMnO_4\rightarrow KMnO_2+MnO_2+O_2\uparrow\)
\(nO_2=\dfrac{13,95}{24,79}=0,6\left(mol\right)\)
\(\Rightarrow nO_2=\dfrac{1}{2}nKMnO_4\Rightarrow nKMnO_4=0,12\left(mol\right)\)
\(mKMnO_4=0,12.\left(39+55+16.4\right)=18,96\left(g\right)\)
15/
\(nCu=\dfrac{12,8}{64}=0,2\left(mol\right)\)
\(nO_2=\dfrac{8,37}{24,79}=0,3\left(mol\right)\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(Xéttỉlệ:\) \(\dfrac{nCu}{2}< \dfrac{nO_2}{1}\left(\dfrac{0,2}{2}=0,1< \dfrac{0,3}{1}=0,3\right)\)
=> O2 dư ; Cu đủ với pứ
Tính sô mol của CuO theo số mol của Cu
=> \(nCuO=nCu=0,2\left(mol\right)\)
\(\Rightarrow mCuO=0,2.\left(64+16\right)=16\left(g\right)\)
Cảm ơn bạn @anayuiky đã nhắc lỗi sai. Mình sửa lại ý c):
PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo phương trình \(n_{KMnO_4}=n_{O_2}.2=0,25.2=0,5mol\)
\(\rightarrow m_{KMnO_4}=0,5.\left(39+55+16.4\right)=79g\)
a. \(n_{H_2}=\frac{V}{22,4}=\frac{11,2}{22,4}=0,5mol\)
\(n_{O_2}=\frac{V}{22,4}=\frac{10,08}{22,4}=0,45mol\)
PTHH: \(2H_2+O_2\rightarrow^{t^o}2H_2O\)
Ban đầu: 0,5 0,45 mol
Trong pứng: 0,5 0,25 0,5 mol
Sau pứng: 0 0,2 0,5 mol
\(\rightarrow M_{O_2\left(dư\right)}=n.M=0,2.32=6,4g\)
b. Theo phương trình \(n_{H_2O}=n_{H_2}=0,5mol\)
\(\rightarrow m_{H_2O}=n.M=0,5.18=9g\)
c. PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9 0,45 mol
\(\rightarrow n_{KMnO_4}=\frac{2}{1}n_{O_2}=\frac{0,45.2}{1}=0,9mol\)
\(\rightarrow m_{KMnO_4}=n.M=0,9.158=142,2g\)
Câu 6.
\(n_{O_2}=\dfrac{16,8}{22,4}=0,75mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
1,5 0,75
\(m_{KMnO_4}=1,5\cdot158=237g\)
Câu 7.
\(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,04 0,02
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\dfrac{2}{75}\) 0,04
\(m_{KClO_3}=\dfrac{2}{75}\cdot122,5=\dfrac{49}{15}\approx3,27g\)
a. \(n_{Fe_3O_4}=\dfrac{6,96}{232}=0,03\left(mol\right)\)
PTHH : 3Fe + 2O2 -to-> Fe3O4
0,09 0,06 0,03
\(m_{Fe}=0,09.56=5,04\left(g\right)\)
\(V_{O_2}=0,06.22,4=1,344\left(l\right)\)
b. PTHH : 2KCl + 3O2 -> 2KClO3
0,06 0,04
\(m_{KClO_3}=0,04.122,5=4,9\left(g\right)\)
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{CuO}=n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right);n_{O_2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ V_{kk\left(đktc\right)}=\dfrac{100.1,12}{20}=5,6\left(l\right)\\ b,m_{CuO}=0,1.80=8\left(g\right)\\ c,2R+O_2\rightarrow\left(t^o\right)2RO\\ n_R=2.n_{O_2}=2.0,05=0,1\left(mol\right)\\ M_R=\dfrac{2,4}{0,1}=24\left(\dfrac{g}{mol}\right)\\ \Rightarrow R:Magie\left(Mg=24\right)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
Theo PT: \(n_{Fe}=3n_{Fe_3O_4}=0,03\left(mol\right)\Rightarrow m_{Fe}=0,03.56=1,68\left(g\right)\)
\(n_{O_2}=2n_{Fe_3O_4}=0,02\left(mol\right)\Rightarrow m_{O_2}=0,02.32=0,64\left(g\right)\)
b, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,04\left(mol\right)\Rightarrow m_{KMnO_4}=0,04.158=6,32\left(g\right)\)
a) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,45}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25----->0,5
=> \(m_{O_2\left(dư\right)}=\left(0,45-0,25\right).32=6,4\left(g\right)\)
b) \(m_{H_2O}=0,5.18=9\left(g\right)\)
c)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
