M + HNO3 => M(NO3)n + NO + H2O
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1.Al\(\rightarrow\)Al+3 +3e_______________.(5x-2y)
xN+5 +(5x-2y)e\(\rightarrow\)xN+\(\frac{2y}{x}\)______.3
\(\rightarrow\)(5x-2y)Al+(18x-6y)HNO3\(\rightarrow\)(5x-2y)Al(NO3)3+3NxOy+(9x-3y)H2O
2.M\(\rightarrow\)M+n +ne____.2
S+6 +2e\(\rightarrow\)S+4_____.n
\(\rightarrow\)2M+3nH2SO4\(\rightarrow\)2M(SO4)n+nSO2+3nH2O
3.M\(\rightarrow\)M+n +ne__________.(5x-2y)
xN+5 +(5x-2y)e\(\rightarrow\)xN+\(\frac{2y}{x}\) ____.n
\(\rightarrow\)(5x-2y)M+(6nx-2ny)HNO3\(\rightarrow\)(5x-2y)M(NO3)n+nNxOy+(3nx-ny)H2O
N+5 +3e\(\rightarrow\)N+2 __________.1
2N+5 +8e\(\rightarrow\)2N+1_________ .2
\(\rightarrow\)5N+5 +19e\(\rightarrow\)N+2 +4N+1______ .2
Zn\(\rightarrow\)Zn+2 +2e ____________ .19
\(\rightarrow\)19Zn+48HNO3\(\rightarrow\)19Zn(NO3)2+2NO+4N2O+24H2O
2N+5 +10e\(\rightarrow\)2N0 .2
2N+5+ 8e\(\rightarrow\)2N+1 .1
\(\rightarrow\)6N+5 +28e\(\rightarrow\)4N0 +2N+1 .3
Al\(\rightarrow\)Al+3 +3e _________.28
\(\rightarrow\)28Al+102HNO3\(\rightarrow\)28Al(NO3)3+6N2+3N2O+51H2O
2Fe+2 \(\rightarrow\)2Fe+3 +2e .5
Mn+7 +5e\(\rightarrow\)Mn+2 .2
\(\rightarrow\)10FeSO4+2KMnO4+2KHSO4\(\rightarrow\)5Fe2(SO4)3+2MnSO4+2K2SO4+H2O
4. (5x-2y)AL + (18x-6y)HNO3 -------> (5x-2y)AL(NO3)3 + 3NxOy +(9x-3y)H2O
5. 2M + 2nH2SO4--------> M2(SO4)n + nSO2 + 2nH2O
6. (5x-2y)M + (6nx-2ny)HNO3 -------->(5x-2y) M(NO3)n +n NxOy + (3nx-ny)H2O
7. 11Zn + 28HNO3 -------> 11Zn( NO3)2 + 2NO + 2N2O + 14H2O
8. 46AL + 168HNO3 -------;> 46AL( NO3)3 + 9N2 + 6N2O + 84H2O
9. 10FeSO4 + 2KMnO4 + 16KHSO4 ---> 5Fe2(SO4)3 +9 K2SO4 + 2MnSO4 + 8H2O.
mk chỉ ghi hệ số thôi nha
2, 0 - 2n - 0 - n - n
3, 0 - 4 - 0 - 0 - 2
4, 2 - 4 - 0 - 0 - 4
câu 1 hình như đề bị sai hay sao đó bn
3FexOy + (12x-2y)HNO3 3xFe(NO3)3 + (3x-2y)NO + (6x-y)H2O
3MxOy + (4nx - 2y)HNO3 = 3xM(NO3)n + (nx - 2y)NO + (2nx - y)H2O
a)\(3M+4nHNO_3-->3M\left(NO_3\right)_n+nNO+2nH_2O\)
b)
\(2M+2nH_2SO_4-->M_2\left(SO_4\right)_n+nSO_2+2nH_2O\)
c)
\(8M+30HNO_3-->8M\left(NO_3\right)_3+3N_2O+15H_2O\)
d)
\(8M+10nHNO_3-->8M\left(NO_3\right)_n+nN_2O+5nH_2O\)
e)\(\left(5x-2y\right)Fe+\left(15x-3y\right)HNO_3-->\left(5x-2y\right)Fe\left(NO_3\right)_3+3N_xO_y+\left(\dfrac{15x-3y}{2}\right)H_2O\)
f) \(3Fe_xO_y+\left(6x+2y\right)HNO_3-->3xFe\left(NO_3\right)_3+\left(2y-3x\right)NO+\left(3x+y\right)H_2O\)
g)\(Fe_xO_y+\left(6x-2y\right)HNO_3-->xFe\left(NO_3\right)_3+\left(3x-2y\right)NO_2+\left(3x-y\right)H_2O\) h)\(Fe_xO_y+2yHCl-->xFeCl_{\dfrac{2y}{x}}+yH_2O\)
i)\(2Fe_xO_y+2yH_2SO_4-->xFe_2\left(SO_4\right)_{\dfrac{2y}{x}}+2yH_2O\)
4A +18HNO3 --> 4A(NO3)3 +3NO +3NO2 +9H2O (1)
vì sau phản ứng khối lượng trong bình giảm => mhh=1,42(g)
nhh=0,045(mol)
=>Mhh=31,56(g/mol)
giả sử trong 1 mol hh có x mol NO
y mol NO2
=>\(\left\{{}\begin{matrix}x+y=1\\30x+46y=31,56\end{matrix}\right.=>\left\{{}\begin{matrix}x=0,9025\left(mol\right)\\y=0,0975\left(mol\right)\end{matrix}\right.\)
lập tỉ lệ :
\(\dfrac{0,9025}{3}>\dfrac{0,0975}{3}\)
=> NO2 hết ,NO dư => tính theo NO2
theo (1) : nA=4/3nNO2=0,13(mol)
=> 5,2/MA=0,13=> MA=40(g/mol)
=>A:Ca
1/
1. 5Al+24HNO3->5Al(NO3)3+6NO+3NO2+12H2O
2. 3Al+48HNO3->3Al(NO3)3+3NO+3N2+24H2O
Yêu cầu là gì
3M + 4nHNO3 ➞ 3M(NO3)n + nNO + 2nH2O
Chúc bạn học tốt !!!