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\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
\(n_{Fe}=\dfrac{0.56}{56}=0.01\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.01.....0.02........0.01........0.01\)
\(V_{H_2}=0.01\cdot22.4=0.224\left(l\right)\)
\(V_{dd}=\dfrac{0.02}{1}=0.02\left(l\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.01}{0.02}=0.5\left(M\right)\)
Note : Đề sai hay thiếu chổ HCl ấy em.
\(n_{Fe}=\dfrac{0.56}{56}=0.01\left(mol\right)\)
\(n_{HCl}=0.1\cdot1=0.1\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có :
\(\dfrac{n_{Fe}}{1}< \dfrac{n_{HCl}}{2}\Rightarrow HCldư\)
Khi đó :
\(n_{Fe}=n_{FeCl_2}=n_{H_2}=0.01\left(mol\right)\)
\(V_{H_2}=0.01\cdot22.4=0.224\left(l\right)\)
\(b.\)
\(n_{HCl\left(dư\right)}=0.1-0.02=0.08\left(mol\right)\)
\(m_{HCl}=0.08\cdot36.5=2.92\left(\right)\)
\(c.\)
\(C_{M_{FeCl_2}}=\dfrac{0.01}{0.1}=0.1\left(M\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0.08}{0.1}=0.8\left(M\right)\)
\(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right);nHCl=0,1.1=0,1\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,1}{2}\\ \rightarrow HCldư\\ n_{H_2}=n_{Fe}=n_{FeCl_2}=0,01\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\\ V_{ddsau}=V_{ddHCl}=0,1\left(l\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\\ n_{HCl\left(dư\right)}=0,1-0,01.2=0,08\left(mol\right)\\ m_{HCl\left(dư\right)}=0,08.36,5=2,92\left(g\right)\\ C_{MddHCl\left(Dư\right)}=\dfrac{0,08}{0,1}=0,8\left(M\right)\)
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
a) Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)=n_{Fe}\)
\(\Rightarrow m_{Fe}=0,25\cdot56=14\left(g\right)\) \(\Rightarrow m_{Cu}=6\left(g\right)\)
b) Theo PTHH: \(n_{FeSO_4}=0,25mol\) \(\Rightarrow m_{FeSO_4}=0,25\cdot152=38\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,25\cdot98}{10\%}=245\left(g\right)\\m_{H_2}=0,25\cdot2=0,5\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{H_2SO_4}-m_{Cu}-m_{H_2}=258,5\left(g\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{38}{258,5}\cdot100\%\approx14,7\%\)
pthh : Fe +H2SO4 → FeSO4 +H2
theo bài ra số mol của h2 =0,15 (mol)
theo pt : nFe=nH2=0,15 (mol)
mFe=0,15 .56 =8,4 (g) ⇒mCu=20-8,4=11,6 (g)
a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)
\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)