Hòa tan hoàn toàn 13 gam kẽm tác dụng với H2SO4
a) Viết phương trình phản ứng hóa học b) Tính thể tích (đktc) khí hidro sinh ra.
thu được sau phản ứng.
c) Dẫn toàn bộ lượng khí thu được ở phản ứng trên qua 18,56 gam Fe3O4 nung nóng. Tính khối lượng sắt
mn giúp mik với ạ!mình cảm ơn
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a. \(n_{Zn}=\dfrac{6.5}{65}=0,1\left(mol\right)\)
PTHH : Zn + 2HCl -> ZnCl2 + H2
0,1 0,2 0,1
b. \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c. \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1
\(V_{H_2}=0,1\cdot22,4=2,24l\)
\(m_{HCl}=0,2\cdot36,5=7,3g\)
\(a,PTHH:Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+CO_2\uparrow\\ b,n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\\ \Rightarrow n_{Na_2SO_4}=0,1\left(mol\right)\\ \Rightarrow m_{Na_2SO_4}=0,1\cdot142=14,2\left(g\right)\\ c,n_{CO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\\ \Rightarrow V_{CO_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(d,n_{Ca\left(OH\right)_2}=0,5\cdot0,3=0,15\left(mol\right)\\ PTHH:CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)
Vì \(\dfrac{n_{Ca\left(OH\right)_2}}{1}>\dfrac{n_{CO_2}}{1}\) nên Ca(OH)2 dư, tính theo CO2
\(\Rightarrow n_{CaCO_3}=n_{CO_2}=0,1\left(mol\right)\\ \Rightarrow m_{CaCO_3}=0,1\cdot100\cdot80\%=8\left(g\right)\)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
c, \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{2}{15}.56=\dfrac{112}{15}\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\a, Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,V\text{ì}:\dfrac{0,2}{1}>\dfrac{0,1}{1}\Rightarrow Zn\text{dư}\\ \Rightarrow n_{Zn\left(p.\text{ứ}\right)}=n_{ZnCl_2}=n_{H_2}=0,1\left(mol\right)\\b, m_{Zn\left(p.\text{ứ}\right)}=0,1.65=6,5\left(g\right)\\ n_{HCl}=0,1.2=0,2\left(mol\right)\\ m_{HCl}=0,2.36,5=7,3\left(g\right)\\ d,m_{ZnCl_2}=136.0,1=13,6\left(g\right)\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{16,25}{65}=0,25\left(mol\right)\\ PTHH:Zn+H_2SO_4->ZnSO_4+H_2\)
tỉ lệ 1 : 1 : 1 : 1
n(mol) 0,25-->0,25------->0,25------>0,25
\(V_{H_2\left(dktc\right)}=n\cdot22,4=0,25\cdot22,4=5,6\left(l\right)\\ m_{ZnSO_4}=n\cdot M=0,25\cdot\left(65+32+16\cdot4\right)=40,25\left(g\right)\)
a,\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1--------------->0,1------>0,1
b, => \(\left\{{}\begin{matrix}C_{M\left(ZnCl_2\right)}=\dfrac{0,1}{\dfrac{6}{1000}}=\dfrac{50}{3}M\\V_{H_2}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)
c, \(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
LTL: \(\dfrac{0,1}{2}< 0,1\)=> O2 dư
Theo pt: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\left(0,1-0,05\right).32=1,6\left(g\right)\\V_{O_2\left(dư\right)}=\left(0,1-0,05\right).22,4=1,12\left(l\right)\end{matrix}\right.\)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, \(n_{ZnSO_4}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnSO_4}=0,3.161=48,3\left(g\right)\)
d, \(n_{Fe_2O_3}=\dfrac{64}{160}=0,4\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{3}\), ta được Fe2O3 dư.
Mà: H% = 30% \(\Rightarrow n_{H_2\left(pư\right)}=0,3.30\%=0,09\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{2}{3}n_{H_2}=0,06\left(mol\right)\\n_{Fe_2O_3\left(pư\right)}=\dfrac{1}{3}n_{H_2}=0,03\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{Fe_2O_3\left(dư\right)}=0,4-0,03=0,37\left(mol\right)\)
\(\Rightarrow a=m_{Fe}+m_{Fe_2O_3\left(dư\right)}=62,56\left(g\right)\)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{18,56}{232}=0,08\left(mol\right)\)
PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Xét tỉ lệ: \(\dfrac{0,08}{1}>\dfrac{0,2}{4}\), ta được Fe3O4 dư.
Theo PT: \(n_{Fe}=\dfrac{3}{4}n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)