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a, \(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1------------->0,5
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5----->0,5
b, \(V_{O_2}=1.22,4=22,4\left(l\right)\)
c, \(m_{CaCO_3}=0,5.100=50\left(g\right)\)
Quy đổi C4H4 thành C2H2
\(n_{CaCO_3}=\dfrac{20}{100}=0,2\left(mol\right)\)
PTHH: 2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,1<--0,25<--------0,2
Ca(OH)2 + CO2 --> CaCO3 + H2O
0,2<------0,2
=> \(m_X=0,1.26=2,6\left(g\right)\)
\(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
\(n_{hhkhí}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\)
PTHH:
CH4 + 2O2 \(\underrightarrow{t^o}\) CO2 + 2H2O
a 2a a
2C2H2 + 5O2 \(\underrightarrow{t^o}\) 4CO2 + 2H2O
b 2,5b 2b
Hệ phương trình: \(\left\{{}\begin{matrix}a+b=0,125\\2a+2,5b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,025\left(mol\right)\\b=0,1\left(mol\right)\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,1}{0,125}=80\%\\ \%_{CH_4}=100\%-80\%=20\%\)
nCO2 = 2.0,025 + 2.0,1 = 0,25 (mol)
PTHH: Ca(OH)2 + CO2 -> CaCO3 + H2O
0,25 0,25
=> mCaCO3 = 0,25.100 = 25 (g)
\(n_P=\dfrac{m}{M}=\dfrac{12,4}{31}=0,4\left(mol\right)\\ PTHH:4P+5O_2-^{t^o}>2P_2O_5\)
Tỉ lệ 4 : 5 : 2
n(mol) 0,4--->0,5----->0,2
\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,5\cdot22,4=11,2\left(l\right)\\ V_{kk}=11,2:\dfrac{1}{5}=56\left(l\right)\)
\(m_{P_2O_5}=n\cdot M=0,2\cdot142=28,4\left(g\right)\)
\(PTHH:P_2O_5+3H_2O->2H_3PO_4\)
tỉ lệ 1 : 3 : 2
n(mol) 0,2----->0,6--------->0,4
\(m_{H_3PO_4}=n\cdot M=0,4\cdot98=39,2\left(g\right)\)
\(C\%=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{39,2}{200}\cdot100\%=19,6\%\)
a, \(n_{C_2H_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=2n_{C_2H_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,1.100=10\left(g\right)\)
b, Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,15\left(mol\right)\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=16,8\left(l\right)\)
Đáp án B
Crackinh 0,2 mol C4H10 → hhX gồm 5 hiđrocacbon.
hhX qua bình Brom dư → mbình tăng = 8,4 gam
• Khí bay ra khỏi dung dịch Brom là hiđrocacbon no CT
→ nY = 0,2 mol, mhhY = 0,2 x 58 - 8,4 = 3,2 gam.
→ M = 16 → n = 1
→ VO2 = 22,4 x 0,4 = 8,96 lít
Theo gt ta có: $n_{O_2}=0,6(mol);n_{hh}=0,25(mol)$
a, $CH_4+2O_2\rightarrow CO_2+2H_2O$
$C_2H_4+3O_2\rightarrow 2CO_2+2H_2O$
Gọi số mol CH4 và C2H4 lần lượt là a;b(mol)
Ta có: $a+b=0,25;2a+3b=0,6\Rightarrow a=0,15;b=0,1$
b, Suy ra $\%V_{CH_4}=60\%;\%V_{C_2H_4}=40\%$
c, Ta có: $n_{CaCO_3}=n_{CO_2}=0,15+0,1.2=0,35(mol)\Rightarrow m_{CaCO_3}=35(g)$
\(a)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ b)\ V_{CH_4} = a(lít) ; V_{C_2H_4} = b(lít)\\ \Rightarrow a + b = 5,6(1)\\ V_{O_2} = 2a + 3b = 13,44(2)\\ (1)(2)\Rightarrow a = 3,36 ; b = 2,24\\ \%V_{CH_4} = \dfrac{3,36}{5,6}.100\% = 60\%\\ \%V_{C_2H_4} = 40\%\\ c) V_{CO_2} = a + 2b = 7,84(lít)\\\)
\(CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ \Rightarrow m_{CaCO_3} = 0,35.100 = 35(gam)\)
a, \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
b, \(n_{C_2H_4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,75\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,75.22,4=16,8\left(l\right)\)
c, \(n_{CO_2}=2n_{C_2H_4}=0,5\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,5.100=50\left(g\right)\)