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a, \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Bạn bổ sung thêm số liệu của khí thoát ra nhé.
a, \(n_K=\dfrac{0,975}{39}=0,025\left(mol\right)\)
A là khí H2, B là CH3COOK
PTHH: 2K + 2CH3COOH → 2CH3COOK + H2
Mol: 0,025 0,025 0,0125
b, \(C_{M_{ddCH_3COOH}}=\dfrac{0,025}{0,1}=0,25M\)
c, \(V_{H_2}=0,0125.22,4=0,28\left(l\right)\)
nKOH = 0,5.0,3 = 0,15 mol
CH3COOH + KOH → CH3COOK + H2O
0,15 0,15 0,15 mol
a) CM CH3COOH = 0,15/0,2 =0,75M
b) Thể tích của dung dịch thu được sau phản ứng: 500 ml
CM CH3COOK = 0,15/0,5 = 0,3M
c) Phản ứng lên men giấm
C2H5OH + O2 → CH3COOH + H2O
0,15 0,15
→ mC2H5OH = 0,15.46 = 6,9 gam
\(n_{KOH}=0,5\cdot0,3=0,15mol\)
\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,15 0,15 0,15 0,15
a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)
b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)
\(n_{CH_3COOH}=\dfrac{130.12}{100.60}=0,26\left(mol\right)\)
\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
0,13 0,26 0,13 0,13 ( mol )
\(m_{CaCO_3}=0,13.100=13\left(g\right)\)
\(V_{CO_2}=0,13.22,4=2,912\left(l\right)\)
\(m_{ddspứ}=13+130-0,13.44=137,28\left(g\right)\)
\(C\%_{\left(CH_3COO\right)_3Ca}=\dfrac{0,13.158}{137,28}.100=14,96\%\)
\(a,Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b,n_{CH_3COOH}=2.0,2=0,4\left(mol\right)\\ C_{MddCH_3COOH}=\dfrac{0,4}{0,4}=1\left(M\right)\\ c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\\ n_{CH_3COOK}=n_{CH_3COOH}=0,4\left(mol\right)\\ V_{ddCH_3COOK}=400+400=800\left(ml\right)=0,8\left(l\right)\\ C_{MddCH_3COOK}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
0,4 0,2
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(b,C_{M_{CH_3COOH}}=\dfrac{0,4}{0,4}=1M\)
\(c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,4 0,4 0,4
\(C_{M_{CH_3COOK}}=\dfrac{0,4}{0,4}=1M\)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
câu 1
\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,25 0,5 0,25 0,25
\(m_{FeCl_2}=0,25.127=31,75g\\
V_{H_2}=0,25.22,4=5,6\\
C_{M\left(HCl\right)}=\dfrac{0,5}{0,2}=2,5M\)
câu 2
1 ) \(m_{\text{dd}}=35+100=135g\\
2,C\%=\dfrac{204}{204+100}.100=60\%\\
=>m\text{dd}=\dfrac{100.204}{60}=340g\)
a) Na2CO3 + 2 CH3COOH -> 2 CH3COONa + H2O + CO2
nNa2CO3= 0,1(mol)
b) mddCH3COOH= 0,95.200= 190(g)
c) => mCH3COOH= 12% . 190=22,8(g)
=> nCH3COOH= 0,38(mol)
Ta có: 0,1/ 1 < 0,38/2
=> Na2CO3 hết, CH3COOH dư, tính theo nNa2CO3.
- Chất trong dd sau phản ứng CH3COONa và CH3COOH dư.
mddsaup.ứ= mNa2CO3 + mddCH3COOH - mCO2= 10,6+190-0,1. 44= 196,2(g)
\(C\%ddCH3COONa=\frac{0,2.82}{196,2}.100\approx8,359\%\\ C\%ddCH3COOH\left(Dư\right)=\frac{\left(0,38-0,2\right).60}{196,2}.100\approx5,505\%\)
Vddsau=VddCH3COOH= 0,2(l)
\(C_{MddCH3COONa}=\frac{0,2}{0,2}=1\left(M\right)\\ C_{MddCH3COOH\left(dư\right)}=\frac{0,38-0,2}{0,2}=0,9\left(M\right)\)