cho 100 gam dung dịch axit axetic tác dụng vừa đủ với kim loại magie. cô cạn dung dịch sau phản ứng người ta thu được 7,1 gam muối khan
a. tính thể tích khí được sinh ra ở đktc ?
b. tính C% của dung dịch axit CH3COOH đã dùng
c. cho toàn bộ lượng axit trên tác dụng với 6,9 gam rượu etylic có H2SO4 đặc làm xúc tác và đun nóng .tính khối lượng este thu được ? biết hiệu suất của phản ứng este hóa là 80%
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a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
\(\begin{array} {l} a)\\ Zn+H_2SO_4\to ZnSO_4+H_2\\ b)\\ n_{Zn}=\dfrac{32,5}{65}=0,5(mol)\\ n_{H_2SO_4}=\dfrac{100.39,2\%}{98}=0,4(mol)\\ \text{Vì }n_{H_2SO_4}<n_{Zn}\to Zn\text{ dư}\\ \text{Theo PT: }n_{H_2}=n_{H_2SO_4}=0,4(mol)\\ \to V_{H_2}=0,4.22,4=8,96(l)\\ c)\\ \text{Theo PT: }n_{ZnSO_4}=n_{H_2SO_4}=0,4(mol)\\ \to m=m_{ZnSO_4}=0,4.161=64,4(g) \end{array}\)
\(n_{Zn}=\dfrac{32,6}{65}=0,5\left(mol\right)\\ n_{H_2SO_4}=\dfrac{100.39,2\%}{98}=0,4\left(mol\right)\\ pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(\dfrac{0,5}{1}>\dfrac{0,4}{1}\)
=>Zn dư
\(n_{H_2}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{H_2}=0,4.22,4=8,96\left(l\right)\)
\(n_{ZnSO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\
m_{ZnSO_4}=0,4.161=64,4\left(g\right)\)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<-----------0,01-------->0,01
=> VH2 = 0,01.22,4 = 0,224 (l)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)
b)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,02------>0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,02` `0,02` `0,02` `(mol)`
`n_[Zn]=[1,3]/65=0,02(mol)`
`b)V_[H_2]=0,02.22,4=0,448(l)`
`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`
\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02 0,04 0,02 0,02 ( mol )
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)
\(n_{XCl_3}=\dfrac{a}{M_X+106,5}\left(mol\right)\)
PTHH: 2X + 6HCl --> 2XCl3 + 3H2
=> \(n_X=\dfrac{a}{M_X+106,5}\left(mol\right)\)
\(n_{X_2\left(SO_4\right)_3}=\dfrac{b}{2.M_X+288}\left(mol\right)\)
PTHH: 2X + 3H2SO4 --> X2(SO4)3 + 3H2
=> \(n_X=\dfrac{b}{M_X+144}\left(mol\right)\)
a, \(n_{CH_3COOH}=\dfrac{15}{60}=0,25\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COONa}=n_{CH_3COOH}=0,25\left(mol\right)\)
\(\Rightarrow a=m_{CH_3COONa}=0,25.82=20,5\left(g\right)\)
b, \(m_{dd}=\dfrac{15}{2\%}=750\left(g\right)\)
\(n_{CH_3COOH}=\dfrac{15}{60}=0,25\left(mol\right)\\ NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\\a, n_{CH_3COONa}=n_{CH_3COOH}=0,25\left(mol\right)\\ a=m_{CH_3COONa}=0,25.82=20,5\left(g\right)\\ b,m_{ddCH_3COOH}=\dfrac{15.100}{2}=750\left(g\right)\)
a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a.Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{ddHCl}=\dfrac{0,4.36,5.100}{7,3}=200\left(g\right)\\ c.m_{ddsau}=4,8+200-0,2.2=204,4\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{204,4}.100\approx9,295\%\\ d.V_{ddHCl}=\dfrac{200}{1,05}=\dfrac{4000}{21}\left(ml\right)=\dfrac{4}{21}\left(l\right)\\ C_{MddHCl}=\dfrac{0,4}{\dfrac{4}{21}}=2,1\left(M\right)\)
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)