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\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)
\(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)
b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)
c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)
nZnCl2 =40,8/136=0,3mol
nNaOH= 0,1.0,5=0,05mol
a)
pt : ZnCl2 + 2NaOH ------> Zn(OH)2\(\downarrow\) + 2NaCl
ncó: 0,3 0,05
n pứ: 0,025<------0,05-------->0,025-------->0,05
n dư: 0,275 0
b)
mZnCl2 dư = 0,275.136=37,4g
mNaCl=0,05.58,5=2,925g
c)
pt : Zn(OH)2 ---to--> ZnO + H2O
n pứ : 0,025------------>0,025
mZnO=0,025.81=2,025g
d)
vdd sau pứ =Vdd NaOH =0,1l
CM(ZnCl2 dư )=0,025/0,1=0,25M
CM(NaOH)=0,05/0,1= 0,5M
a, \(CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(n_{CuCl_2}=\dfrac{20,25}{135}=0,15\left(mol\right)\)
Theo PT: \(n_{KOH}=2n_{CuCl_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,3}{0,3}=1\left(M\right)\)
c, \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,15\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,15.80=12\left(g\right)\)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
1
\(n_{CuCl_2}=0,2.0,5=0,1\left(mol\right)\\ n_{NaOH}=0,5.0,5=0,25\left(mol\right)\)
a. \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,1------->0,2------------>0,1---------->0,2
b. Xét \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\) => NaOH dư
=> \(m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
c. \(n_{NaOH.dư}=0,25-0,2=0,05\left(mol\right)\)
Các chất có trong nước lọc:
\(CM_{NaOH}=\dfrac{0,05}{0,2+0,5}=\dfrac{1}{14}\approx0,07M\)
\(CM_{NaCl}=\dfrac{0,2}{0,2+0,5}=\dfrac{2}{7}\approx0,29M\)
2
\(n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ n_{NaOH}=\dfrac{150.8\%}{100\%}:40=0,3\left(mol\right)\)
a. \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,15<-------0,3--------->0,15------->0,3
b. Xét \(\dfrac{0,2}{1}>\dfrac{0,3}{2}\) => \(CuCl_2\) dư
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,15.98=14,7\left(g\right)\)
c. \(m_{dd}=27+150=177\left(g\right)\)
Các chất có trong nước lọc:
\(C\%_{CuCl_2}=\dfrac{\left(0,2-0,15\right).135.100\%}{177}=3,81\%\)
\(C\%_{NaCl}=\dfrac{0,3.58,5.100\%}{177}=9,92\%\)
3
\(n_{HCl}=0,3.1=0,3\left(mol\right)\\ n_{AgNO_3}=0,5.0,5=0,25\left(mol\right)\)
a. Hiện tượng: xuất hiện kết tủa trắng bạc clorua \(AgCl\)
b.
\(AgNO_3+HCl\rightarrow AgCl+HNO_3\)
0,25------->0,25----->0,25--->0,25
Xét \(\dfrac{0,25}{1}< \dfrac{0,3}{1}\)=> axit dư.
\(m_{kt}=m_{AgCl}=0,25.143,5=35,875\left(g\right)\)
c. Bạn xem đề đủ chưa, có thiếu D (khối lượng riêng) hay không rồi nói mình làm nhé: )